塩野 毅Takeshi Shiono

Last Updated :2022/06/01

所属・職名
大学院先進理工系科学研究科 教授
ホームページ
メールアドレス
tshionohiroshima-u.ac.jp

基本情報

主な職歴

  • 1984年04月01日, 1993年11月30日, 東京工業大学, 資源化学研究所, 助手
  • 1993年12月01日, 2004年06月30日, 東京工業大学, 資源化学研究所, 助教授

学歴

  • 東京工業大学, 総合理工学研究科, 化学環境工学専攻, 日本, 1983年04月, 1984年03月
  • 東京工業大学, 総合理工学研究科, 化学環境工学専攻, 日本, 1981年04月, 1983年03月
  • 東京工業大学, 工学部, 化学工学科, 日本, 1977年04月, 1981年03月

学位

  • 工学博士 (東京工業大学)
  • 工学修士 (東京工業大学)

研究分野

  • 化学 / 材料化学 / 高分子・繊維材料

研究キーワード

  • 配位重合
  • 遷移金属触媒
  • リビング重合
  • 共重合
  • ポリオレフィン
  • シクロオレフィン

所属学会

  • アメリカ化学会
  • 日本化学会
  • 日本液晶学会
  • 触媒学会
  • 高分子学会
  • 石油学会

教育活動

授業担当

  1. 2022年, 教養教育, 1ターム, 教養ゼミ
  2. 2022年, 学部専門, 通年, 卒業論文
  3. 2022年, 学部専門, 1ターム, 高分子合成化学
  4. 2022年, 学部専門, 3ターム, 高分子工業化学
  5. 2022年, 修士課程・博士課程前期, 1ターム, 応用化学特別演習A
  6. 2022年, 修士課程・博士課程前期, 1ターム, 応用化学特別演習A
  7. 2022年, 修士課程・博士課程前期, 2ターム, 応用化学特別演習A
  8. 2022年, 修士課程・博士課程前期, 2ターム, 応用化学特別演習A
  9. 2022年, 修士課程・博士課程前期, 3ターム, 応用化学特別演習B
  10. 2022年, 修士課程・博士課程前期, 4ターム, 応用化学特別演習B
  11. 2022年, 修士課程・博士課程前期, 1ターム, 応用化学特別演習A
  12. 2022年, 修士課程・博士課程前期, 2ターム, 応用化学特別演習A
  13. 2022年, 修士課程・博士課程前期, 3ターム, 応用化学特別演習B
  14. 2022年, 修士課程・博士課程前期, 3ターム, 応用化学特別演習B
  15. 2022年, 修士課程・博士課程前期, 4ターム, 応用化学特別演習B
  16. 2022年, 修士課程・博士課程前期, 4ターム, 応用化学特別演習B
  17. 2022年, 修士課程・博士課程前期, 年度, 応用化学特別研究
  18. 2022年, 修士課程・博士課程前期, 年度, 応用化学特別研究
  19. 2022年, 修士課程・博士課程前期, 年度, 応用化学特別研究
  20. 2022年, 修士課程・博士課程前期, 2ターム, 高分子合成化学論
  21. 2022年, 修士課程・博士課程前期, 4ターム, Advanced Synthetic Polymer Chemistry
  22. 2022年, 博士課程・博士課程後期, 年度, 応用化学特別研究
  23. 2022年, 修士課程・博士課程前期, 1ターム, サステナブル物質科学

研究活動

学術論文(★は代表的な論文)

  1. Living ring-opening metathesis polymerization of Exo-norbornenes bearing both cyano and ester functionalities by a well-defined ruthenium catalyst, POLYMER JOURNAL, 39巻, 4号, pp. 318-329, 2007
  2. Synthesis of poly(ester-urethane)s from hydroxytelechelic polylactide: Effect of initiators on their physical and degradation properties, POLYMER DEGRADATION AND STABILITY, 93巻, 1号, pp. 117-124, 200801
  3. Precise control of microstructure of functionalized polypropylene synthesized by the ansa-zirconocene/MAO catalysts, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 46巻, 5号, pp. 1738-1748, 20080301
  4. Catalytic synthesis of a monodisperse olefin block copolymer using a living polymerization system, MACROMOLECULAR RAPID COMMUNICATIONS, 29巻, 6号, pp. 525-529, 20080319
  5. Ring-opening metathesis polymerization of norbornene catalyzed by tantalum and niobium complexes with chelating O-donor ligands, POLYMER INTERNATIONAL, 57巻, 7号, pp. 950-956, 200807
  6. Synthesis, characterization, and thermal properties of ring-opening metathesis polynorbornenes and their hydrogenated derivatives bearing various ester and cyano groups, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 46巻, 10号, pp. 3314-3325, 20080515
  7. Highly active copolymerization of ethylene and dicyclopentadiene with [(eta(1)-t-BuN)SiMe2(eta(1)-C29H36)]TiMe2(THF) complex, CHEMISTRY LETTERS, 37巻, 6号, pp. 590-591, 20080605
  8. Facile synthesis of tailor-made stereoblock polypropylenes via successive variation of monomer pressure, MACROMOLECULES, 41巻, 17号, pp. 6596-6598, 20080909
  9. A New Approach for Controlling Birefringent Property of Cyclic Olefin Copolymers, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 46巻, 22号, pp. 7395-7400, 20081115
  10. Random Copolymerization of Norbornene with Higher 1-Alkene with ansa-Fluorenylamidodimethyltitanium Catalyst, MACROMOLECULES, 41巻, 22号, pp. 8292-8294, 20081125
  11. SUBSTITUENT EFFECTS OF tert-BUTYL GROUPS ON FLUORENYL LIGAND OF [t-BuNSiMe(2)Flu]ZrMe2, CHINESE JOURNAL OF POLYMER SCIENCE, 26巻, 5号, pp. 575-578, 200809
  12. A Highly Active Catalyst Composed of ansa-Fluorenylamidodimethyltitanium Derivative for Propene Polymerization, TOPICS IN CATALYSIS, 52巻, 6-7号, pp. 675-680, 200906
  13. Synthesis of Regioblock Polybutadiene with CoCl2-Based Catalyst via Reversible Coordination of Lewis Base, MACROMOLECULES, 42巻, 20号, pp. 7642-7643, 20091027
  14. Highly Active Syndiospecific Living Polymerization of Higher 1-Alkene with ansa-Fluorenylamidodimethyltitanium Complex, MACROMOLECULAR RAPID COMMUNICATIONS, 30巻, 21号, pp. 1812-1816, 20091102
  15. Ring-opening polymerization of six-membered cyclic esters catalyzed by tetrahydroborate complexes of rare earth metals, POLYMER, 50巻, 20号, pp. 4788-4793, 20090923
  16. Highly Active Living Random Copolymerization of Norbornene and 1-Alkene with ansa-Fluorenylamidodimethyltitanium Derivative: Substituent Effects on Fluorenyl Ligand, MACROMOLECULES, 43巻, 10号, pp. 4527-4531, 20100525
  17. Additive effects of alkylaluminium compounds on propylene-1,3-butadiene copolymerization using isospecific zirconocene catalysts, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 695巻, 12-13号, pp. 1694-1699, 20100601
  18. Synthesis of Stereoblock Polypropylene by Change of Temperature in Living Polymerization, MACROMOLECULAR RESEARCH, 18巻, 8号, pp. 737-741, 201008
  19. Efficient Molecular Weight Control with Trialkylaluminum in Ethylene/Norbornene Copolymerization by [Ph2C(Flu)(3-MeCp)]ZrCl2/Methylaluminoxane Catalyst, MACROMOLECULAR CHEMISTRY AND PHYSICS, 211巻, 19号, pp. 2132-2137, 20101001
  20. Highly Thermostable and Low Birefringent Norbornene-Styrene Copolymers with Advanced Optical Properties: A Potential Plastic Substrate for Flexible Displays, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 49巻, 1号, pp. 65-71, 20110101
  21. Highly trans-1,4-specific polymerization of 1,3-butadiene catalyzed by [2,6-bis{(4S)(-)-isopropyl-2-oxazolin-2-yl} pyridine]chromium complex activated with modified methylaluminoxane, POLYMER INTERNATIONAL, 60巻, 4号, pp. 692-697, 201104
  22. Living polymerization of olefins with ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium-based catalysts, POLYMER JOURNAL, 43巻, 4号, pp. 331-351, 201104
  23. The Influence of t-Butyl and Cyclododecyl Substitution on Ethylene/1-Hexene Copolymerization Using Ansa-Fluorenylamidodimethyltitanium Derivatives, MOLECULES, 16巻, 5号, pp. 4122-4130, 201105
  24. Impregnation of Poly(L-lactide-ran-cyclic carbonate) Copolymers with Useful Compounds with Supercritical Carbon Dioxide, JOURNAL OF APPLIED POLYMER SCIENCE, 121巻, 3号, pp. 1431-1441, 20110805
  25. High Activity of Rare Earth Tetrahydroborates for Ring-Opening Polymerization of omega-Pentadecalactone, JOURNAL OF APPLIED POLYMER SCIENCE, 121巻, 4号, pp. 2098-2103, 20110815
  26. 2-[1-(2,6-Dibenzhydryl-4-chlorophenylimino)ethyl]-6-[1-(arylimino)ethyl]pyridyliron(II) dichlorides: Synthesis, characterization and ethylene polymerization behavior, POLYMER, 53巻, 9号, pp. 1870-1880, 20120417
  27. Incorporation of L-lactide random copolymers with Japanese cypress oil (alpha-pinene) using supercritical carbon dioxide, GREEN CHEMISTRY, 14巻, 4号, pp. 1211-1219, 2012
  28. Effect of Ga- and BCl3-modified silica-supported [t-BuNSiMe2(2,7-t-Bu(2)Flu)]TiMe2/MAO catalyst on ethylene/1-hexene copolymerization, EUROPEAN POLYMER JOURNAL, 48巻, 7号, pp. 1304-1312, 201207
  29. 2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinolylcobalt dichloride: Synthesis and polyethylene wax formation, APPLIED CATALYSIS A-GENERAL, 447巻, pp. 67-73, 20121207
  30. Copolymerization of ethylene with 1,1-disubstituted olefins catalyzed by ansa-(fluorenyl)(cyclododecylamido)dimethyltitanium complexes, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 51巻, 5号, pp. 1223-1229, 20130301
  31. Precise synthesis of olefin block copolymers using a syndiospecific living polymerization system, CHINESE JOURNAL OF POLYMER SCIENCE, 31巻, 4号, pp. 541-549, 201304
  32. Copolymerization of ethylene/1-hexene with zirconocene/MAO catalyst supported on spherical zirconia modified with BCl3, SiCl4, and glycerol, POLYMER BULLETIN, 70巻, 6号, pp. 1753-1768, 201306
  33. Synthesis of high-molecular weight block copolymers of norbornene and propylene with methyl methacrylate initiated by a fluorenylamido titanium complex, POLYMER CHEMISTRY, 4巻, 14号, pp. 3974-3980, 20130721
  34. Repression by Cu of the expression of Fe-superoxide dismutase of chloroplasts in the Moss Barbula unguiculata but not in the liverwort Marchantia paleacea var. diptera., J. Hattori Bot. Lab, 93巻, pp. 141-153, 20030401
  35. The role of additives on the improvement of the isotacticity of polypropylene - A possible interpretation -, Chem. Lett., pp. 425-428, 19820401
  36. Synthesis of EP-rubber using Ti-catalysts, Stud. Surf. Sci. Catal., 25巻, pp. 109-122, 19860401
  37. Structure of polyethylene and copolymers of ethylene with 1-octene and oligoethylene produced with the Cp2ZrCl2 and [(C5Me4)SiMe2N(t-Bu)]TiCl2 catalysts, Macromol. Chem. Phys., 197巻, pp. 4237-4251, 19960401
  38. Alternating copolymerization of ethylene and propene with the [ethylene(1-indenyl)(9-fluorenyl)]zirconium dichloride-methylaluminoxane catalyst system, Macomol.Rapid Commun, 19巻, pp. 337-339, 19980401
  39. Synthesis and functionalization of poly(ethylene-co-dicyclopentadiene, J Appl Polym Sci, 72巻, pp. 103-108, 19990401
  40. The role of additives on the improvement of the isospecificity of polypropylene - a plausible interpretation, Chem. Lett., pp. 425-428, 19820401
  41. Effect of hydrogen on the molecular weight of polypropylene with Ziegler-Natta catalysts, Polym. Bull., 8巻, pp. 261-268, 19820401
  42. Effect of ethyl benzoate on the copolymerization of ethylene with higher -olefins over TiCl4/MgCl2 catalysts, Polym. Bull., 10巻, pp. 168-174, 19830401
  43. Polymerization of ethylene over catalysts composed of diethylaluminium chloride and metal chlorides, J. Chem. Soc. = Chem. Commun., pp. 840-841, 19840401
  44. Preparation of a stable supported catalyst for propene polymerization, Makromol. Chem., Rapid Commun., 6巻, 8号, pp. 537-540, 19850401
  45. Homo- and copolymerization of ethylene and propylene with a soluble chromium catalyst, Polymer, 26巻, 11号, pp. 1888-1890, 19850401
  46. Preparation of highly active Cr-catalysts for ethylene polymerization, Polymer, 26巻, 11号, pp. 1891-1894, 19850401
  47. Stereospecific polymerization of propene using MgCl2-supported Ti catalysts combined with (RCp)2TiMe2(R=H, Me), Makromol. Chem., Rapid Commun., 7巻, 11号, pp. 719-723, 19860401
  48. Polymerization of ethylene with Cr[OC(CH3)3]4/Al(C2H5)2Cl as catalyst modified with some metal chlorides, Makromol. Chem., 187巻, 2号, pp. 351-356, 19860401
  49. Polymerization of ethylene and propylene with Cr(C17H35)3/AlEt2Cl/metal chlorides catalyst, Macromolecules, 19巻, 12号, pp. 2893-2895, 19860401
  50. Isotactic polymerization of propene with (mu -1,1’-ethylene-di-4,5,6,7-tetrahydroindenyl)-zirconium dichloride combined with methyaluminoxiane, Makromol. Chem. Rapid Commun., 8巻, 6号, pp. 305-310, 19860401
  51. Highly active chromium catalysts for ethylene polymerization, Advances in polyolefins, pp. 143-151, 19870401
  52. Polymerization of alpha-olefins with the catalyst system prepared from a hydrated transition metal compound and trimethylaluminium, Makromol. Chem., Rapid Commun., 9巻, 3号, pp. 141-144, 19880401
  53. Polymerization of styrene with the catalyst system prepared from hydrated transition metal (Ti, Zr) compounds and trimethylaluminium, Makromol. Chem.= Rapid Commun., 9巻, 5号, pp. 351-354, 19880401
  54. Influence of internal and external donors on activity and stereospecificity of Ziegler-Natta catalysts;, Makromol. Chem., 189巻, 7号, pp. 1531-1541, 19880401
  55. Effect of diesters and organosilicon compounds on the stability and stereospecificity of Ziegler-Natta catalyst, Transition Metal Catalyzed Polymerizations=Kodansha-Elsevior= Tokyo, pp. 266-279, 19880401
  56. A highly non-stereospecific catalyst for propene polymerization, Polym. Bull., 21巻, pp. 19-21, 19890401
  57. Highly isospecific catalyst for propene polymerization composed of TiCl4/MgCl2 and Cp2TiMe2 without donors, Makromol. Chem.= Rapid Commun., 10巻, 6号, pp. 293-297, 19890401
  58. Evaluation of propagation rate constants for isospecific and atactic polymerization of propene with MgCl2-supported catalysts, Makromol. Chem.= Rapid Commun., 10巻, 9号, pp. 503-507, 19890401
  59. Perfect conversion of aspecific sites into isospecific sites in Ziegler-Natta catalysts, Macromolecules, 22巻, 9号, pp. 3824-3826, 19890401
  60. Stereospecific polymerization of higher alpha-olefins with the Solvay type TiCl3/Cp2Ti(CH3)2 catalyst, Makromol. Chem., 190巻, 11号, pp. 2683-2691, 19890401
  61. Preparation and characterization of syndiotactic poly(vinylcyclohexane), Macromolecules, 22巻, 4号, pp. 1499-1500, 19890401
  62. A direct evidence for the improvement of isospecificity in Ziegler-Natta catalysts by ethyl benzoate, Makromol. Chem.= Rapid Commun., 11巻, 3号, pp. 117-121, 19900401
  63. Synthesis of terminally hydroxylated isotactic polypropylene using Zn(C2H5)2 and oxygen as chain transfer and quenching reagents, Makromol. Chem., Rapid Commun., 11巻, 4号, pp. 169-175, 19900401
  64. Polymerization of styrene with heterogeneous Ziegler-Natta catalysts, Makromol. Chem., Rapid Commun., 11巻, 5号, pp. 229-234, 19900401
  65. Ethylene polymerization with an SiO2/TiCl4/Al(CH2CH(CH3)2)3 one-phase catalyst, Makromol. Chem., Rapid Commun., 11巻, 11号, pp. 541-547, 19900401
  66. Synthesis of recyclable polyolefins from alpha, omega-dihydroxy-polybutadiene using condensation and hydrogenation reactions, Makromol. Chem., Rapid Commun., 12巻, 7号, pp. 387-392, 19910401
  67. Possibility of mass-transfer resistance in ethylene polymerization with MgCl2-supported catalysts, Macromolecules, 24巻, 7号, pp. 1699-1700, 19910401
  68. Propene polymerization with a Mg(OC2H5)2-supported TiCl4 catalyst, 3 The role of benzoyl chloride, Makromol. Chem., 192巻, 8号, pp. 1727-1731, 19910401
  69. Structural characterization of solution-crystallized 13C-labeled polyethylene over the wide range of temperatures by means of high resolution 13C NMR Spectroscopy, J. Mol. Sci., 263巻, pp. 319-327, 19910401
  70. K. Soga, J. R. Park and T. Shiono: Copolymerization of ethylene and propylene with a CpTiCl3/SiO2-MAO catalyst system, Polym. Commun., 32巻, 10号, pp. 310-313, 19910401
  71. Dynamic study of the noncrystalline phase of 13C-labeled polyethylene by means of variable-temperature 13C CP/MAS NMR spectroscopy, J. Polym. Sci.: Part B: Polymer Phys., 30巻, pp. 591-601, 19920401
  72. Regioirregular polypropylene prepared with SiO2-supported titanium catalysts, Macromolecules, 25巻, 2号, pp. 521-524, 19920401
  73. Synthesis of terminally Al-functionalized polypropylene, Macromolecules, 25巻, 13号, pp. 3356-3361, 19920401
  74. Synthesis of terminally carboxylated and chlorinated polypropylenes using ZnEt2 as a chain transfer reagent, Makromol. Chem., 193巻, 11号, pp. 2751-2761, 19920401
  75. Synthesis of terminally halogenated isotactic polypropylene, Makromol. Chem., Rapid Commun., 13巻, 8号, pp. 371-376, 19920401
  76. Polymerization of 1,3-butadiene with the catalyst system composed of a cobalt compound and methylalmoxane, Polymer Inter., 29巻, pp. 209-212, 19920401
  77. カミンスキー系触媒によるエチレン-プロピレン共重合体の合成とその末端修飾, 高分子論文集, 49巻, 10号, pp. 847-854, 19921001
  78. Synthesis of polypropylenes functionalized with secondary amino group at the chain ends, Macromolecules, 26巻, 8号, pp. 2085-2089, 19930401
  79. Reaction between carbon monoxide and a Ti-polyethylene bond with a MgCl2-supported TiCl4 catalyst system, Makromol. Chem., 194巻, 7号, pp. 2075-2085, 19930401
  80. Copolymerization of ethylene and propylene with a TiCl4/MgCl2-Al(C2H5)3 catalyst system using a stopped-flow method, Makromol. Chem., 194巻, 8号, pp. 2173-2181, 19930401
  81. Propylene polymerization with Mg(OEt)2/benzoyl chloride/TiCl4-triethylaluminum/external donor catalyst systems, J Appl Polym Sci, 47巻, pp. 1449-1461, 19930401
  82. Propene polymerization with the one-phase catalyst SiO2/TiCl4/Al(CH2CH(CH3)2)3, Makromol. Chem., Rapid Commun., 14巻, 2号, pp. 85-89, 19930401
  83. 部分水素化シス-1,4-ポリブタジエンのエチレンによるメタセシス分解, 高分子論文集, 50巻, 10号, pp. 873-880, 19931001
  84. Activation of SiO2-supported zirconocene catalysts by common trialkylaluminums, Makromol. Chem., 194巻, 12号, pp. 3499-3504, 19930401
  85. Synthesis of alpha, omega-divinylpolyethylene-like Polymers from cis-1,4-polybutadiene using partial hydrogenation and metathesis degradation with ethylene, Makromol. Chem. Rapid Commun., 14巻, 6号, pp. 323-327, 19930401
  86. Polymerization of ethylene with homogeneous metallocene catalysts activated by common trialkylaluminums and Si(CH3)3OH, Makromol. Chem., Rapid Commun., 14巻, 12号, pp. 765-770, 19930401
  87. Highly isospecific SiO2-supported zirconocene catalysts activated by ordinary alkylaluminums, Macromol.Rapid Commun., 15巻, 2号, pp. 139-143, 19940401
  88. Reaction of a Ti-polyethylene bond with carbon monoxide over the bis(cyclopentadienyl)-titaniumdichloride-methylaluminoxane catalyst system, Polymer, 35巻, 1号, pp. 187-192, 19940401
  89. Synthesis of vinyl-terminated isotactic poly(propylene) using coupling reaction between Zn-terminated Polymer and allyl halides, Macromol. Chem. Phys., 195巻, 4号, pp. 1381-1388, 19940401
  90. Structure of polypropylene and poly(ethylene-co-propylene) produced with an alumina-supported CpTiCl3/common alkylaluminium catalyst system, Macromol., Chem. Phys., 195巻, 5号, pp. 1503-1515, 19940401
  91. Synthesis of isotactic polypropylene functionalized with a primary amino group at the initiation chain end, Macromolecules, 27巻, 9号, pp. 2635-2637, 19940401
  92. Polymerization of olefins with the TiCl4/SiO2 catalyst system modified with MgCl2, Macromol. Chem. Phys., 195巻, 7号, pp. 2591-2598, 19940401
  93. Synthesis of isotactic poly(propene)-block-poly(methyl methacrylate) using magnesium bromide-terminated isotactic poly(propene), Macromolecules, 27巻, 21号, pp. 6229-6231, 19940401
  94. エチレンビス(テトラヒロドインデニル)ジルコニウムジクロリド-メチルアルミノキサン触媒におけるオレフィン重合の連鎖移動反応, 高分子論文集, 51巻, 10号, pp. 663-665, 19940401
  95. Synthesis of alpha, omega-dialkenyl isotactic poly(propylene) using bis(4-methyl-3-pentenyl)zinc as a chain transfer reagent, Macromol. Chem. Phys., 195巻, 10号, pp. 3303-3309, 19940401
  96. Polymerization of propene with highly isospecific SiO2-supported zirconocene catalysts activated with common alkylaluminums, Macromol. Chem. Phys., 195巻, 10号, pp. 3347-3360, 19940401
  97. Stereospecific polymerization of methyl methacrylate initiated by dimethylzirconocene/B(C6F5)3 (or Ph3CB(C6F5)4/Zn(C2H5)2, Macromolecules, 27巻, 26号, pp. 7938-7940, 19940401
  98. Isospecific polymerization of propene over TiCl3 combined with bis(-alkenyl)zinc compounds, Macromolecules, 28巻, 2号, pp. 437-443, 19950401
  99. Polymerization of 1,3-butadiene with MgCl2-supported cobalt catalysts activated by ordinary alkylaluminums, Polymer Inter., 26巻, pp. 41-45, 19950401
  100. Structure of chain-ends in polybutadiene produced with the CoBr2(PPh)3/MgCl2/SiPh2(OCH3)2-Al(CH3)3 catalyst system, Macromol.Rapid Commun., 16巻, 3号, pp. 169-174, 19950401
  101. Isospecific polymerization of methyl methacrylate initiated by chiral zirconocene/Ph3CB(C6F5)4 in the presence of Lewis acids, Macromolecules, 28巻, 9号, pp. 3067-3073, 19950401
  102. Characterization of polybutadiene produced with the CoBr2(PPh)3/MgCl2/SiPh2(OCH3)2-Al(CH3)3 catalyst system, Macromol.Rapid Commun., 16巻, 5号, pp. 373-378, 19950401
  103. Polymerization of methyl methacrylate with achiral 4B group metallocene compounds, Macromol. Chem. Phys., 196巻, 6号, pp. 1971-1980, 19950401
  104. Polymerization of 1,3-butadiene over MgCl2-supported cobalt catalysts combined with trimethylaluminum, Macromol. Chem. Phys., 197巻, 2号, pp. 729-743, 19960401
  105. 三塩化チタン-ジエチルアルミニウムクロリド-ジエチル亜鉛系触媒による末端ハロゲン化アイソタクチックポリプロピレンの合成, 接着学会誌, 32巻, 7号, pp. 261-265, 19960401
  106. Structures of polyethylene and Copolymers of ethylene with 1-octene produced with the Cp2ZrCl2 and [(C5Me5)]SiMe2N(t-Bu)]TiCl2 catalysts, Macromol. Chem. Phys., 197巻, 12号, pp. 4237-4251, 19960401
  107. Isotactic copolymerization of methyl methacrylate with alkyl acrylate, Polym. Bull., 36巻, pp. 667-671, 19960401
  108. Functionalization of initiation chain ends of isotactic polypropylene using modified cocatalysts, Main Group Elements and Their Compounds, pp. 255-266, 19960401
  109. Additive effects of Lewis bases on propene polymerization over MgCl2-supported TiCl4 catalysts combined with Cp2TiMe2, Polym. J., 29巻, 3号, pp. 224-229, 19970401
  110. Synthesis of aluminum-terminated polypropylene by a MgCl2-supported TiCl4 catalyst combined with Al(i-Bu)3 as cocatalyst, Macromolecules, 30巻, 4号, pp. 1231-1232, 19970401
  111. Control of molecular weight distribution of isotactic polypropylene obtained by a MgCl2-supported TiCl4 catalyst, Polymer, 38巻, 26号, pp. 6409-6411, 19970401
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  385. Precise Synthesis of Cycloolefin Copolymer Using ansa-Silylene(fluorenyl)(amido)dimethyltitanium Complex as a Catalyst, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 72巻, 2号, pp. 118-125, 20140201
  386. Synthesis of C-1 symmetrical ansa-cyclopentadienylamidotitanium complexes and their application for living polymerization of propylene, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 770巻, pp. 136-141, 20141101
  387. Heterogenization of an Anilinonaphthoquinone-Chelated Nickel Complex for Ethylene Polymerization Using Silica-Supported Modified Methylaluminoxane, MACROMOLECULAR CHEMISTRY AND PHYSICS, 215巻, 18号, pp. 1792-1796, 20140901
  388. Synthesis and Thermal, Mechanical, and Optical Properties of A-B-A or A-B Block Copolymers Containing Poly(norbornene-co-1-octene), JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 52巻, 2号, pp. 267-271, 20140215
  389. Synthesis of Biodegradable Thermoplastic Elastomers from epsilon-Caprolactone and Lactide, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 53巻, 3号, pp. 489-495, 20150201
  390. Ethylene-Propylene Copolymerization Behavior of ansa-Dimethylsilylene(fluorenyl)(amido)dimethyltitanium Complex: Application to Ethylene-Propylene-Diene or Ethylene-Propylene-Norbornene Terpolymers, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 53巻, 5号, pp. 685-691, 20150301
  391. Synthesis and application of alpha-diimine Ni(II) and Pd(II) complexes with bulky steric groups to polymerization of ethylene and methyl methacrylate, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 398巻, pp. 231-240, 20150301
  392. Pseudo-living copolymerization of norbornene and omega-alkenylborane - Synthesis of monodisperse functionalized cycloolefin copolymer, POLYMER, 56巻, pp. 218-222, 20150115
  393. Synthesis of polystyrene-grafted cycloolefin copolymer, POLYMER, 70巻, pp. 252-256, 20150723
  394. 新規含ホウ素アルミニウム錯体の合成とオレフィン重合触媒としての応用, 次世代ポリオレフィン総合研究, 8巻, pp. 59-62, 20141129
  395. 縄文の炎・藤沢野焼祭, ペトロテック, 38巻, 10号, pp. 713-713, 20151001
  396. Stereospecific Ring-Opening Metathesis Polymerization of Norbornene Catalyzed by Ruthenium and Osmium Complexes with Chelating Hetero-Donor Ligands, KOBUNSHI RONBUNSHU, 72巻, 7号, pp. 460-467, 20150724
  397. Room-temperature Suzuki-Miyaura cross-coupling reaction with alpha-diimine Pd(II) catalysts, APPLIED ORGANOMETALLIC CHEMISTRY, 29巻, 11号, pp. 771-776, 20151101
  398. Highly soluble polynorbornene prepared by an anilinonaphthoquinone-ligated nickel complex via coordination-insertion polymerization, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 798巻, pp. 384-387, 20151201
  399. The preparation of boron-containing aluminoxanes and their application as cocatalysts in the polymerization of olefins, POLYMER JOURNAL, 48巻, 1号, pp. 67-71, 20160101
  400. Structure-stereospecificity relationships of propylene polymerization using substituted ansa-silylene(fluorenyl)(amido) titanium complexes, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 804巻, pp. 95-100, 20160215
  401. Synthesis of stereodiblock polyisoprene consisting of cis-1,4 and trans-1,4 sequences by using a neodymium catalyst: change of the stereospecificity triggered by an aluminum compound, POLYMER CHEMISTRY, 7巻, 6号, pp. 1239-1243, 20160221
  402. Facile Synthesis of Novel Polyethylene-Based A-B-C Block Copolymers Containing Poly(methyl methacrylate) Using a Living Polymerization System, MACROMOLECULAR RAPID COMMUNICATIONS, 37巻, 3号, pp. 227-231, 20160201
  403. Synthesis of Highly Branched Polyolefins Using Phenyl Substituted alpha-Diimine Ni(II) Catalysts, POLYMERS, 8巻, 4号, 20160401
  404. 化学教育徒然草-生長と成長-, 化学と教育, 64巻, 6号, pp. 1-1, 20160620
  405. オレフィンと13族アルケニル化合物の共重合による官能基化ポリオレフィンの合成, 触媒, 58巻, 1号, pp. 27-31, 20160101
  406. 計算化学的手法によるフルオレニルアミドチタン錯体を用いたプロピレン重合の機構解析, 次世代ポリオレフィン総合研究, 9巻, pp. 27-30, 20151125
  407. Effects of supercritical carbon dioxide treatment on the morphology of poly(l-lactide), JOURNAL OF APPLIED POLYMER SCIENCE, 133巻, 39号, 20161015
  408. Precision Chain-Walking Polymerization of trans-4-Octene Catalyzed by -Diimine Nickel(II) Catalysts Bearing ortho-sec-Phenethyl Groups, MACROMOLECULAR RAPID COMMUNICATIONS, 37巻, 16号, pp. 1375-1381, 201608
  409. Theoretical investigation of the mechanism of syndiospecific propylene polymerization using ansa-dimethylsilylene(fluorenyl)(amido)titanium complexes, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 823巻, pp. 112-115, 20161115
  410. Controlled Ring-Opening Polymerization of L-Lactide and epsilon-Caprolactone Catalyzed by Aluminum-Based Lewis Pairs or Lewis Acid Alone, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 55巻, 2号, pp. 297-303, 201701
  411. Enzymatic degradation of poly(L-lactide) treated with supercritical carbon dioxide, POLYMER DEGRADATION AND STABILITY, 134巻, pp. 366-375, 201612
  412. Synthesis of Hydroxy-Functionalized Cyclic Olefin Copolymer and Its Block Copolymers with Semicrystalline Polyolefin Segments, MACROMOLECULAR RAPID COMMUNICATIONS, 38巻, 7号, 201704
  413. Synthesis of highly thermostable norbornene-isoprene-1-octene terpolymer with titanium catalyst, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 55巻, 13号, pp. 2136-2140, 20170701
  414. Living Polymerization of Propylene with ansa-Dimethylsilylene(fluorenyl)(cumylamido) Titanium Complexes, POLYMERS, 9巻, 4号, 201704
  415. Synthesis and Biodegradation of Poly(l-lactide-co-beta-propiolactone), INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 18巻, 6号, 201706
  416. Effect of end-group modification of poly(lactide)s by cinnamoyl chloride on their thermal stability, POLYMER DEGRADATION AND STABILITY, 141巻, pp. 97-103, 201707
  417. Quasi-Living Polymerization of Propene with an Isotactic-Specific Zirconocene Catalyst, MOLECULES, 22巻, 5号, 201705
  418. An Alternative Method for the Preparation of Trialkylaluminum-Depleted Modified Methylaluminoxane (dMMAO), MACROMOLECULES, 50巻, 15号, pp. 5989-5993, 20170808
  419. Living polymerization of higher 2-alkene with alpha-diimine nickel catalysts: Synthesis and characterization of high molecular weight poly(2-alkene)s, POLYMER, 127巻, pp. 88-100, 20171003
  420. Synthesis of Stereodiblock Polybutadiene Using Cp*Nd(BH4)(2)(thf)(2) as a Catalyst, CATALYSTS, 7巻, 10号, 201710
  421. Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex, POLYMERS, 9巻, 11号, 201711
  422. Highly Robust Nickel Catalysts Containing Anilinonaphthoquinone Ligand for Copolymerization of Ethylene and Polar Monomers, MACROMOLECULES, 50巻, 23号, pp. 9216-9221, 20171212
  423. Selective synthesis of highly soluble cyclic olefin copolymers with pendant vinyl groups using 1,5-hexadiene as a comonomer, POLYMER, 136巻, pp. 109-113, 20180131
  424. Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts with Low Load of Methylaluminoxane for Syndiotactic-Specific Living Polymerization of Propylene, ORGANOMETALLICS, 36巻, 16号, pp. 3009-3012, 20170828
  425. Chain-Walking Polymerization of Linear Internal Octenes Catalyzed by alpha-Diimine Nickel Complexes, ORGANOMETALLICS, 37巻, 9号, pp. 1358-1367, 20180514
  426. Reversible star assembly of polyolefins using interconversion between boroxine and boronic acid, POLYMER CHEMISTRY, 9巻, 27号, pp. 3774-3779, 20180721
  427. Efficient control of ethylene-norbornene copolymerization behavior of a fluorenylamido-ligated titanium complex: substituent effects of the amido ligand and copolymer properties, POLYMER CHEMISTRY, 9巻, 35号, pp. 4492-4497, 20180921
  428. Efficient ethylene copolymerization with polar monomers using palladium anilinonaphthoquinone catalysts, POLYMER CHEMISTRY, 9巻, 45号, pp. 5476-5482, 20181207
  429. Effect of Added Phenols and Silanol on the Cocatalyst Activity of Methylaluminoxane, KOBUNSHI RONBUNSHU, 75巻, 6号, pp. 551-556, 2018
  430. Synthesis of ansa-Fluorenylamidotitanium(tetrahydrofuran) Complex and Its Catalytic Ability for Polymerization of Olefins, KOBUNSHI RONBUNSHU, 75巻, 6号, pp. 564-569, 2018
  431. Synthesis and Properties of Stereoblock Copolymers Composed of Lactide and epsilon-Caprolactone, KOBUNSHI RONBUNSHU, 76巻, 1号, pp. 61-67, 2019
  432. Optically Transparent Functional Polyolefin Elastomer with Excellent Mechanical and Thermal Properties, ACS MACRO LETTERS, 8巻, 3号, pp. 299-303, 201903
  433. Cis-1,4 Specific Polymerization of 1,3-Butadiene Using PNP-pincer Ligated Iron(II) Complexes, CHEMISTRY LETTERS, 48巻, 6号, pp. 525-528, 201906
  434. Preparation of Methylaluminoxane from CO2 and Me3Al, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 18号, pp. 2392-2395, 20190515
  435. Stereospecific polymerization of conjugated dienes using neodymium alkylborohydride complexes, DALTON TRANSACTIONS, 48巻, 21号, pp. 7267-7273, 20190607
  436. 重合技術によるポリプロピレンの高性能化・高機能化, ファインケミカル, 48巻, 6号, pp. 15-32, 20190615
  437. Copolymerization of Norbornene and Styrene with Anilinonaphthoquinone-Ligated Nickel Complexes, POLYMERS, 11巻, 7号, 201907
  438. ★, Effect of the number of arms on the mechanical properties of a star-shaped cyclic olefin copolymer, POLYMER CHEMISTRY, 10巻, 41号, pp. 5578-5583, 20191107
  439. Impregnation of poly(L-lactide-ran-delta-valerolactone) with essential bark oil using supercritical carbon dioxide, SCIENTIFIC REPORTS, 9巻, 20191108
  440. Copolymerization of Ethylene and Fluoroalkylnorbornene Using Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts, MACROMOLECULAR CHEMISTRY AND PHYSICS, 220巻, 19号, 201910
  441. Chain-walking polymerization of 3-heptene with phenyl substituted alpha-diimine nickel catalysts, POLYMER, 181巻, 20191024
  442. Copolymerization of norbornene and conjugated dienes using anilinonaphthoquinone-ligated nickel complexes, POLYMER, 187巻, 202001
  443. Crystal structure of di-mu-trihydro(pentafluorophenyl)borato-tetrakis(tetrahydrofuran)disodium, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 76巻, pp. 145-+, 202002
  444. Coordination-Insertion Copolymerization of Norbornene and p-Substituted Styrenes Using Anilinonaphthoquinone-Ligated Nickel Complexes, MACROMOLECULAR CHEMISTRY AND PHYSICS, 221巻, 5号, 202003
  445. Synthesis, properties and biodegradation of periodic copolyesters composed of hydroxy acids, ethylene glycol, and terephthalic acid, POLYMER DEGRADATION AND STABILITY, 174巻, 202004
  446. Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization, ORGANOMETALLICS, 39巻, 10号, pp. 1855-1860, 20200526
  447. ★, Synthesis and Properties of Gradient Copolymers Composed of Norbornene and Higher alpha-Olefins Using an ansa-Fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)(4)] Catalyst System, MACROMOLECULES, 53巻, 11号, pp. 4323-4329, 20200609
  448. High Activity of Rare Earth Tetrahydroborates for Ring-Opening Polymerization of omega-Pentadecalactone, JOURNAL OF APPLIED POLYMER SCIENCE, 121巻, 4号, pp. 2098-2103, 2011
  449. 架橋型ジアミドジメチルチタン錯体-アルミノキサン触媒系によるプロピレンのリビング重合, 触媒, 44巻, 6号, pp. 429-431, 20020910
  450. アゾベンゼン液晶エラストマーの光屈曲:ホメオトロピック配向フィルムの光応答性, 日本液晶学会討論会講演予稿集, 2004巻, 0号, pp. 107-107, 2004
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著書等出版物

  1. 2016年03月10日, 精密重合が拓く高分子合成-高度な制御と進む実用化-, 精密重合が拓く高分子合成-高度な制御と進む実用化-, 2016年03月, 2016, 単行本(学術書), 共著, 日本語, 塩野 毅, ISBN978-4-7598-1380-7, 198, 90-95
  2. 2016年03月, 日本の高分子科学技術史第2巻, 高分子学会, 2016年, 03, 単行本(学術書), 共著, 日本語, 塩野 毅, 252, 20-22
  3. 2015年, Coordination Polymerization (Styrene and Polar Vinyl Monomers), 2015年, 単行本(学術書), 共著, English, 978-3-642-29647-5, 2672, 474-480
  4. 2015年, 2015年, 単行本(学術書), 共著, English, 978-3-642-29647-5, 2672, 469-474
  5. 2014年04月, Springer, 2014年, 4, 教科書, 共著, 英語, ISBN 978-3-662-43538-0, 301, 1-49
  6. 2013年03月, 高分子基礎科学 One Point 2,精密重合II:イオン・配位・開環・逐次重合, 共立出版, 2013年, 03, 共編著
  7. 2011年04月, 触媒調製ハンドブック, エヌ・ティー・エス, 2011年, 04, 共編著
  8. 2010年11月, Taylor and Francis, Inc., 2010年, 11, 調査報告書, 監修
  9. 2010年11月, 2010年, 11, 調査報告書, 監修
  10. 2010年11月, 2010年, 11, 調査報告書, 監修
  11. 2010年11月, 2010年, 11, 調査報告書, 監修
  12. 2010年04月, 高分子の合成(下), 講談社, 2010年, 04, 共編著
  13. 2008年12月, 触媒便覧“18.1 重合反応”, 講談社サイエンティフィク, 2008年, 12, 共編著
  14. 2006年01月, 実験化学講座28 触媒 , 丸善, 2006年, 01, 教科書, 共編著, 日本化学会編 塩野 毅 , 413
  15. 2005年06月, 高分子辞典第3版 , 朝倉書店, 2005年, 06, 事典・辞書, 共編著, 高分子学会編 塩野 毅 , 830
  16. 2005年03月, 実験化学講座26 高分子化学 , 丸善, 2005年, 03, 教科書, 共編著, 日本化学会編 塩野 毅 , 485
  17. 2004年12月, 触媒活用大辞典 , 工業調査会, 2004年, 12, 事典・辞書, 共編著, 触媒活用大辞典編集委員会編 塩野 毅 , 1134
  18. 2004年03月, 有機合成のための触媒反応103 , 東京化学同人, 2004年, 03, 教科書, 共編著, 檜山為次郎 野崎京子編 塩野 毅 , 215
  19. 2003年01月, “Product class 10: organometallic complexes of titanium” , Science of Synthesis, 2003年, 単行本(学術書), 共著, k.mikami y.matsumoto 塩野 毅
  20. 2000年01月, 触媒の辞典 , 朝倉書店, 2000年, 事典・辞書, 共編著, 小野嘉夫 御園生誠 諸岡良彦編集 塩野 毅
  21. 1995年01月, 新高分子実験学2 高分子の合成・反応(1)付加系高分子の合成 , 共立出版, 1995年, 教科書, 共編著, 高分子学会編 塩野 毅
  22. 1992年05月, 実験化学講座28高分子合成 , 丸善, 1992年, 05, 教科書, 共編著, 塩野 毅 , 487
  23. 2018年07月31日, 高耐熱樹脂の開発事例集, 第10章 4節:錯体触媒によるポリオレフィンの精密合成と耐熱性向上, 技術情報協会, 2018年, 201807, 単行本(学術書), 共著, Japanese, 塩野毅,田中亮, ISBN978-4-86104-720-6 C3058, 529, 241-257
  24. 2016年06月30日, ポリプロピレンの構造制御と複合化、成形加工技術, 第1章 1節:ポリプロピレンの精密合成, 技術情報協会, 2016年, 06, 単行本(学術書), 共著, Japanese, 田中亮, 塩野毅, 414, 3-11
  25. 2018年10月31日, ブロック共重合体の構造制御と応用展開, 第10章 配位重合によるオレフィンブロック共重合体の合成, 配位重合 ポリオレフィン ブロック共重合体, シーエムシー出版, 2018年, 10, 単行本(学術書), 共著, 日本語, 塩野毅,田中亮, 978-4-7813-1351-1, 240, 141-156
  26. 2018年12月17日, 次世代ポリオレフィン総合研究Vol.12, 末端ボロン酸修飾を用いた星型ポリオレフィンの合成, 末端ボロン酸修飾 星型ポリマー ポリオレフィン, 三恵社, 2018年, 12, 単行本(学術書), 共著, 日本語, 田中亮, 渡子直紀, 中山祐正, 塩野毅, 9784864879750, 186, 55-58
  27. 2019年02月28日, 次世代のポリマー・高分子開発,新しい用途展開と将来展望, 配位重合によるステレオブロックポリマーの合成とその性質, 配位重合 ステレオブロックポリマー 合成 性質, 技術情報協会, 2019年, 2, 単行本(学術書), 共著, 日本語, 田中亮, 塩野毅, 978-4-86104-738-1, 608, 426-423

招待講演、口頭・ポスター発表等

  1. 環境を考慮した近未来の高分子材料, 塩野毅, 第67回高分子討論会, 2018年09月13日, 招待, 日本語, 高分子学会, 北海道大学,札幌

社会活動

委員会等委員歴

  1. 理事, 2018年06月, 2020年05月, 高分子学会