金指 正言MASAKOTO KANEZASHI

Last Updated :2022/11/17

所属・職名
大学院先進理工系科学研究科 教授
メールアドレス
kanezashihiroshima-u.ac.jp
その他連絡先
東広島市鏡山一丁目4番1号 工学部A4棟312号室
TEL:082-424-2035 FAX:082-424-5494
自己紹介
近年,環境問題や省エネプロセスを実現するために,水素,二酸化炭素などの気体分離,エタノール水溶液からの脱水あるいは脱アルコールなどの液体混合物の分離,濾過分離など,膜分離プロセスが注目されています。私は,多孔性材料をベースにガス分離から液体分離まで分離対象に応じた膜開発と分離特性の評価について研究しています。特にアモルファスシリカを用いたサブナノレベルでの細孔径制御,吸着性制御などマイクロポーラス構造の制御技術を中心に研究を行なっています。

基本情報

主な職歴

  • 2005年10月01日, 2007年09月30日, アリゾナ州立大学, 工学部化学工学科, 博士研究員
  • 2007年10月01日, 2010年03月31日, 広島大学, 大学院工学研究科物質化学システム専攻, 助教
  • 2010年04月01日, 2017年02月28日, 広島大学, 大学院工学研究院物質化学工学部門, 助教
  • 2017年03月01日, 2020年03月31日, 広島大学, 大学院工学研究科化学工学専攻, 准教授
  • 2020年04月01日, 2022年09月30日, 広島大学, 大学院先進理工系科学研究科, 准教授
  • 2022年10月01日, 広島大学, 大学院先進理工系科学研究科, 教授

学位

  • 博士(工学) (広島大学)
  • 修士(工学) (広島大学)

教育担当

  • 【学士課程】 工学部 : 第三類(応用化学・生物工学・化学工学系) : 化学工学プログラム
  • 【博士課程前期】 先進理工系科学研究科 : 先進理工系科学専攻 : 化学工学プログラム
  • 【博士課程後期】 先進理工系科学研究科 : 先進理工系科学専攻 : 化学工学プログラム

研究分野

  • 工学 / プロセス・化学工学 / 化工物性・移動操作・単位操作

研究キーワード

  • ゾル-ゲル法
  • 膜分離工学
  • ガス分離
  • 細孔径制御
  • マイクロポーラス構造制御

所属学会

教育活動

授業担当

  1. 2022年, 学部専門, 1ターム, 工学プログラミング基礎
  2. 2022年, 学部専門, 2ターム, 物理化学I
  3. 2022年, 学部専門, セメスター(後期), 基礎化学実験
  4. 2022年, 学部専門, 2ターム, 応用化学・化学工学・生物工学概論
  5. 2022年, 学部専門, 2ターム, 基礎工業概論
  6. 2022年, 学部専門, セメスター(前期), 化学工学演習II
  7. 2022年, 修士課程・博士課程前期, セメスター(前期), 化学工学特別演習A
  8. 2022年, 修士課程・博士課程前期, 3ターム, 化学工学特別演習B
  9. 2022年, 修士課程・博士課程前期, 4ターム, 化学工学特別演習B
  10. 2022年, 修士課程・博士課程前期, 年度, 化学工学特別研究
  11. 2022年, 修士課程・博士課程前期, 4ターム, Advanced Surface Control Engineering
  12. 2022年, 博士課程・博士課程後期, 年度, 化学工学特別研究

教育に関する受賞

  • 2013年12月12日, 平成25年度広島大学大学院工学研究科・工学部教育顕彰, 広島大学, 第三類基礎化学実験(物理化学実験)における教育と実験環境の改善
  • 2017年11月16日, 平成29年度広島大学大学院工学研究科・工学部教育顕彰, 広島大学, 化学工学プログラミングにおけるテキスト作成とアクティブラーニングの実践

研究活動

学術論文(★は代表的な論文)

  1. Low-temperature cross-linking fabrication of sub-nanoporous SiC-based membranes for application to the pervaporation removal of methanol, JOURNAL OF MEMBRANE SCIENCE, 662巻, 20221015
  2. ★, Tailoring the structure of a sub-nano silica network via fluorine doping to enhance CO2 separation and evaluating CO2 separation performance under dry or wet conditions, JOURNAL OF MEMBRANE SCIENCE, 658巻, 20220915
  3. Transesterification membrane reactor with organosilica membrane in batch and continuous flow modes, CHEMICAL ENGINEERING JOURNAL, 450巻, 20221215
  4. Hydrophilic behavior of methyl-terminated organosilica thin films modified by atmospheric-pressure water vapor plasma, MATERIALS LETTERS, 325巻, 20221015
  5. ★, Design of carbon-ceramic composite membranes with tunable molecular cut-offs from a carboxylic benzoxazine ligand chelated to silica-zirconia, MOLECULAR SYSTEMS DESIGN & ENGINEERING, 7巻, 9号, 20220830
  6. Structural transformation of the nickel coordination-induced subnanoporosity of aminosilica membranes for methanol-selective, high-flux pervaporation, JOURNAL OF MEMBRANE SCIENCE, 656巻, 20220815
  7. Development of robust and high-performance polysilsesquioxane reverse osmosis membranes modified by SiO2 nanoparticles for water desalination, SEPARATION AND PURIFICATION TECHNOLOGY, 296巻, 20220901
  8. Open-air plasma deposition of polymer-supported silica-based membranes for, SEPARATION AND PURIFICATION TECHNOLOGY, 291巻, 20220615
  9. Preparation of amine- and ammonium-containing polysilsesquioxane membranes for CO2 separation, POLYMER JOURNAL, 54巻, 7号, pp. 875-882, 202207
  10. Structural transformation of the nickel coordination-induced subnanoporosity of aminosilica membranes for methanol-selective, high-flux pervaporation, JOURNAL OF MEMBRANE SCIENCE, 656巻, 20220815
  11. Development of Highly Water-Permeable Robust PSQ-Based RO Membranes by Introducing Hydroxyethylurea-Based Hydrophilic Water Channels, ACS APPLIED MATERIALS & INTERFACES, 14巻, 18号, pp. 21426-21435, 20220511
  12. Reverse osmosis and pervaporation of organic liquids using organosilica membranes: Performance analysis and predictions, AICHE JOURNAL, 68巻, 4号, 202204
  13. ★, Effect of fluorine doping on the network pore structure of non-porous organosilica bis(triethoxysilyl)propane (BTESP) membranes for use in molecular separation, JOURNAL OF MEMBRANE SCIENCE, 644巻, 20220215
  14. Network tailoring of organosilica membranes via aluminum doping to improve the humid-gas separation performance, RSC ADVANCES, 12巻, 10号, pp. 5834-5846, 20220216
  15. Development of PSQ-RO membranes with high water permeability by copolymerization of bis[3-(triethoxysilyl)propyl]amine and triethoxy (3-glycidyloxypropyl)silane, JOURNAL OF MEMBRANE SCIENCE, 644巻, 20220215
  16. ★, Boosting the CO2 capture efficiency through aromatic bridged organosilica membranes, JOURNAL OF MEMBRANE SCIENCE, 643巻, 20220301
  17. ★, Enhancement of the H-2-permselectivity of a silica-zirconia composite membrane enabled by ligand-ceramic to carbon-ceramic transformation, JOURNAL OF MEMBRANE SCIENCE, 642巻, 20220215
  18. Structural two-phase evolution of aminosilica-based silver-coordinated membranes for increased hydrogen separation, JOURNAL OF MEMBRANE SCIENCE, 642巻, 20220215
  19. ★, Ultrahigh permeation of CO2 capture using composite organosilica membranes, SEPARATION AND PURIFICATION TECHNOLOGY, 282巻, 20220201
  20. Atmospheric-pressure PECVD synthesis of polymer-supported molecular sieving silica membranes for gas separation: Effect of pore size of polymeric support, MATERIALS LETTERS, 308巻, 20220201
  21. Enhanced production of butyl acetate via methanol-extracting transesterification membrane reactors using organosilica membrane: Experiment and modeling, CHEMICAL ENGINEERING JOURNAL, 429巻, 20220201
  22. Controlled organosilica networks via metal doping for improved dehydration membranes with layered hybrid structures, SEPARATION AND PURIFICATION TECHNOLOGY, 278巻, 20220101
  23. Facile low-temperature route toward the development of polymer-supported silica-based membranes for gas separation via atmospheric-pressure plasma-enhanced chemical vapor deposition, JOURNAL OF MEMBRANE SCIENCE, 638巻, 20211115
  24. Steam recovery via nanoporous and subnanoporous organosilica membranes: The effects of pore structure and operating conditions, SEPARATION AND PURIFICATION TECHNOLOGY, 275巻, 20211115
  25. Effect of the Ti/Zr ratio on the hydrothermal and chemical stability of TiO2-ZrO2 nanofiltration membranes, SEPARATION AND PURIFICATION TECHNOLOGY, 274巻, 20211101
  26. Preparation of polysilsesquioxane reverse osmosis membranes for water desalination from tris[(ethoxysilyl)alkyl]amines by sol-gel process and interfacial polymerization, APPLIED ORGANOMETALLIC CHEMISTRY, 35巻, 11号, 202111
  27. ★, Hydrothermal stability of fluorine-induced microporous silica membranes: Effect of steam treatment conditions, AICHE JOURNAL, 67巻, 9号, 20210901
  28. Pervaporation via silicon-based membranes: Correlation and prediction of performance in pervaporation and gas permeation, AICHE JOURNAL, 67巻, 7号, 202107
  29. ★, Pore Structure Controllability and CO2 Permeation Properties of Silica-Derived Membranes with a Dual-Network Structure, INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 60巻, 23号, pp. 8527-8537, 20210616
  30. ★, Facile development of microstructure-engineered, ligand-chelated SiO2-ZrO2 composite membranes for molecular separations, MOLECULAR SYSTEMS DESIGN & ENGINEERING, 6巻, 6号, pp. 429-444, 20210601
  31. Microporous Nickel-Coordinated Aminosilica Membranes for Improved Pervaporation Performance of Methanol/Toluene Separation, ACS APPLIED MATERIALS & INTERFACES, 13巻, 19号, pp. 23247-23259, 20210519
  32. ★, Recent Progress in a Membrane-Based Technique for Propylene/Propane Separation, MEMBRANES, 11巻, 5号, 202105
  33. ★, Design of a SiOC network structure with oxidation stability and application to hydrogen separation membranes at high temperatures, JOURNAL OF MEMBRANE SCIENCE, 625巻, 20210501
  34. Metal-induced microporous aminosilica creates a highly permeable gas-separation membrane, MATERIALS CHEMISTRY FRONTIERS, 5巻, 7号, 20210407
  35. Multiple Amine-Contained POSS-Functionalized Organosilica Membranes for Gas Separation, MEMBRANES, 11巻, 3号, 202103
  36. Improved performance of organosilica membranes for steam recovery at moderate-to-high temperatures via the use of a hydrothermally stable intermediate layer, JOURNAL OF MEMBRANE SCIENCE, 620巻, 20210215
  37. ★, Hydrocarbon permeation properties through microporous fluorine-doped organosilica membranes with controlled pore sizes, JOURNAL OF MEMBRANE SCIENCE, 619巻, 20210201
  38. TiO2 Coatings Via Atmospheric-Pressure Plasma-Enhanced Chemical Vapor Deposition for Enhancing the UV-Resistant Properties of Transparent Plastics, ACS OMEGA, 6巻, 2号, pp. 1370-1377, 20210119
  39. Ultrafast Synthesis of Silica-Based Molecular Sieve Membranes in Dielectric Barrier Discharge at Low Temperature and Atmospheric Pressure, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143巻, 1号, pp. 35-40, 20210113
  40. ★, A carbon-silica-zirconia ceramic membrane with CO2 flow-switching behaviour promising versatile high-temperature H-2/CO2 separation, JOURNAL OF MATERIALS CHEMISTRY A, 8巻, 44号, pp. 23563-23573, 20201128
  41. SiC mesoporous membranes for sulfuric acid decomposition at high temperatures in the iodine-sulfur process, RSC ADVANCES, 10巻, 68号, pp. 41883-41890, 20201117
  42. ★, ゾル-ゲル法によりマイクロポーラス構造を制御したシリカ系膜のプロピレン/プロパン透過特性, 膜, 45巻, pp. 275-280, 20201101
  43. Tuning the microstructure of polycarbosilane-derived SiC(O) separation membranes via thermal-oxidative cross-linking, SEPARATION AND PURIFICATION TECHNOLOGY, 248巻, 20201001
  44. ★, Amino-decorated organosilica membranes for highly permeable CO2 capture, JOURNAL OF MEMBRANE SCIENCE, 611巻, 20201001
  45. Al2O3 nanofiltration membranes fabricated from nanofiber sols: Preparation, characterization, and performance, JOURNAL OF MEMBRANE SCIENCE, 611巻, 20201001
  46. Pervaporation removal of methanol from methanol/organic azeotropes using organosilica membranes: Experimental and modeling, JOURNAL OF MEMBRANE SCIENCE, 610巻, 20200901
  47. Filtration of surfactant-stabilized oil-in-water emulsions with porous ceramic membranes: Effects of membrane pore size and surface charge on fouling behavior, JOURNAL OF MEMBRANE SCIENCE, 610巻, 20200901
  48. Experimental study and modeling of organic solvent reverse osmosis separations through organosilica membranes, AICHE JOURNAL, 66巻, 9号, 202009
  49. High-performance molecular-separation ceramic membranes derived from oxidative cross-linked polytitanocarbosilane, JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 103巻, 8号, pp. 4473-4488, 202008
  50. ★, Pore size tuning of bis(triethoxysilyl)propane (BTESP)-derived membrane for gas separation: Effects of the acid molar ratio in the sol and of the calcination temperature, SEPARATION AND PURIFICATION TECHNOLOGY, 242巻, 20200701
  51. Evaluation of experimentally obtained permeance based on module simulation: How should permeance be evaluated?, AICHE JOURNAL, 66巻, 7号, 202007
  52. ★, Pore subnano-environment engineering of organosilica membranes for highly selective propylene/propane separation, JOURNAL OF MEMBRANE SCIENCE, 603巻, 20200515
  53. ★, Development of an acetylacetonate-modified silica-zirconia composite membrane applicable to gas separation, JOURNAL OF MEMBRANE SCIENCE, 599巻, 20200401
  54. ★, Fine-tuned, molecular-composite, organosilica membranes for highly efficient propylene/propane separation via suitable pore size, AICHE JOURNAL, 66巻, 4号, 202004
  55. Development of high-performance sub-nanoporous SiC-based membranes derived from polytitanocarbosilane, JOURNAL OF MEMBRANE SCIENCE, 598巻, 20200315
  56. Energy-efficient separation of organic liquids using organosilica membranes via a reverse osmosis route, JOURNAL OF MEMBRANE SCIENCE, 597巻, 20200301
  57. Chemical-free cleaning of fouled reverse osmosis (RO) membranes derived from bis(triethoxysilyl)ethane (BTESE), JOURNAL OF MEMBRANE SCIENCE, 601巻, 20200301
  58. Phase inversion/sintering-induced porous ceramic microsheet membranes for high-quality separation of oily wastewater, JOURNAL OF MEMBRANE SCIENCE, 595巻, 20200201
  59. Ceramic-Supported Polyhedral Oligomeric Silsesquioxane-Organosilica Nanocomposite Membrane for Efficient Gas Separation, INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 58巻, 47号, pp. 21708-21716, 20191127
  60. Selective water vapor permeation from steam/non-condensable gas mixtures via organosilica membranes at moderate-to-high temperatures, JOURNAL OF MEMBRANE SCIENCE, 589巻, 20191101
  61. Evaluating the chemical stability of metal oxides in SO3 and applications of SiO2-based membranes to O-2/SO3 separation, JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 102巻, 11号, pp. 6946-6956, 201911
  62. Vapor-permeation dehydration of isopropanol using a flexible and thin organosilica membrane with high permeance, JOURNAL OF MEMBRANE SCIENCE, 588巻, 20191015
  63. Free glycerol removal from monoglyceride using TiO2-ZrO2 nanofiltration membranes, SEPARATION AND PURIFICATION TECHNOLOGY, 224巻, pp. 366-372, 20191001
  64. TiO2-ZrO2 membranes of controlled pore sizes with different Ti/Zr ratios for nanofiltration, JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 92巻, 1号, pp. 12-24, 201910
  65. Molecular Dynamics Simulation Study of Solid Vibration Permeation in Microporous Amorphous Silica Network Voids, MEMBRANES, 9巻, 10号, 201910
  66. Infrared-spectroscopic porosimetry: Development and application for characterization of hundred-nanometer-thick porous thin films, THIN SOLID FILMS, 685巻, pp. 299-305, 20190901
  67. ★, Tailoring the microstructure and permeation properties of bridged organosilica membranes via control of the bond angles, JOURNAL OF MEMBRANE SCIENCE, 584巻, pp. 56-65, 20190815
  68. Molecular dynamics simulation study on the mechanisms of liquid-phase permeation in nanopores, SEPARATION AND PURIFICATION TECHNOLOGY, 220巻, pp. 259-267, 20190801
  69. Research and development on membrane IS process for hydrogen production using solar heat, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 44巻, 35号, pp. 19141-19152, 20190719
  70. ★, Tailoring the molecular sieving properties and thermal stability of carbonized membranes containing polyhedral oligomeric silsesquioxane (POSS)-polyimide via the introduction of norbornene, JOURNAL OF MEMBRANE SCIENCE, 582巻, pp. 59-69, 20190715
  71. ★, マイクロポーラス構造制御による高透過性分子ふるい膜の開発, 膜, 44巻, pp. 121-125, 201906
  72. Hydrothermal stability and permeation properties of TiO2-ZrO2 (5/5) nanofiltration membranes at high temperatures, SEPARATION AND PURIFICATION TECHNOLOGY, 212巻, pp. 1001-1012, 20190401
  73. ★, Effects of Calcination Condition on the Network Structure of Triethoxysilane (TRIES) and How Si-H Groups Influence Hydrophobicity Under Hydrothermal Conditions, INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 58巻, 9号, pp. 3867-3875, 20190306
  74. Tailoring Ultramicroporosity To Maximize CO2 Transport within Pyrimidine-Bridged Organosilica Membranes, ACS APPLIED MATERIALS & INTERFACES, 11巻, 7号, pp. 7164-7173, 20190220
  75. Effect of Sintering Temperature on Sol-Gel Synthesis of Porous Polymeric Membrane Supported Layered Hybrid Organosilica Membranes and Their Vapor Permeation Property, KAGAKU KOGAKU RONBUNSHU, 45巻, 5号, pp. 177-183, 2019
  76. Pervaporation dehydration of aqueous solutions of various types of molecules via organosilica membranes: Effect of membrane pore sizes and molecular sizes, SEPARATION AND PURIFICATION TECHNOLOGY, 207巻, pp. 108-115, 20181222
  77. Diethylenedioxane-bridged microporous organosilica membrane for gas and water separation, SEPARATION AND PURIFICATION TECHNOLOGY, 207巻, pp. 370-376, 20181222
  78. Improved thermal and oxidation stability of bis( triethoxysilyl) ethane ( BTESE)- derived membranes, and their gas- permeation properties, JOURNAL OF MATERIALS CHEMISTRY A, 6巻, 46号, pp. 23378-23387, 20181214
  79. UV-Protective TiO2 Thin Films with High Transparency in Visible Light Region Fabricated via Atmospheric-Pressure Plasma-Enhanced Chemical Vapor Deposition, ACS APPLIED MATERIALS & INTERFACES, 10巻, 49号, pp. 42657-42665, 20181212
  80. Preparation, characterization, and evaluation of TiO2-ZrO2 nanofiltration membranes fired at different temperatures, JOURNAL OF MEMBRANE SCIENCE, 564巻, pp. 691-699, 20181015
  81. Atmospheric-pressure plasma-enhanced chemical vapor deposition of UV-shielding TiO2 coatings on transparent plastics, MATERIALS LETTERS, 228巻, pp. 479-481, 20181001
  82. Preparation of Hybrid Organosilica Reverse Osmosis Membranes by Interfacial Polymerization of Bis[(trialkoxysilyl)propyl]amine, CHEMISTRY LETTERS, 47巻, 9号, pp. 1210-1212, 201809
  83. Atmospheric-Pressure Plasma-Enhanced Chemical Vapor Deposition of Hybrid Silica Membranes, JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 51巻, 9号, pp. 732-739, 201809
  84. ★, Fluorine Doping of Microporous Organosilica Membranes for Pore Size Control and Enhanced Hydrophobic Properties, ACS OMEGA, 3巻, 8号, pp. 8612-8620, 201808
  85. Role of Amine Type in CO2 Separation Performance within Amine Functionalized Silica/Organosilica Membranes: A Review, APPLIED SCIENCES-BASEL, 8巻, 7号, 201807
  86. Acid post-treatment of sol-gel-derived ethylene-bridged organosilica membranes and their filtration performances, JOURNAL OF MEMBRANE SCIENCE, 556巻, pp. 196-202, 20180615
  87. シリカ系多孔質膜のナノ/サブナノチューニングと水素分離への応用, 膜, 43巻, 4号, pp. 180-187, 201806
  88. ★, Tailoring a Thermally Stable Amorphous SiOC Structure for the Separation of Large Molecules: The Effect of Calcination Temperature on SiOC Structures and Gas Permeation Properties, ACS OMEGA, 3巻, 6号, pp. 6369-6377, 201806
  89. Enhanced CO2 Separation Performance for Tertiary Amine-Silica Membranes via Thermally Induced Local Liberation of CH3Cl, AICHE JOURNAL, 64巻, 5号, pp. 1528-1539, 201805
  90. Facile and Scalable Flow-Induced Deposition of Organosilica on Porous Polymer Supports for Reverse Osmosis Desalination, ACS APPLIED MATERIALS & INTERFACES, 10巻, 16号, pp. 14070-14078, 20180425
  91. Bis(triethoxysilyl)ethane (BTESE)-derived silica membranes: pore formation mechanism and gas permeation properties, JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 86巻, 1号, pp. 63-72, 201804
  92. ★, Fluorine-induced microporous silica membranes: Dramatic improvement in hydrothermal stability and pore size controllability for highly permeable propylene/propane separation, JOURNAL OF MEMBRANE SCIENCE, 549巻, pp. 111-119, 20180301
  93. Preparation of bridged silica RO membranes from copolymerization of bis(triethoxysilyl)ethene/(hydroxymethyl)triethoxysilane. Effects of ethenylene-bridge enhancing water permeability, JOURNAL OF MEMBRANE SCIENCE, 546巻, pp. 173-178, 20180115
  94. ★, シリカ系分子ふるい膜のネットワーク制御とNormalized Knudsen-based Permeance (NKP) 法による細孔径評価, ゼオライト, 35巻, pp. 13-22, 201801
  95. Fabrication and CO2 permeation properties of amine-silica membranes using a variety of amine types, JOURNAL OF MEMBRANE SCIENCE, 541巻, pp. 447-456, 20171101
  96. ★, Gas permeation properties for organosilica membranes with different Si/C ratios and evaluation of microporous structures, AICHE JOURNAL, 63巻, 10号, pp. 4491-4498, 201710
  97. Preparation of cyclic peptide nanotube structures and molecular simulation of water adsorption and diffusion, JOURNAL OF MEMBRANE SCIENCE, 537巻, pp. 101-110, 20170901
  98. Preparation of Bridged Polysilsesquioxane Membranes from Bis[3-(triethoxysilyl)propyl] amine for Water Desalination, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 90巻, 9号, pp. 1035-1040, 201709
  99. Development and permeation properties of SiO2-ZrO2 nanofiltration membranes with a MWCO of < 200, JOURNAL OF MEMBRANE SCIENCE, 535巻, pp. 331-341, 20170801
  100. ★, Preparation and Gas Permeation Properties of Fluorine-Silica Membranes with Controlled Amorphous Silica Structures: Effect of Fluorine Source and Calcination Temperature on Network Size, ACS APPLIED MATERIALS & INTERFACES, 9巻, 29号, pp. 24625-24633, 20170726
  101. Pyrimidine-bridged organoalkoxysilane membrane for high-efficiency CO2 transport via mild affinity, SEPARATION AND PURIFICATION TECHNOLOGY, 178巻, pp. 232-241, 20170507
  102. Preparation of bridged polysilsesquioxane-based membranes containing 1,2,3-triazole moieties for water desalination, POLYMER JOURNAL, 49巻, 4号, pp. 401-406, 201704
  103. Organosilica bis(triethoxysilyl)ethane (BTESE) membranes for gas permeation (GS) and reverse osmosis (RO): The effect of preparation conditions on structure, and the correlation between gas and liquid permeation properties, JOURNAL OF MEMBRANE SCIENCE, 526巻, pp. 242-251, 20170315
  104. Synthesis of organically bridged trialkoxysilanes bearing acetoxymethyl groups and applications to reverse osmosis membranes, APPLIED ORGANOMETALLIC CHEMISTRY, 31巻, 3号, 201703
  105. Preparation of POSS-derived robust RO membranes for water desalination, DESALINATION, 404巻, pp. 322-327, 20170217
  106. SiO2-ZrO2 nanofiltration membranes of different Si/Zr molar ratios: Stability in hot water and acid/alkaline solutions, JOURNAL OF MEMBRANE SCIENCE, 524巻, pp. 700-711, 20170215
  107. ★, Pore size tuning of sol-gel-derived triethoxysilane (TRIES) membranes for gas separation, JOURNAL OF MEMBRANE SCIENCE, 524巻, pp. 64-72, 20170215
  108. Atmospheric-pressure plasma-enhanced chemical vapor deposition of microporous silica membranes for gas separation, JOURNAL OF MEMBRANE SCIENCE, 524巻, pp. 644-651, 20170215
  109. Fabrication and Microstructure Tuning of a Pyrimidine-Bridged Organoalkoxysilane Membrane for CO2 Separation, INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 56巻, 5号, pp. 1316-1326, 20170208
  110. Photo-induced sol-gel synthesis of polymer-supported silsesquioxane membranes, RSC ADVANCES, 7巻, 12号, pp. 7150-7157, 201702
  111. Catalytic Ammonia Decomposition over High-Performance Ru/Graphene Nanocomposites for Efficient COx-Free Hydrogen Production, CATALYSTS, 7巻, 1号, 201701
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著書等出版物

  1. 2022年04月, CO2の分離・回収・貯留の最新技術, 第2章 2.2.3 分離技術 ゾル-ゲル法によるシリカ系多孔膜のCO2分離, エヌ・ティー・エス出版, 2022年04月, 単行本(学術書), 単著, Jananese, 金指 正言, 978-4-86043-771-8, 370, 99-106
  2. 2019年07月, Current Trends and Future Developments on (Bio-)Membranes: Microporous Membrane and Membrane Reactors, Chaper 5: Gas permeation properties and pore size evaluation of microporous silica membranes, Elsevier, 2019年, 201907, 単行本(学術書), 共著, English, M. Kanezashi, T. Tsuru, 978-0-12-816350-4, 408, p.101-126
  3. 2019年04月26日, 水素の製造,輸送・貯蔵技術と材料開発事例集, 第3節 シリカ系多孔膜の細孔構造制御と水素分離への応用, 技術情報協会, 2019年, 4, 単行本(学術書), 共著, 日本語, 金指 正言,都留 稔了, ISBN978-4-86104-745-9, 415, 132-139
  4. 2018年03月, 二酸化炭素・水素分離膜の開発と応用, ゾル-ゲル法によるシリカ系膜の水素透過特性, シーエムシー出版, 2018年, 3, 単行本(学術書), 共著, Japanese, 金指正言,長澤寛規,都留稔了, ISBN978-4-7813-1321-4, 291, 111-119
  5. 2017年07月31日, ゾル-ゲルテクノロジーの最新動向, 第17章 シリカ系分子ふるい膜の細孔構造制御と透過特性, シーエムシー出版, 2017年, 201707, 単行本(学術書), 共著, Japanese, 金指 正言, 都留 稔了, ISBN978-4-7813-1258-3, 416, 12
  6. 2016年10月, Carbon Dioxide Capture: Processes, Technology and Environmental Implications, Hybrid organosilica membranes for CO2 separation under wet conditions, Nova Science Publishers, Inc., 2016年, 10, 単行本(学術書), 共著, English, X. Ren, M. Kanezashi, T. Tsuru, 978-1-63485-334-7, 326, 12
  7. 2014年12月19日, エネルギー・化学プロセスにおける膜分離技術, 第3章 第2節 ゾル-ゲル法によるシリカ膜の開発と応用技術, S&T出版, 2014年, 12, 単行本(学術書), 単著, 日本語, 金指 正言, ISBN978-4-907002-42-8, 306, 10
  8. 2014年02月24日, ゾル-ゲル法の最新応用と展望, 第6章4. ガス分離用多孔質無機膜, シーエムシー出版, 2014年, 02, 単行本(学術書), 共著, 日本語, 金指 正言, 都留 稔了, ISBN978-4-7813-0931-6, 321, 10
  9. 2014年01月21日, 最近の化学工学63「ここまできた膜分離プロセス~基礎から応用~」, 第11章 ゾル-ゲル法による多孔質セラミック膜の作製, 三恵社, 2014年, 01, 単行本(学術書), 共著, 日本語, 都留 稔了, 金指 正言, ISBN978-4-86487-178-5, 212, 11
  10. 2013年06月, Encyclopedia of Membrane Science and Technology, Sol-gel-derived silica membranes, John Wiley & Sons, 2013年, 06, 単行本(学術書), 単著, 英語, Masakoto Kanezashi, 24
  11. 2012年12月, Zeolites: Synthesis, Chemistry and Applications, Normalized Knudsen-based permeance of zeolite and silica membranes for evaluation of micro-pore sizes, Nova Science Publishers, Inc., 2012年12月, 12, 単行本(学術書), 共著, English, H. R. Lee, G. Li, M. Kanezashi, T. Yoshioka, T. Tsuru, ISBN978-1-61942-890-4, 275-284
  12. 2011年08月, Sol-Gel Process: Uniformity, Polymers and Applications, Controlling silica networks using bridged alkoxides for hydrogen separation membranes, Nova Science Publishers, 2011年, 単行本(学術書), 共著, 英語, Toshinori Tsuru, H. R. Lee, Masakoto Kanezashi, 8
  13. 2011年05月, Membrane Science and Technology Series 14, Gas permeation properties of helium, hydrogen and polar molecules through microporous silica membranes at high temperatures: Correlation with silica network structure, Elsevier, 2011年, 単行本(学術書), 共著, 英語, Masakoto Kanezashi, Toshinori Tsuru, 20

招待講演、口頭・ポスター発表等

  1. ゾル-ゲル法によるシリカ系多孔膜の細孔構造制御とCO2透過特性, 金指 正言, 膜によるCO2分離回収技術と研究開発動向~Direct Air Capture:DACも含めて~, 2022年08月22日, 招待, 日本語, 技術情報センター, プレプリント
  2. Molecular-level Engineering of Hybrid Inorganic-Organic Membrane via Utilization of Unsaturated Precursors, M. Kanezashi, The 13th Conference of the Aseanian Membrane Society (AMS13), 2022年07月05日, 招待, 英語, Nanyang Technological University, Singapore, プレプリント
  3. シリカ系多孔膜によるCO2透過特性, 金指 正言, 二酸化炭素分離膜開発の最新動向と今後の展望, 2022年03月10日, 招待, 日本語, 日本膜学会, オンライン開催, 発表資料
  4. Microstructure engineering of ligand-modified ceramic membranes derived from network-forming precursors, M. Kanezashi, 14th Pacific Rim Conference of Ceramic Societies (PACRIM14), 2021年12月16日, 招待, 英語, The American Ceramic Society, オンライン開催, プレプリント
  5. シリカネットワークエンジニアリングによる構造安定化と気体分離膜の開発, 金指 正言, 第21回反好会講演会, 2021年09月21日, 招待, 日本語, 化学工学会反応工学部会, 発表資料
  6. Tailoring the amorphous microporous silica structure for gas separation membrane, M. Kanezashi, 2020 Dalian University of Technology-Overseas Partner Universities Series Online Exchange Conference, 2021年01月08日, 招待, 英語, Dalian University of Technology, 発表資料
  7. Development of silica-derived molecular sieving membranes via controlling microporous structure, M. Kanezashi, AIChE Annual Meeting, 2020年11月19日, 招待, 英語, American Institute of Chemical Engineers, Virtual Meeting (Web), プレプリント
  8. Tailoring molecular sieving property and thermal stability of organic inorganic hybrid membranes for gas separation, M. Kanezashi, 13th Pacific Rim Conference of Ceramic Societies (PACRIM13), 2019年10月30日, 招待, 英語, The Ceramic Society of Japan, Okinawa, プレプリント
  9. ゾル-ゲル法によるシリカ系分子ふるい膜の細孔構造制御と透過特性, 金指 正言, 日本ゾル–ゲル学会第17回討論会, 2019年08月06日, 招待, 日本語, プレプリント
  10. ゾル-ゲル法によるシリカ系分子ふるい膜の開発と各種ガス分離プロセスへの応用, 金指 正言, JPIJS関西地区討論会, 2019年07月25日, 招待, 日本語, プレプリント
  11. Development of highly permeable molecular sieving membranes via controlling microporous structure, Masakoto Kanezashi, 9th International Symposium on Inorganic Membranes (ISIM9), 2019年07月, 招待, 英語, 発表資料
  12. ゾル-ゲル法によりネットワーク構造を制御したシリカ系膜の炭化水素透過特性, 金指正言,長澤寛規,都留稔了, 化学工学会第83年会, 2018年03月13日, 招待, 日本語, プレプリント
  13. Pore size controllability and gas permeation properties of sol-gel derived amorphous silica membranes, Masakoto Kanezashi, International Institute for Carbon-Neutral Energy Research (I2CNER) workshop 2018, 2018年02月02日, 招待, 英語, International Institute for Carbon-Neutral Energy Research (I2CNER), Kyushu University, 発表資料
  14. 炭化水素分離のためのシリカ系膜の開発, 金指 正言, 第34回ニューメンブレンテクノロジーシンポジウム, 2017年10月17日, 招待, 日本語, 日本膜学会,一般社団法人日本能率協会, 東京, 発表資料
  15. Tailoring the subnano amorphous silica network structure for development of highly permeable gas separation membranes, M. Kanezashi, The Society of Chemical Engineers, Japan (SCEJ) 49th Autumn Meeting (Joint Session of SCEJ and KIChE), 2017年09月21日, 招待, 英語, The Society of Chemical Engineers, Japan, プレプリント
  16. ゾル-ゲル法によりアモルファス構造を制御したシリカ系膜の開発と透過特性, 金指 正言, 無機膜研究センター産業化戦略協議会 第5回セミナー, 2017年05月19日, 招待, 日本語, 発表資料
  17. 橋架けアルコキシドによるオルガノシリカ膜の細孔構造制御と炭化水素透過特性, 金指正言,米田悠里,長澤寛規,都留稔了, 化学工学会第82年会, 2017年03月, 招待, 日本語, 化学工学会
  18. ゾル-ゲル法によりネットワーク構造を制御したシリカ系気体分離膜の開発, 金指 正言, 日本セラミックス協会 第29回秋季シンポジウム, 2016年09月09日, 招待, 日本語
  19. Tailoring the silica network structure for highly permeable gas separation membranes and evaluation of gas permeation properties, Masakoto Kanezashi, 7th International Symposium on Inorganic Membranes (ISIM7), 2016年07月30日, 招待, 英語
  20. シリカ系気体分離膜のネットワーク構造制御と透過特性評価, 金指 正言, 日本膜学会第38年会, 2016年05月11日, 招待, 日本語, 日本膜学会, 早稲田大学
  21. Normalized Knudsen-based Permeance (NKP)によるアモルファスシリカ膜の細孔径評価, 金指 正言, 分離工学セミナー「サブナノポア測定技術の最新動向:多孔質吸着材および分離膜の開発に向けて」, 2015年04月, 招待, 日本語, 日本膜学会,化学工学会膜分科会,化学工学会中国四国支部
  22. シリカネットワーク構造制御による新規水素分離膜の創製, 金指 正言, 化学工学会第43回秋季大会, 2011年09月, 招待, 日本語, 化学工学会
  23. Sol-gel derived Pd-SiO2 composite membranes for hydrogen separation, 金指 正言, 第20回日本MRS学術シンポジウム, 2010年12月, 招待, 日本語
  24. Sol-gel derived silica membranes for hydrogen separation, Masakoto Kanezashi, 2nd International Symposium on Inorganic Membranes, 2009年07月, 招待, 英語

受賞

  1. 2021年11月06日, 第20回(令和3年度)広島大学学長表彰 Phoenix Outstanding Researcher Award, 広島大学
  2. 2020年11月07日, 第19回(令和2年度)広島大学学長表彰 Phoenix Outstanding Researcher Award, 広島大学
  3. 2019年11月02日, 第18回(令和元年度)広島大学学長表彰 Phoenix Outstanding Researcher Award, 広島大学
  4. 2018年, Outstanding Paper Award of 2018 Journal of Chemical Engineering of Japan, Hiroshima University, Atmospheric-pressure plasma-enhanced chemical vapor deposition of hybrid silica membranes
  5. 2016年05月11日, 日本膜学会膜学研究奨励賞, 日本膜学会, シリカ系気体分離膜のネットワーク構造制御と透過特性評価
  6. 2013年, Outstanding Paper Award of 2013 Journal of Chemical Engineering of Japan, Hiroshima University, Micropore filling phase permeation of a condensable vapor in silica membranes: A molecular dynamics study
  7. 2011年03月01日, 化学工学会研究奨励賞 實吉雅郎記念賞, 化学工学会, シリカネットワーク構造制御による新規水素分離膜の創製
  8. 2005年08月, Best poster award, ICOM 2005 (International Congress on Membranes and Membrane Processes), Hydrogen separation performance and stability of Ni-doped silica membranes in high temperature steam

社会活動

委員会等委員歴

  1. 膜工学分科会幹事(中国・四国・九州地区), 2017年04月01日, 9999年, 化学工学会膜工学分科会
  2. 中国地区化学工学懇話会幹事, 2018年04月20日, 2020年04月, 中国地区化学工学懇話会
  3. 化学工学誌トピックス委員, 2019年01月01日, 公益社団法人 化学工学会
  4. 膜誌編集委員, 2019年04月01日, 日本膜学会
  5. 膜工学ニュース論文紹介サービス編集委員, 2020年04月01日, 9999年99月, 化学工学会 分離プロセス部会 膜工学分科会
  6. 日本ゾル-ゲル学会理事, 2020年04月01日, 9999年99月, 日本ゾル-ゲル学会

学術会議等の主催

  1. 日本セラミックス協会 第29回秋季シンポジウム, 秋季シンポジウム現地実行委員, 2016年04月, 2016年09月
  2. The 7th International Symposium on Inorganic Membranes (ISIM7), 組織委員, 2016年01月, 2016年07月
  3. The 10th Conference of Aseanian Membrane Society (AMS10), 実行委員, 2015年10月, 2016年07月
  4. 日本ゾル-ゲル学会第11回討論会, 運営委員, 2013年08月
  5. ZMPC 2012 (International Symposium on Zeolites and Microporous Crystals), 運営委員, 2012年07月
  6. 日本膜学会第34年会, 組織委員, 2012年05月
  7. 膜シンポジウム2009, 運営委員, 2009年11月
  8. 化学工学会第41回秋季大会, 実行委員, 2009年09月
  9. AMS5 (The Fifth Conference of Aseanian Membrane Society), Secretariat of AMS5 special issue, 2009年07月

その他社会貢献活動(広大・部局主催含)

  1. 日本ゾル-ゲル学会第11回討論会,2013/8/1-2,広島大学,運営委員, セミナー・ワークショップ