SHANG RONGRONG SHANG

Last Updated :2022/12/01

所属・職名
大学院先進理工系科学研究科 助教
メールアドレス
rshanghiroshima-u.ac.jp
自己紹介
Dr. Rong Shang was born in China. She obtained her B.Sc. (1st Class Hons) from University of Canterbury in New Zealand in 2007. Supported by an international Ph.D. student scholarship, she then joined the laboratory of Prof. Anthony F. Hill at the Research School of Chemistry, Australian National University (Canberra, Australia), working on main-group element substituted group 6 carbyne complexes. In 2011, she took on a ERC post-doctoral research fellowship in Prof. Holger Braunschweig's group at the University of Würzburg (Germany), working on the reactivity of transition metal borylene complexes. Since 2015, she has been an Assistant Professor at Hiroshima University. She received tenure in 2019. Her research interests lie in the areas of main-group and organometallic chemistry, speicalizing in structure, bonding and reactivity studies.

基本情報

主な職歴

  • 2015年03月01日, 2020年03月31日, 広島大学, 大学院理学研究科, 助教
  • 2011年09月01日, University of Wurzburg, Institute of Inorganic Chemistry, Post-doctoral Research Fellow

学歴

  • オーストラリア国立大学, 大学院数理科学研究科, 化学専攻, オーストラリア, 2011年
  • University of Canterbury, Department of Chemistry, Faculty of Science, 化学, ニュージーランド, 2007年12月

学位

  • Doctor of Philosophy (THE AUSTRALIAN NATIONAL UNIVERSITY)

教育活動

授業担当

  1. 2022年, 教養教育, 1ターム, 化学基礎A
  2. 2022年, 教養教育, 2ターム, 化学基礎B
  3. 2022年, 学部専門, 3ターム, Inorganic and Organic Chemistry I (無機化学および有機化学 I)
  4. 2022年, 学部専門, 4ターム, Inorganic and Organic Chemistry II (無機化学および有機化学 II)
  5. 2022年, 学部専門, 4ターム, 先端化学
  6. 2022年, 学部専門, セメスター(前期), 卒業研究
  7. 2022年, 学部専門, セメスター(後期), 卒業研究
  8. 2022年, 学部専門, セメスター(前期), 化学英語演習
  9. 2022年, 学部専門, セメスター(後期), 化学英語演習
  10. 2022年, 学部専門, セメスター(前期), 化学実験I
  11. 2022年, 学部専門, セメスター(後期), 化学実験II
  12. 2022年, 学部専門, 4ターム, グローバル対策セミナーB
  13. 2022年, 修士課程・博士課程前期, 1ターム, 基礎化学特別演習A
  14. 2022年, 修士課程・博士課程前期, 2ターム, 基礎化学特別演習A
  15. 2022年, 修士課程・博士課程前期, 3ターム, 基礎化学特別演習B
  16. 2022年, 修士課程・博士課程前期, 年度, 基礎化学特別研究
  17. 2022年, 博士課程・博士課程後期, 年度, 基礎化学特別研究

研究活動

学術論文(★は代表的な論文)

  1. Synthesis of New Dipyrido-Annulated N-Heterocyclic Carbenes with Aryl Substituents, Z. Anorg. Allg. Chem., 641巻, pp. 2199, 2015
  2. Activation of boryl-, borylene and metalloborylene complexes by isonitriles, Chem. Commun., 51巻, pp. 13032, 2015
  3. A metal-mediated boron-centred isomerisation reaction via C-H activation, Chem. Commun., 51巻, pp. 16569, 2015
  4. Reactivity of Transition-Metal Borylene Complexes: Recent Advances in B-C and B-B Bond Formation via Borylene Ligand Coupling, Inorg. Chem., 54巻, pp. 3099, 2015
  5. Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments, Chem. Sci., 6巻, pp. 2989, 2015
  6. Isolation of the Key Intermediates of Base-Promoted Borylene-Carbonyl Coupling Reactions, Chem. Sci., 5巻, pp. 2271, 2014
  7. Reversible Intramolecular Coupling of the Terminal Borylene and a Carbonyl Ligand of [Cp(CO)2Mn=B-tBu], Angew. Chem., Int. Ed., 52巻, pp. 729, 2013
  8. [sigma]-Coordination of metal-boryl bonds to gold(I), Chem. Commun. (front cover), 49巻, pp. 9905, 2013
  9. A Golden Ring: Molecular Gold Carbido Complexes, J. Am. Chem. Soc., 135巻, pp. 4942, 2013
  10. Metathesis Reactions of a Manganese Borylene Complex with Polar Heteroatom-Carbon Double Bonds: A Pathway to Previously Inaccessible Carbene Complexes, J. Am. Chem. Soc., 135巻, pp. 8726, 2013
  11. Boratocarbyne Complexes: Li[Mo{CB(OMe)3}(CO)2{HB(pzMe2)3}] and [K(18-crown-6)][Mo(CBF2OMe)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl), Organometallics, 31巻, pp. 4635, 2012
  12. Borylcarbyne Complexes: [Mo(CBR2)(CO)2{HB(pzMe2)3}] (BR2 = B(NMe2)2, BO2C6H4; pz = pyrazol-1-yl), Organometallics, 30巻, pp. 3237, 2011
  13. Group 14 Substituted Carbyne Complexes - An Almost Complete Set: [Mo(CAPh3)(CO)2(Tp*)] (Tp* = Hydrotris(dimethylpyrazolyl)borate; A = Si, Ge, Sn, Pb but A ≠ C), Organometallics, 30巻, pp. 139, 2011
  14. Analogies between Metallaboratranes, Triboronates, and Boron Pincer Ligand Complexes, Organometallics, 29巻, pp. 5661, 2010
  15. The odd bit of carbon, Comments Inorg. Chem., 31巻, pp. 121, 2010
  16. Synthesis of a Thiocarbamoyl Alkylidyne Complex and Caveats Associated with the Use of [Mo(CLi)(CO)2(Tp*)] (Tp* = Hydrotris(3,5-dimethylpyrazol-1-yl)borate), Organometallics, 29巻, pp. 6482, 2010
  17. The synthesis and structure of a thiobenzyl-functionalized dibenzoferrocene complex, J. Coord. Chem., 63巻, pp. 2790, 2010
  18. A Bis-Carbyne (Ethanediylidyne) Complex via the Catalytic Demercuration of a Mercury Bis(carbido) Complex, Organometallics, 28巻, pp. 4394, 2009
  19. Structural and spectroscopic investigations of non-planar tris(dialkylamino)cyclopropenium cations, J. Phys. Org. Chem., 21巻, pp. 127, 2008
  20. Methyltriphenylphosphonium bromide chloroform hemisolvate, Acta Crystallogr., Sect. E Struct. Rep. Online, E63巻, pp. o3951, 2007
  21. Interactions of Isonitriles with Metal–Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron, Chem. - Euro J., 22巻, pp. 11736, 2016
  22. Direct Conversion from Terminal Borylene to Terminal Phosphinidene, Angew. Chem., Int. Ed., 55巻, pp. 12673, 2016
  23. Synthesis of a Sterically Demanding Dispiropiperidine and Its Application in Monoamidodialkyl Zincate Complexes, Inorg. Chem., 55巻, pp. 10767, 2016
  24. Rearrangement of bis(alkylidynyl)phosphines to phospha-acyls, Chem. Commun., 53巻, pp. 1832-1835, 2017
  25. Frontispiece: Triaminotriborene: A Homocatenated Boron Chain Connected by B–B Multiple Bonds, Angew. Chem., Int. Ed. (VIP), 56巻, pp. 15234, 2017
  26. Triaminotriborane(3): A Homocatenated Boron Chain Connected by B-B Multiple Bonds, Angew. Chem., Int. Ed., 56巻, 48号, pp. 15234-15240, 2017
  27. Facile reactions of gold(i) complexes with tri(tert-butyl)azadiboriridine, Dalton Trans. (back cover), 47巻, pp. 5181-5188, 2018
  28. Luminescent Di- and Tetranuclear Gold Complexes of Bis(diphenylphosphinyl)-Functionalized Dipyrido-Annulated N-Heterocyclic Carbene, Inorg. Chem., 58巻, pp. 6328-6335, 20190423
  29. Synthesis and characterization of a pair of O-fac/O-mer 12-P-6 alkyloxaphosphates with a P–O–C–C four-membered ring, Chem. Sci. (back cover), 10巻, pp. 3466-3472, 20190215
  30. Bis(diphenylphosphinyl)-functionalized dipyrido- annulated NHC towards copper(I) and silver(I), Dalton Trans., 48巻, 32号, pp. 12250-12256, 20190708
  31. Development of aryl-containing dipyrrolyldiketone difluoroboron complexes (BONEPYs): Tune the hydrogen bond oCH···F for fluoride recognition, Chin. Chem. Lett., 20191001
  32. The Substituent Effect of Bridged Triarylamine Helicenes on Light-emitting and Charge Transfer Properties, Chem. Lett., 49巻, 5号, pp. 457-460, 20200227
  33. Synthesis and Properties of Hypervalent Electron-rich Pentacoordinate Nitrogen Compounds, Chem. Sci., 11巻, pp. 5082-5088, 20200408
  34. In Search of Fulminate Analogues: LnMCPNR, Chem. - Euro J., 26巻, pp. 8819-8827, 20200505
  35. Catalytic Dehydrogenation of Ammonia Borane Mediated by a Pt(0)/Borane Frustrated Lewis Pair: Theoretical Design, ChemPhysChem, 20201006
  36. A Digallane Gold Complex with a 12-Electron Auride Center: Synthesis and Computational Studies, Organometallics, 39巻, 23号, pp. 4372, 20201029
  37. Synthesis and Isolation of an Anionic Bis(dipyrido-annulated) N-Heterocyclic Carbene CCC-Pincer Iridium(III) Complex by Facile C–H Bond Activation., Inorganic Chemistry, 2021

外部資金

競争的資金等の採択状況

  1. 令和3年度科学研究費助成事業(学術研究助成基金助成金) C, 反芳香族B,N-カルベンσ配位子の開発と常磁性/アニオン性金錯体の合成と物性解明, 2021年
  2. コニカミノルタ株式会社 開発統括本部, 3座配位ピンサー型Ir錯体の合成研究
  3. 平成31年度科学研究費助成事業(学術研究助成基金助成金) 若手研究, ジボロン遷移金属錯体:ホウ素化反応に見られる遷移金属のB-B結合活性化の解明, 2018年, 2019年
  4. 平成29年度 広島大学女性研究者共同研究費助成, Boron-containing transition metal complexes for Chemical Transformations and Catalysis, 2017年
  5. 産学連携若手研究者支援プログラム, Clever Molecular Design For Catalysts of Sustainable Chemical Transformations, 2017年
  6. 科学研究費助成事業(研究活動スタート支援), Investigation of Transition Metal Base containing Frustrated Lewis Pairs for Potential Catalysts of Sustainable Chemical Transformations, 2015年, 2016年