津野地 直NAO TSUNOJI

Last Updated :2021/10/07

所属・職名
大学院先進理工系科学研究科 助教
ホームページ
メールアドレス
tnao7373hiroshima-u.ac.jp
自己紹介
構造中に分子大の空間を持っているナノ空間材料(ゼオライト、メソポーラスシリカ、層状ケイ酸塩)の精密合成を行っています。また、それら材料を用いて二酸化炭素削減、環境・エネルギー対策に有効な技術開発を進めています。

基本情報

主な職歴

  • 2013年04月01日, 2015年03月31日, 日本学術振興会, 日本学術振興会特別研究員(DC1)

学歴

  • 広島大学, 工学研究科, 応用科学専攻, 日本, 2013年04月, 2015年03月

学位

  • 博士(工学) (広島大学)
  • 修士(工学) (広島大学)

教育担当

  • 【学士課程】 工学部 : 第三類(応用化学・生物工学・化学工学系) : 応用化学プログラム
  • 【博士課程前期】 先進理工系科学研究科 : 先進理工系科学専攻 : 応用化学プログラム
  • 【博士課程前期】 先進理工系科学研究科 : 先進理工系科学専攻 : スマートイノベーションプログラム
  • 【博士課程後期】 先進理工系科学研究科 : 先進理工系科学専攻 : 応用化学プログラム
  • 【博士課程後期】 先進理工系科学研究科 : 先進理工系科学専攻 : スマートイノベーションプログラム

研究分野

  • 工学 / プロセス・化学工学 / 触媒・資源化学プロセス
  • 化学 / 材料化学 / 無機工業材料

研究キーワード

  • 多孔体
  • 層状・層間化合物
  • セラミックス
  • 触媒
  • ゼオライト
  • 層状ケイ酸塩
  • メソポーラスシリカ

所属学会

教育活動

授業担当

  1. 2021年, 学部専門, 4ターム, 物理化学演習
  2. 2021年, 学部専門, セメスター(後期), 化学実験II
  3. 2021年, 修士課程・博士課程前期, 1ターム, 応用化学特別演習A
  4. 2021年, 修士課程・博士課程前期, 2ターム, 応用化学特別演習A
  5. 2021年, 修士課程・博士課程前期, 3ターム, 応用化学特別演習A
  6. 2021年, 修士課程・博士課程前期, 4ターム, 応用化学特別演習A
  7. 2021年, 修士課程・博士課程前期, 3ターム, 応用化学特別演習B
  8. 2021年, 修士課程・博士課程前期, 4ターム, 応用化学特別演習B
  9. 2021年, 修士課程・博士課程前期, 1ターム, 応用化学特別演習B
  10. 2021年, 修士課程・博士課程前期, 2ターム, 応用化学特別演習B
  11. 2021年, 修士課程・博士課程前期, 年度, 応用化学特別研究
  12. 2021年, 修士課程・博士課程前期, 年度, 応用化学特別研究
  13. 2021年, 博士課程・博士課程後期, 年度, 応用化学特別研究

研究活動

学術論文(★は代表的な論文)

  1. Synthesis of high-silica AEI zeolites with enhanced thermal stability by hydrothermal conversion of FAU zeolites, J. Mater. Chem. A, 3巻, pp. 857-865, 20141113
  2. Incorporation of heteropolyacids into layered silicate HUS-2 grafted with 3-aminopropyltriethoxysilane, Bull. Chem. Soc. Jpn., 87巻, pp. 1379-1385, 20140901
  3. Regeneration of Br?nsted acid sites in phosphorus-modified HZSM-5(Ga) by modification with various metal cations, Appl. Catal. A, 481巻, pp. 161-168, 20140527
  4. Design of Layered Silicate by Grafting with Metal Acetylacetonate for High Activity and Chemoselectivity in Photooxidation of Cyclohexane, Appl. Mater. Interfaces, 6巻, pp. 4616-4621, 20140511
  5. Synthesis and characteristics of novel layered silicate HUS-7 using benzyltrimethylammonium hydroxide and its unique and selective phenol adsorption behavior, J. Mater. Chem. A, 2巻, pp. 3372-3380, 20131219
  6. An Efficient Way to Synthesize Hiroshima University Silicate-1 (HUS-1) and the Selective Adsorption Property of Ni2+ from Seawater, Bull. Chem. Soc. Jpn., 1巻, pp. 160-166, 20140115
  7. Facile Synthesis of AEI Zeolite by Hydrothermal Conversion of FAU Zeolite in the Presence of Tetraethylphosphonium Cations, Chem. Lett., 43巻, pp. 302-304, 20131112
  8. Characterization of layered silicate HUS-5 and formation of novel nanoporous silica through transformation of HUS-5 ion-exchanged with alkylammonium cations, J. Mater. Chem. A, 1巻, pp. 9680-9688, 2013
  9. Molecular Recognitive Adsorption of Aqueous Propionic Acid on Hiroshima University Silicate-2 (HUS-2), Chem. Lett., 42巻, pp. 244-246, 2013
  10. Conversion of ethanol into propylene over TON type zeolite, J. Jpn. Petrol. Inst., 56巻, pp. 22-30, 2013
  11. Molecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent, Chem. Commun., 48巻, 7073号, pp. 7075, 2012
  12. Synthesis and characteristics of novel layered silicates HUS-2 and HUS-3 derived from a SiO2-choline hydroxide-NaOH-H2O system, J. Mater. Chem., 22巻, pp. 13682-13690, 2012
  13. Conversion of ethanol to propylene over HZSM-5(Ga) co-modified with lanthanum and phosphorous, Appl. Catal. A, 399巻, pp. 262-267, 2012
  14. Effect of acidity of ZSM-5 zeolite on conversion of ethanol to propylene, Appl. Catal. A, 399巻, pp. 262-267, 2011
  15. Highly active and selective Ti-incorporated porous silica catalysts derived from grafting of titanium(IV)acetylacetonate, JOURNAL OF MATERIALS CHEMISTRY A, 3巻, 29号, pp. 15280-15291, 20150626
  16. Synthesis of titanated chabazite with enhanced thermal stability by hydrothermal conversion of titanated faujasite, Microporous Mesoporous Mater, 215巻, pp. 58-66, 20150519
  17. Design of Microporous Material HUS-10 with Tunable Hydrophilicity, Molecular Sieving, and CO2 Adsorption Ability Derived from Inter layer Silylation of Layered Silicate HUS-2, ACS APPLIED MATERIALS & INTERFACES, 7巻, 43号, pp. 24360-24369, 20151104
  18. One-pot Synthesis of Phosphorus-modified AEI Zeolites Derived by the Dual-template Method as a Durable Catalyst with Enhanced Thermal/Hydrothermal Stability for Selective Catalytic Reduction of NOx by NH3, CHEMISTRY LETTERS, 45巻, 2号, pp. 122-124, 20160205
  19. Remarkable Charge Separation and Photocatalytic Efficiency Enhancement through Interconnection of TiO2 Nanoparticles by Hydrothermal Treatment, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55巻, 11号, pp. 3600-3605, 20160307
  20. Synthesis of phosphorus-modified small-pore zeolites utilizing tetraalkyl phosphonium cations as both structure-directing and phosphorous modification agents, MICROPOROUS AND MESOPOROUS MATERIALS, 223巻, pp. 129-139, 20160315
  21. Nanosized CHA zeolites with high thermal and hydrothermal stability derived from the hydrothermal conversion of FAU zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 225巻, pp. 524-533, 20160501
  22. Selective catechol synthesis by TiO2 photocatalysis with the aid of a layered silicate adsorbent, CLAY SCIENCE, 19巻, pp. 56-62, 2015
  23. A BODIPY sensor for water based on a photo-induced electron transfer method with fluorescence enhancement and attenuation systems, NEW JOURNAL OF CHEMISTRY, 40巻, 9号, pp. 7278-7281, 2016
  24. Encapsulation of Two Potassium Cations in Preyssler-Type Phosphotungstates: Preparation, Structural Characterization, Thermal Stability, Activity as an Acid Catalyst, and HAADF-STEM Images, INORGANIC CHEMISTRY, 55巻, 21号, pp. 11583-11592, 20161107
  25. Fe oxide nanoparticles/Ti-modified mesoporous silica as a photo-catalyst for efficient and selective cyclohexane conversion with O-2 and solar light, JOURNAL OF MATERIALS CHEMISTRY A, 4巻, 41号, pp. 15829-15835, 2016
  26. Synthesis of epsilon-Keggin-Type Cobaltomolybdate-Based 3D Framework Material and Characterization Using Atomic-Scale HAADF-STEM and XANES, INORGANIC CHEMISTRY, 56巻, 4号, pp. 2042-2049, 20170220
  27. Mesoporous MCM-48 Immobilized with Aminopropyltriethoxysilane: A Potential Catalyst for Transesterification of Triacetin, CATALYSIS LETTERS, 147巻, 4号, pp. 1040-1050, 201704
  28. Incorporation of various heterometal atoms in CHA zeolites by hydrothermal conversion of FAU zeolite and their performance for selective catalytic reduction of NOx with ammonia, MICROPOROUS AND MESOPOROUS MATERIALS, 246巻, pp. 89-101, 20170701
  29. Aggregation-induced emission (AIE) characteristic of water-soluble tetraphenylethene (TPE) bearing four sulfonate salts, NEW JOURNAL OF CHEMISTRY, 41巻, 12号, pp. 4747-4749, 20170621
  30. Design of a highly active base catalyst through utilizing organic-solvent-treated layered silicate Hiroshima University Silicates, DALTON TRANSACTIONS, 46巻, 23号, pp. 7441-7450, 20170621
  31. Hydrothermal Conversion of Titanated FAU to AEI Zeolite and Its Enhanced Catalytic Performance for NOx Reduction, Adv. Porous Mater., 4巻, 1号, pp. 62-72, 2016
  32. Development of a Dual-Fluorescence Emission Sensor Based on Photo-Induced Electron Transfer and Aggregation-Induced Emission Enhancement for Detection of Water, CHEMISTRYSELECT, 2巻, 26号, pp. 7765-7770, 20170911
  33. Thermally stable nanosized LEV zeolites synthesized by hydrothermal conversion of FAU zeolites in the presence of N,N-dimethylpiperidinium cations, JOURNAL OF MATERIALS CHEMISTRY A, 5巻, 36号, pp. 19245-19254, 20170928
  34. Thiourea bridged periodic mesoporous organosilica with ultra-small Pd nanoparticles for coupling reactions, RSC ADVANCES, 7巻, 89号, pp. 56306-56310, 2017
  35. A Collective Case Screening of the Zeolites made in Japan for High Performance NH3-SCR of NOx, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 91巻, 3号, pp. 355-361, 201803
  36. Templated synthesis of atomically thin platy hematite nanoparticles within a layered silicate exhibiting efficient photocatalytic activity, JOURNAL OF MATERIALS CHEMISTRY A, 6巻, 12号, pp. 5166-5171, 20180328
  37. Preparation of Preyssler-type Phosphotungstate with One Central Potassium Cation and Potassium Cation Migration into the Preyssler Molecule to form Di-Potassium-Encapsulated Derivative, ACS OMEGA, 3巻, 2号, pp. 2363-2373, 201802
  38. Reactivity of a (Benzene)Ruthenium(II) Cation on a Di-lacunary -Keggin-Type Silicotungstate and Synthesis of a Mono-(Benzene)Ruthenium(II)-Attached -Keggin-Type Silicotungstate, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 17号, pp. 1778-1786, 20180508
  39. Synthesis of phosphorus-modified AFX zeolite using a dual-template method with tetraethylphosphonium hydroxide as phosphorus modification agent, MICROPOROUS AND MESOPOROUS MATERIALS, 267巻, pp. 192-197, 20180901
  40. Templated synthesis of atomically-thin Ag nanocrystal catalysts in the interstitial space of a layered silicate, CHEMICAL COMMUNICATIONS, 54巻, 35号, pp. 4402-4405, 20180428
  41. Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface, CHEMCATCHEM, 10巻, 12号, pp. 2536-2540, 20180621
  42. Stepwise Gel Preparation for High-Quality CHA Zeolite Synthesis: A Common Tool for Synthesis Diversification, CRYSTAL GROWTH & DESIGN, 18巻, 9号, pp. 5652-5662, 201809
  43. Tetraphenylethene- and diphenyldibenzofulvene-anthracene- based fluorescence sensors possessing photo-induced electron transfer and aggregation-induced emission enhancement characteristics for detection of water, NEW JOURNAL OF CHEMISTRY, 42巻, 16号, pp. 13339-13350, 20180821
  44. Iron Aquo Complex as an Efficient and Selective Homogeneous Photocatalyst for Organic Synthetic Reactions, CHEMCATCHEM, 10巻, 20号, pp. 4509-4513, 20181023
  45. Facile synthesis of highly crystalline EMT zeolite by hydrothermal conversion of FAU zeolite in the presence of 1,1'-(1,4-butanediyl)bis(1-azonia-4-azabicyclo [2,2,2]octane) dihydroxide, MICROPOROUS AND MESOPOROUS MATERIALS, 274巻, pp. 299-303, 20190115
  46. Zeolitic intralayer microchannels of magadiite, a natural layered silicate, to boost green organic synthesis, CHEMICAL SCIENCE, 9巻, 46号, 20181214
  47. Comparative study between high-silica faujasites (FAU) from organic-free system and the commercial zeolite Y, MICROPOROUS AND MESOPOROUS MATERIALS, 276巻, pp. 154-159, 20190301
  48. A Sandwich Complex of Bismuth Cation and Mono-Lacunary alpha-Keggin-Type Phosphotungstate: Preparation and Structural Characterisation, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 3-4号, pp. 357-362, 20190131
  49. Zeolite hydrothermal conversion in the presence of various cyclic alkylammonium cations and synthesis of nanosized BEA and MFI zeolites, MICROPOROUS AND MESOPOROUS MATERIALS, 277巻, pp. 115-123, 20190315
  50. Comparison of sulfonic acid loaded mesoporous silica in transesterification of triacetin, REACTION KINETICS MECHANISMS AND CATALYSIS, 126巻, 1号, pp. 167-179, 201902
  51. Phosphorus modified small-pore zeolites and their catalytic performances in ethanol conversion and NH3-SCR reactions, APPLIED CATALYSIS A-GENERAL, 575巻, pp. 204-213, 20190405
  52. Microporous materials formed via intercalation of ultrathin coordination polymers in a layered silicate, NANO ENERGY, 59巻, pp. 162-168, 201905
  53. Hydrothermal Conversion of Titanated FAU to AEI Zeolite and Its Enhanced Catalytic Performance for NOx Reduction, ADVANCED POROUS MATERIALS, 4巻, 1号, pp. 62-72, 201606
  54. Photocatalytic Activation of C-H Bonds by Spatially Controlled Chlorine and Titanium on the Silicate Layer, ACS CATALYSIS, 9巻, 6号, pp. 5742-5751, 201906
  55. Condensed ferric dimers for green photocatalytic synthesis of nylon precursors, CHEMICAL SCIENCE, 10巻, 27号, pp. 6604-6611, 20190721
  56. Synthesis of GME zeolite with high porosity by hydrothermal conversion of FAU zeolite using a dual-template method with tetraethylphosphonium and N,N-dimethyl-3,5-dimethylpiepridinium hydroxides, JOURNAL OF POROUS MATERIALS, 26巻, 5号, pp. 1345-1352, 201910
  57. Immobilizaion of Preyssler type heteropoly acids on siliceous mesporous supports and their catalytic activities in the dehydration of ethanol, REACTION KINETICS MECHANISMS AND CATALYSIS, 128巻, 1号, pp. 139-147, 201910
  58. Formation Pathway of AEI Zeolites as a Basis for a Streamlined Synthesis, CHEMISTRY OF MATERIALS, 32巻, 1号, pp. 60-74, 20200114
  59. Theoretical study on P-31 NMR chemical shifts of phosphorus-modified CHA zeolites, MICROPOROUS AND MESOPOROUS MATERIALS, 294巻, 20200301
  60. Merging periodic mesoporous organosilica (PMO) with mesoporous aluminosilica (Al/Si-PMO): A catalyst for green oxidation, MOLECULAR CATALYSIS, 482巻, 202002
  61. Synthesis of Preyssler-Type Phosphotungstate with Sodium Cation in the Central Cavity through Migration of the Ion, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 93巻, 3号, pp. 461-466, 202003
  62. In Situ Spectroscopic Studies on the Redox Cycle of NH3-SCR over Cu-CHA Zeolites, CHEMCATCHEM, 12巻, 11号, pp. 3050-3059, 20200605
  63. ★, High-quality synthesis of a nanosized CHA zeolite by a combination of a starting FAU zeolite and aluminum sources, DALTON TRANSACTIONS, 49巻, 29号, pp. 9972-9982, 20200807
  64. ★, Triple-template system for phosphorus-modified AFX/CHA intergrowth zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 309巻, 20201215
  65. ★, Synthesis of Phosphorus-Modified AFX Zeolite by the Hydrothermal Conversion of Tetraalkylphosphonium Hydroxide-Impregnated FAU Zeolite, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 94巻, 1号, pp. 1-7, 202101
  66. AFX Zeolite for Use as a Support of NH3-SCR Catalyst Mining through AICE Joint Research Project of Industries-Academia-Academia, CATALYSTS, 11巻, 2号, 202102
  67. Exceptionally stable green rust, a mixed-valent iron-layered double hydroxide, as an efficient solar photocatalyst for H-2 production from ammonia borane, APPLIED CATALYSIS B-ENVIRONMENTAL, 286巻, 20210605
  68. Nitrogen doping-mediated oxygen vacancies enhancing co-catalyst-free solar photocatalytic H-2 production activity in anatase TiO2 nanosheet assembly, APPLIED CATALYSIS B-ENVIRONMENTAL, 285巻, 20210515
  69. Fluorescence sensors for detection of water based on tetraphenylethene-anthracene possessing both solvatofluorochromic properties and aggregation-induced emission (AIE) characteristics, NEW JOURNAL OF CHEMISTRY, 45巻, 9号, 20210307
  70. Bispropylurea bridged polysilsesquioxane: A microporous MOF-like material for molecular recognition, CHEMOSPHERE, 276巻, 202108
  71. ★, Controlling hydrocarbon oligomerization in phosphorus-modified CHA zeolite for a long-lived methanol-to-olefin catalyst, APPLIED CATALYSIS A-GENERAL, 620巻, 20210625
  72. Complexation of B(C6F5)(3) and 9,10-Dicyanoanthracene: Dual Role of Borane as Spatial and Electronic Tuner, CHEMISTRY LETTERS, 49巻, 9号, pp. 1022-1025, 202009
  73. ★, Multiple templating strategy for the control of aluminum and phosphorus distributions in AFX zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 321巻, 202107
  74. ★, In situ/operando spectroscopic studies on NH3–SCR reactions catalyzed by a phosphorus-modified Cu-CHA zeolite, Catal. Today, 376巻, pp. 73-80, 202004
  75. Post-synthetic amine functionalized SAPO-5 & SAPO-34 molecular sieves for epoxide ring opening reactions, Mater. Today: Proc., 45巻, 3号, pp. 3726-3732, 202004

著書等出版物

  1. 2013年, 工業材料, ゼオライト前駆体としての新規層状ケイ酸塩HUS-nの合成とその特性 (特集 我が国で発展を遂げるゼオライトの利活用の新段階), 日刊工業出版プロダクション, 2013年, 単行本(学術書), 共著, Japanese, 津野地直、井出裕介、定金正洋、佐野庸治
  2. 2015年11月20日, 高機能ゼオライトの最新技術:ゼオライト水熱転換によるゼオライトの合成と応用, 2015年, 11, 津野地直、佐野庸治
  3. 2015年12月01日, ゼオライト, 新規層状ケイ酸塩HUSsを活用した吸着剤,多孔体および触媒の設計, 2015年, 12, 津野地直、佐野庸治
  4. 2016年12月08日, ナノ空間材料ハンドブック, ゼオライト水熱転換, 共著
  5. 2018年10月, 進化するゼオライト合成, 触媒 = Catalysts & catalysis, 佐野 庸治;津野地 直
  6. 2018年09月, リン修飾小細孔ゼオライトの合成とNH₃-SCR触媒特性, ゼオライト = Zeolite, 2018年, 10, 津野地 直;佐野 庸治
  7. 2018年10月, 触媒(Catalysts and Catalysis), 進化するゼオライト合成, 2018年, 10

受賞

  1. 2021年07月, 8th Conference of the Federation of European Zeolite Associations (FEZA 2021 Virtual), Poster Prizes, Federation of European Zeolite Associations, Phosphorus modification into various small-pore zeolites for improvement of catalytic durability in ethanol conversion and NH3-SCR reactions
  2. 2019年04月09日, 日本化学会 第99春季年会(2019)優秀講演賞(学術), 公益社団法人日本化学会会長
  3. 2019年10月31日, JPIJS(石油学会ジュニア・ソサイアティ) The 49th Petroleum-Petrochemical Symposium of JPI, JPIJS International Session, Best Presentation Award
  4. 2018年12月01日, 第34回ゼオライト研究発表会 若手優秀講演賞, 日本ゼオライト学会
  5. 2013年03月, 日本化学会中国支部支部長賞, 日本化学会

外部資金

競争的資金等の採択状況

  1. 先導研究プログラム 未踏チャレンジ2050, 二酸化炭素回収と資源化の複合化技術開発, 2020年10月, 2025年09月
  2. 科学研究費助成事業(特別研究員奨励費)特別枠, 構造と機能性ユニットとの協奏効果を利用した機能性層状ケイ酸塩の合成, 2013年04月01日, 2015年03月31日
  3. 研究活動スタート支援, 層状ケイ酸塩を利用したゼオライト合成における問題解決, 2015年10月01日, 2017年03月31日
  4. 科学研究費助成事業(若手研究(B)), 層状ケイ酸塩の結晶性表面を活用した高性能触媒反応場の設計, 2017年, 2019年