安倍 学MANABU ABE

Last Updated :2022/11/01

所属・職名
学術・社会連携室 理事
ホームページ
メールアドレス
mabehiroshima-u.ac.jp
その他連絡先
東広島市鏡山一丁目3番1号 C309広島大学大学院理学研究科化学専攻
TEL:082-424-7432 FAX:082-424-7432
自己紹介
・自然界に豊富に存在する光エネルギーを用いる化学反応の開発 ・光照射によって抗がん剤などの生物活性物質をデリバリーする薬剤の開発 ・化学反応に介在する不安定化学種の直接観測に基づく化学反応の機構解明

基本情報

主な職歴

  • 2021年, 2021年, 関西学院大学, 理工学部, 非常勤講師
  • 2021年, 東京工業大学, 大学院理工学研究院, 非常勤講師
  • 2021年, 京都大学, 大学院工学研究科, 非常勤講師
  • 2020年, 広島大学, 大学院先進理工系科学研究科, 教授
  • 2018年, 2018年, 大阪府立大学, 工学部, 非常勤講師
  • 2018年, 2018年, 大阪大学, 基礎工学部, 非常勤講師
  • 2015年, 2015年, 大阪市立大学, 理学部, 非常勤講師
  • 2012年, 2012年, 九州大学, 理学部, 非常勤講師
  • 2008年, 2008年, 群馬大学, 工学部, 非常勤講師
  • 2008年, 2008年, 三重大学, 工学部, 非常勤講師
  • 2007年, 2020年03月31日, 広島大学, 教授
  • 2006年, 2007年, 大阪大学, 助教授
  • 2003年, 2003年, 岐阜大学, 工学部, 非常勤講師
  • 2000年, 2006年, 大阪大学, 講師
  • 1995年, 2000年, 大阪大学, 助手

学歴

  • 京都工芸繊維大学, 工芸科学研究科, 材料科学専攻, 日本, 1992年04月, 1995年03月
  • 京都工芸繊維大学, 工芸学部, 工業化学科, 日本, 1986年04月, 1990年03月

学位

  • 博士(工学) (京都工芸繊維大学)
  • 修士(工学) (京都工芸繊維大学)

教育担当

  • 【学士課程】 理学部 : 化学科 : 化学プログラム
  • 【博士課程前期】 先進理工系科学研究科 : 先進理工系科学専攻 : 基礎化学プログラム
  • 【博士課程後期】 先進理工系科学研究科 : 先進理工系科学専攻 : 基礎化学プログラム

研究分野

  • 化学 / 基礎化学 / 有機化学
  • 化学 / 複合化学 / 合成化学
  • 化学 / 複合化学 / 機能物性化学
  • 複合領域 / 生体分子科学 / ケミカルバイオロジー

研究キーワード

  • 量子化学計算
  • 軌道論
  • 反応論
  • 有機光化学

所属学会

  • 日本化学会, 1990年10月
  • 光化学協会, 1995年04月
  • 有機合成化学協会, 1992年10月
  • ケイ素化学協会, 2006年10月
  • 電子スピンサイエンス学会, 2006年10月
  • アメリカ化学会, 1995年04月

教育活動

授業担当

  1. 2022年, 教養教育, 2ターム, 現代化学
  2. 2022年, 学部専門, 4ターム, 先端化学
  3. 2022年, 学部専門, セメスター(前期), 卒業研究
  4. 2022年, 学部専門, セメスター(後期), 卒業研究
  5. 2022年, 学部専門, 1ターム, 反応有機化学
  6. 2022年, 学部専門, 3ターム, 有機化学III
  7. 2022年, 学部専門, セメスター(前期), 化学特別講義(ペプチド合成化学)
  8. 2022年, 博士課程・博士課程後期, セメスター(前期), 化学特別研究
  9. 2022年, 博士課程・博士課程後期, セメスター(後期), 化学特別研究
  10. 2022年, 博士課程・博士課程後期, セメスター(前期), 反応有機化学セミナー
  11. 2022年, 博士課程・博士課程後期, セメスター(後期), 反応有機化学セミナー
  12. 2022年, 修士課程・博士課程前期, 1ターム, 基礎化学特別演習A
  13. 2022年, 修士課程・博士課程前期, 2ターム, 基礎化学特別演習A
  14. 2022年, 修士課程・博士課程前期, 3ターム, 基礎化学特別演習B
  15. 2022年, 修士課程・博士課程前期, 4ターム, 基礎化学特別演習B
  16. 2022年, 修士課程・博士課程前期, 年度, 基礎化学特別研究
  17. 2022年, 修士課程・博士課程前期, 年度, 基礎化学特別研究
  18. 2022年, 博士課程・博士課程後期, 年度, 基礎化学特別研究
  19. 2022年, 博士課程・博士課程後期, 年度, 基礎化学特別研究
  20. 2022年, 博士課程・博士課程後期, 年度, 基礎化学特別研究

研究活動

学術論文(★は代表的な論文)

  1. Assemblies of 1,4-Bis(diarylamino)naphthalenes and Aromatic Amphiphiles: Highly Reducing Photoredox Catalysis in Water, SYNLETT, 33巻, 12号, pp. 1184-1188, 20220721
  2. Photoreaction of 4-(Bromomethyl)-7-(diethylamino)coumarin:Generation of a Radical and Cation Triplet Diradical during the C-BrBond Cleavage br, ORGANIC LETTERS, 24巻, 15号, pp. 2804-2808, 20220422
  3. Thermal Reaction Behavior of Triphenylimidazolyl Radical with a Bulky Substituent, JOURNAL OF ORGANIC CHEMISTRY, 87巻, 10号, pp. 6877-6885, 20220520
  4. A stable silylborane with diminished boron Lewis acidity, DALTON TRANSACTIONS, 51巻, 17号, pp. 6543-6546, 20220503
  5. Protonation-Enhanced Reactivity of Triplet State in Dearomative Photocycloaddition of Quinolines to Olefins, ORGANIC LETTERS, 23巻, 16号, pp. 6257-6261, 20210820
  6. 2-(4-Nitrophenyl)-1H-indolyl-3-methyl Chromophore: A Versatile Photocage that Responds to Visible-light One-photon and Near-infrared-light Two-photon Excitations, CHEMISTRY LETTERS, 51巻, 2号, pp. 153-156, 202202
  7. Impacts of Solvent and Alkyl Chain Length on the Lifetime of Singlet Cyclopentane-1,3-diyl Diradicaloids with pi-Single Bonding, JOURNAL OF ORGANIC CHEMISTRY, 87巻, 3号, pp. 1858-1866, 20220204
  8. Long-lived localised singlet diradicaloids with carbon-carbon pi-single bonding (C-pi-C), CHEMICAL COMMUNICATIONS, 57巻, 86号, pp. 11301-11309, 20211028
  9. Impact of Five-membered Heterocyclic Rings on Photophysical Properties Including Two-photon Absorption Character, CHEMISTRY LETTERS, 50巻, 10号, pp. 1810-1813, 202110
  10. SOMO-HOMO Conversion in Triplet Cyclopentane-1,3-diyl Diradicals, ACS OMEGA, 6巻, 35号, pp. 22773-22779, 20210907
  11. Direct Detection of Singlet Cyclopentane-1,3-diyl Diradicals By Infrared and Ultraviolet-Visible Spectroscopy at Cryogenic Temperature and Their Photoreactivity, JOURNAL OF ORGANIC CHEMISTRY, 86巻, 17号, pp. 12046-12053, 20210903
  12. Structural Investigation of Photochemical Intermediates in Solution by Cold UV Spectroscopy in the Gas Phase: Photosubstitution of Dicyanobenzenes by Allylsilanes, JOURNAL OF PHYSICAL CHEMISTRY A, 125巻, 28号, pp. 6238-6245, 20210722
  13. New aspect of photophysics of 7,7,8,8-tetracyanoquinodimethane and its solvated complexes: intra- vs. inter-molecular charge-transfer, RSC ADVANCES, 11巻, 36号, pp. 22381-22389, 20210703
  14. SOMO-HOMO Conversion in Triplet Carbenes, ORGANIC LETTERS, 23巻, 13号, pp. 4955-4959, 20210702
  15. 1,3-Diradicals Embedded in Curved Paraphenylene Units: Singlet versus Triplet State and In-Plane Aromaticity, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143巻, 19号, pp. 7426-7439, 20210519
  16. Discovery of 4-alkoxy-2-aryl-6,7-dimethoxyquinolines as a new class of topoisomerase I inhibitors endowed with potent in vitro anticancer activity, EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 215巻, 20210405
  17. p-Nitroterphenyl units for near-infrared two-photon uncaging of calcium ions, JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 409巻, 20210315
  18. Simple generation of various alpha-monofluoroalkyl radicals by organic photoredox catalysis: modular synthesis of beta-monofluoroketones, CHEMICAL COMMUNICATIONS, 57巻, 21号, pp. 2609-2612, 20210314
  19. Light-triggered elimination of CO2 and absorption of O-2 (artificial breathing reaction) in photolysis of 2-(4-nitrophenyl)-1H-indole derivatives, PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 20巻, 3号, pp. 421-434, 202103
  20. Chemistry of Tertiary Carbon Center in the Formation of Congested C-O Ether Bonds, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 60巻, 8号, pp. 4329-4334, 20210219
  21. Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with pi-single bonding character, CHEMICAL SCIENCE, 12巻, 2号, pp. 613-625, 20210114
  22. Dynamic solvent effects in radical-radical coupling reactions: an almost bottleable localised singlet diradical, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 22巻, 48号, 20201228
  23. Conformation of K+(Crown Ether) Complexes Revealed by Ion Mobility-Mass Spectrometry and Ultraviolet Spectroscopy, JOURNAL OF PHYSICAL CHEMISTRY A, 124巻, 48号, pp. 9980-9990, 20201203
  24. Structural Transformation of the 2-(p-Aminophenyl)-1-hydroxyinden-3-ylmethyl Chromophore as a Photoremovable Protecting Group, CHEMPHOTOCHEM, 4巻, 12号, pp. 5392-5398, 202012
  25. Photoinduced alpha-Cleavage of 2-Azido-2-phenyl-1,3-indandione at Cryogenic Temperatures, ORGANIC LETTERS, 22巻, 20号, pp. 7885-7890, 20201016
  26. Heavy-Atom Tunneling Processes during Denitrogenation of 2,3-Diazabicyclo[2.2.1]hept-2-ene and Ring Closure of Cyclopentane-1,3-diyl Diradical. Stereoselectivity in Tunneling and Matrix Effect, JOURNAL OF ORGANIC CHEMISTRY, 85巻, 14号, pp. 8881-8892, 20200717
  27. Photochemical [2+2] cycloaddition reaction of carbonyl compounds with Danishefsky diene, ORGANIC & BIOMOLECULAR CHEMISTRY, 18巻, 26号, pp. 4962-4970, 20200714
  28. Reactivity and Product Analysis of a Pair of Cumyloxyl and tert-Butoxyl Radicals Generated in Photolysis of tert-Butyl Cumyl Peroxide, JOURNAL OF ORGANIC CHEMISTRY, 85巻, 13号, pp. 8627-8638, 20200702
  29. Photoinduced Reactivity in a Dispiro-1,2,4-trioxolane: Adamantane Ring Expansion and First Direct Observation of the Long-Lived Triplet Diradical Intermediates, JOURNAL OF PHYSICAL CHEMISTRY A, 124巻, 21号, pp. 4202-4210, 20200528
  30. Duality of Reactivity of a Biradicaloid Compound with an o-Quinodimethane Scaffold, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 142巻, 11号, pp. 5408-5418, 20200318
  31. Efficient Generation and Synthetic Applications of Alkyl-Substituted Siloxycarbenes: Suppression of Norrish-Type Fragmentations of Alkanoylsilanes by Triplet Energy Transfer, CHEMISTRY-A EUROPEAN JOURNAL, 26巻, 6号, pp. 1249-1253, 20200127
  32. Direct Suzuki-Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons, ACS CATALYSIS, 10巻, 1号, pp. 346-351, 20200103
  33. Insights into the photochemistry of 5-aminotetrazole derivatives with applications in coordination chemistry. Effect of the saccharyl moiety on the photostability, PURE AND APPLIED CHEMISTRY, 92巻, 1号, pp. 49-62, 202001
  34. Bulky Substituent Effect on Reactivity of Localized Singlet Cyclopentane-1,3-diyls with pi-Single Bonding (C-pi-C) Character, CHEMISTRY-AN ASIAN JOURNAL, 14巻, 23号, pp. 4223-4228, 20191202
  35. Photodecomposition of Thienylsulfonyl Azides: Generation and Spectroscopic Characterization of Triplet Thienylsulfonyl Nitrenes and 3-Thienylnitrene, JOURNAL OF PHYSICAL CHEMISTRY A, 123巻, 43号, pp. 9311-9320, 20191031
  36. Transforming Triplet Vinylnitrene into Triplet Alkylnitrene at Cryogenic Temperatures, ORGANIC LETTERS, 21巻, 18号, pp. 7194-7198, 20190920
  37. The Effect of Viscosity on the Diffusion and Termination Reaction of Organic Radical Pairs, CHEMISTRY-A EUROPEAN JOURNAL, 25巻, 42号, pp. 9846-9850, 20190725
  38. Formation and Reactivity of Triplet Vinylnitrenes as a Function of Ring Size, JOURNAL OF ORGANIC CHEMISTRY, 84巻, 14号, pp. 9215-9225, 20190719
  39. Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of alpha-CF2H-Substituted Ketones in Flow, ACS CATALYSIS, 9巻, 7号, pp. 6555-6563, 201907
  40. Separation of Spectroscopically Uniform Nanographenes, CHEMISTRY-AN ASIAN JOURNAL, 14巻, 10号, pp. 1786-1791, 20190515
  41. Generation of "Sumanenylidene": A Ground-State Triplet Carbene on a Curved -Conjugated Periphery, CHEMISTRY-AN ASIAN JOURNAL, 14巻, 10号, pp. 1844-1848, 20190515
  42. Generation of Extremely Long-lived Localized Singlet Diradicals: New Insights into Bond-homolysis Process and Discovery of Novel Bonding System (C-pi-C), JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 77巻, 5号, pp. 503-511, 201905
  43. Photochemical generation of the 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) radical from caged nitroxides by near-infrared two-photon irradiation and its cytocidal effect on lung cancer cells, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 15巻, pp. 863-873, 20190410
  44. 1,2-Diazacyclopentane-3,5-diyl Diradicals: Electronic Structure and Reactivity, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 141巻, 9号, pp. 3920-3933, 20190306
  45. Curve Effect on Singlet Diradical Contribution in Kekule-type Diradicals: A Sensitive Probe for Quinoidal Structure in Curved -Conjugated Molecules, MOLECULES, 24巻, 1号, 20190101
  46. Chloro- and Dichloro-methylsulfonyl Nitrenes: Spectroscopic Characterization, Photoisomerization, and Thermal Decomposition, MOLECULES, 23巻, 12号, 201812
  47. Methoxyphosphinidene and Isomeric Methylphosphinidene Oxide, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140巻, 42号, pp. 13604-13608, 20181024
  48. Extremely Long Lived Localized Singlet Diradicals in a Macrocyclic Structure: A Case Study on the Stretch Effect, CHEMISTRY-A EUROPEAN JOURNAL, 24巻, 55号, pp. 14808-14815, 20181001
  49. Triplet States of Tetrazoles, Nitrenes, and Carbenes from Matrix Photolysis of Tetrazoles, and Phenylcyanamide as a Source of Phenylnitrene, JOURNAL OF PHYSICAL CHEMISTRY A, 122巻, 37号, pp. 7276-7283, 20180920
  50. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer, CHEMICAL COMMUNICATIONS, 54巻, 67号, pp. 9290-9293, 20180828
  51. Sulfamoyl nitrenes: singlet or triplet ground state?, CHEMICAL COMMUNICATIONS, 54巻, 48号, pp. 6136-6139, 20180618
  52. Selective Probing of Potassium Ion in Solution by Intramolecular Excimer Fluorescence of Dibenzo-Crown Ethers, CHEMPHYSCHEM, 19巻, 11号, pp. 1331-1335, 20180605
  53. Unusually Long-Wavelength Emissions of Cyclopropanes: New Insight into C-C Bond Homolysis, CHEMISTRY-A EUROPEAN JOURNAL, 24巻, 30号, pp. 7595-7600, 20180528
  54. Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 57巻, 12号, pp. 3212-3216, 20180312
  55. Experimental Observation of Thermally Excited Triplet States of Heavier Group 15 Element Centered Diradical Dianions, CHEMISTRY-A EUROPEAN JOURNAL, 24巻, 13号, pp. 3156-3160, 20180302
  56. Photochemically Induced Intramolecular Radical Cyclization Reactions with Imines, JOURNAL OF ORGANIC CHEMISTRY, 83巻, 4号, pp. 1867-1875, 20180216
  57. Magnetically Bistable Nitrenes: Matrix Isolation of Furoylnitrenes in Both Singlet and Triplet States and Triplet 3-Furylnitrene, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140巻, 1号, pp. 10-13, 20180110
  58. Photochemical [2+2] cycloaddition reaction of enone derivatives with 2-siloxy-1H-pyrrole derivatives, ARKIVOC, pp. 192-204, 2018
  59. Fast Heavy-Atom Tunneling in Trifluoroacetyl Nitrene, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56巻, 49号, pp. 15672-15676, 20171204
  60. Artocarmins G-M, Prenylated 4-Chromenones from the Stems of Artocarpus rigida and Their Tyrosinase Inhibitory Activities, JOURNAL OF NATURAL PRODUCTS, 80巻, 12号, pp. 3173-3179, 201712
  61. Contrasting Photolytic and Thermal Decomposition of Phenyl Azidoformate: The Curtius Rearrangement Versus Intramolecular C-H Amination, JOURNAL OF PHYSICAL CHEMISTRY A, 121巻, 45号, pp. 8604-8613, 20171116
  62. Is pi-Single Bonding (C-pi-C) Possible? A Challenge in Organic Chemistry, CHEMISTRY LETTERS, 46巻, 11号, pp. 1586-1592, 201711
  63. Two ring opened oxetane taxoids containing a C-20 benzoyloxy group from the roots of Taxus wallichiana Zucc., TETRAHEDRON LETTERS, 58巻, 40号, pp. 3897-3900, 20171004
  64. Laser flash photolysis of nanocrystalline alpha-azidop-methoxy-p-acetophenone, ORGANIC & BIOMOLECULAR CHEMISTRY, 15巻, 35号, pp. 7380-7386, 20170921
  65. N-Methylcarbamoyl azide: spectroscopy, X-ray structure and decomposition via methylcarbamoyl nitrene, ORGANIC CHEMISTRY FRONTIERS, 4巻, 9号, pp. 1839-1848, 20170901
  66. Computational study on 1,3-disilacyclobutane-1,3-diylidene disilylenes: A synthetic strategy for cis-bent disilenes, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 30巻, 9号, 201709
  67. B(MIDA)-Containing Diborons, ACS OMEGA, 2巻, 9号, pp. 5911-5916, 201709
  68. Design and Synthesis of Two-Photon Responsive Chromophores for Near-Infrared Light-Induced Uncaging Reactions, SYNTHESIS-STUTTGART, 49巻, 15号, pp. 3337-3346, 201708
  69. Mechanistic study of stereoselectivity in azoalkane denitrogenations, PURE AND APPLIED CHEMISTRY, 89巻, 6号, pp. 759-764, 201706
  70. Design and Synthesis of a Caged Carboxylic Acid with a Donor-pi-Donor Coumarin Structure: One-photon and Two-photon Uncaging Reactions Using Visible and Near-Infrared Lights, ORGANIC LETTERS, 19巻, 10号, pp. 2622-2625, 20170519
  71. Direct observation of methoxycarbonylnitrene, CHEMICAL COMMUNICATIONS, 53巻, 35号, pp. 4783-4786, 20170501
  72. Suplatast tosilate protects the lung against hyperoxic lung injury by scavenging hydroxyl radicals, FREE RADICAL BIOLOGY AND MEDICINE, 106巻, pp. 1-9, 201705
  73. Photolysis of 3,5-diphenylisoxazole in argon matrices, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 30巻, 4号, 201704
  74. Paterno-Buchi photochemical [2+2] cycloaddition of aromatic carbonyl compounds with 2-siloxy-1H-pyrrole derivatives(dagger), JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 30巻, 4号, 201704
  75. Direct Detection of a Chemical Equilibrium between a Localized Singlet Diradical and Its sigma-Bonded Species by Time-Resolved UV/Vis and IR Spectroscopy, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56巻, 11号, pp. 2984-2988, 20170306
  76. Control of the Termination Mechanism in Radical Polymerization by Viscosity: Selective Disproportionation in Viscous Media, CHEMISTRY-A EUROPEAN JOURNAL, 23巻, 6号, pp. 1299-1305, 201701
  77. Light-harvesting organogel based on tris(phenylisoxazolyl)benzene, SUPRAMOLECULAR CHEMISTRY, 29巻, 6号, pp. 471-476, 2017
  78. The structure of electronically excited ,-unsaturated lactones, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 29巻, 12号, pp. 718-724, 201612
  79. Using Molecular Architecture to Control the Reactivity of a Triplet Vinylnitrene, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138巻, 45号, pp. 14905-14914, 20161116
  80. Design, Synthesis, and Reaction of pi-Extended Coumarin-based New Caged Compounds with Two-photon Absorption Character in the Near-IR Region, CHEMISTRY LETTERS, 45巻, 10号, pp. 1186-1188, 20161005
  81. Design and Synthesis of a 4-Nitrobromobenzene Derivative Bearing an Ethylene Glycol Tetraacetic Acid Unit for a New Generation of Caged Calcium Compounds with Two-Photon Absorption Properties in the Near-IR Region and Their Application in Vivo, ACS OMEGA, 1巻, 2号, pp. 193-201, 201608
  82. Impact of Diradical Spin State (Singlet vs Triplet) and Structure (Puckered vs Planar) on the Photodenitrogenation Stereoselectivity of 2,3-Diazabicyclo[2.2.1]heptanes, JOURNAL OF PHYSICAL CHEMISTRY B, 120巻, 29号, pp. 7217-7226, 20160728
  83. Computational Study of Cyclobutane-1,3-diylidene Dicarbenes: Ground-State Spin Multiplicity and New Strategy toward the Synthesis of Bicyclo[1.1.0]but-1(3)-enes, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 89巻, 7号, pp. 770-778, 20160715
  84. Biphenalenylidene: Isolation and Characterization of the Reactive Intermediate on the Decomposition Pathway of Phenalenyl Radical, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138巻, 7号, pp. 2399-2410, 20160224
  85. A Puckered Singlet Cyclopentane-1,3-diyl: Detection of the Third Isomer in Homolysis, CHEMISTRY-A EUROPEAN JOURNAL, 22巻, 7号, pp. 2299-2306, 20160212
  86. Design and synthesis of a new chromophore, 2-(4-nitrophenyl)benzofuran, for two-photon uncaging using near-IR light, CHEMICAL COMMUNICATIONS, 52巻, 2号, pp. 331-334, 2016
  87. Intra- and Intermolecular Reactivity of Triplet Sumanenetrione, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 88巻, 11号, pp. 1612-1617, 20151115
  88. Multiple crystal forms of N,N '-diacetylchitobiose deacetylase from Pyrococcus furiosus, ACTA CRYSTALLOGRAPHICA SECTION F-STRUCTURAL BIOLOGY COMMUNICATIONS, 71巻, pp. 657-662, 201506
  89. Direct Detection of a Triplet Vinylnitrene, 1,4-Naphthoquinone-2-ylnitrene, in Solution and Cryogenic Matrices, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137巻, 12号, pp. 4207-4214, 20150401
  90. Electron-spin resonance (ESR) characterization of quintet spin-state bis-nitroxide-bearing cyclopentane-1,3-diyl diradicals, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 28巻, 2号, pp. 116-120, 201502
  91. Photolysis of acetophenone derivatives with alpha-cyclopropyl substituents, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 28巻, 2号, pp. 137-146, 201502
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  3. 2010年, 2010年

招待講演、口頭・ポスター発表等

  1. Photochemical Release of 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) Radical from Caged Nitroxides by Near Infrared Two-photon Irradiation and Its Cytocidal effect on Lung Cancer Cells, Manabu Abe, Asian Photochemistry Conference 2018, 2018年12月17日, 招待, 英語, Asian Photochemistry Association, Taipei
  2. Design and synthesis of NIR two-photon responsive chromophores, Manabu Abe, 14th Korea-Japan Symposium on Frontier Photoscience: Photochemistry, Solar Cells, and Photocatalysts, 2018年10月26日, 招待, 日本語
  3. Is π SIngle Bonding Possible?, Manabu Abe, 24th IUPAC International Conference on Physical Organic Chemistry, 2018年06月06日, 招待, 日本語
  4. Design and synthesis of NIR two-photon responsive chromophores, Manabu Abe, International Symposium on Caged Compounds, 2018年03月09日, 招待, 日本語
  5. Unusually Long-wavelength Emissions of Bicyclo[2.1.0]pentanes: New Insight unto C–C Bond Homolysis, Manabu Abe, Molecular Biradicals: Structure, Properties, and Reactivity, 2018年03月01日, 招待, 日本語
  6. Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light, Manabu Abe, International Conference on Chemical Science and Technology, 2018年02月24日, 招待, 英語
  7. Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light, Manabu Abe, Korea-Japan Frontier PhotoSceince (KJFP-2017), 2017年10月26日, 招待, 英語
  8. Is π SIngle Bonding Possible?, Manabu Abe, Japan-Taiwan Bilateral Conference on Molecular Architecture, 2017年10月15日, 招待, 日本語
  9. Nitrogen Atom Effect on Reactivity of 1,3-Diradicals, Manabu Abe, European Symposium on Organic Reactivity, 2017年09月05日, 招待, 英語
  10. Is π SIngle Bonding Possible?, Manabu Abe, Herbert Mayr’s 70th Birthday, 2017年08月03日, 招待, 英語
  11. 2017年07月18日, 招待, 英語
  12. 2017年06月18日, 招待, 英語
  13. 2017年04月02日, 招待, 英語
  14. 2016年11月26日, 招待, 英語
  15. 2016年09月26日, 招待, 英語
  16. 2016年08月01日, 招待, 英語
  17. 2016年07月03日, 招待, 英語
  18. Selective Formation of Oxetanes via Radical Ion Pairs and Triplet 1,4-Diradicals, 安倍 学, First Japan-Singapore Bilateral Symposium on Catalysis, Singapore, 2008年01月, 招待, 日本語
  19. Photochemical Generation of Long-lived Singlet Diradicals and Their Reactivity, 安倍 学, 2007 Korean-Japan Bilateral Symposium on Frontier Photoscience (2007KJFP), Gyeongju, Korea, 2007年11月, 招待, 日本語
  20. Selective Formation of Oxetanes via Radical Ion Pairs and Triplet 1,4-Diradicals, 安倍 学, Lecture at National Chiao Tung University, Hsinchu, Taiwan, 2007年09月, 招待, 日本語
  21. Generation of Singlet 1,3-Diradicals and Their Chemistry, 安倍 学, Lecture at National Taiwan University, Taipei, Taiwan, 2007年09月, 招待, 日本語
  22. Denitrogenation Reaction of 4-Spirocyclopropane-1-Pyrazolines: Dynamics Effects?, 安倍 学, 4th Heron Island Conference, 'Synthesis and Mechanism: Reactive Intermediates and Unusual Molecules, Australia, 2007年07月, 招待, 日本語
  23. Heteroatom Effects on the Reactivity of Cyclopentane-1,3-Diyls, 安倍 学, The Post ISNA-12 Symposium on Physical Organic Chemistry in Fukuoka, Fukuoka, 2007年07月, 招待, 日本語
  24. Denitrogenation Mechanism of Cyclic Azoalkanes: Electronic Effect and Dynamics Effect, 安倍 学, Lecture at National Tsing-Hua University, Hsinchu, Taiwan, 2007年07月, 招待, 日本語
  25. Selective Formation of Oxetanes via Radical Ion Pairs and Triplet 1,4-Diradicals, 安倍 学, Lecture at Murcia University, 2007年02月, 招待, 日本語
  26. Selective Formation of Oxetanes via Radical Ion Pairs and Triplet 1,4-Diradicals, 安倍 学, Lecture at Universit?t Giessen, 2007年01月, 招待, 日本語
  27. The Chemistry of 1,3-Diradicals: Spin Control and Reactivity, 安倍 学, Lecture at Ruhr-Universit?t Bochum, Germany, 2007年01月, 招待, 日本語
  28. The Chemistry of 1,3-Diradicals: Spin Control and Reactivity, 安倍 学, Lecture at Universit?t Erlangen-Nuernberg, Germany, 2007年01月, 招待, 日本語
  29. Selective Formation of Oxetanes via Radical Ion Pairs and Triplet 1,4-Diradicals, 安倍 学, Lecture at LMU Muenchen, Germany, 2007年01月, 招待, 日本語
  30. The Chemistry of 1,3-Diradicals: Spin Control and Reactivity, 安倍 学, Lecture at Universit?t Ulm, Germany, 2007年01月, 招待, 日本語
  31. Selective Formation of Oxetanes via Radical Ion Pairs and Triplet 1,4-Diradicals, 安倍 学, Lecture at TU Muenchen, Germany, 2007年01月, 招待, 日本語
  32. The Chemistry of 1,3-Diradicals: Spin Control and Reactivity, 安倍 学, Lecture at Universit?t Koeln, Germany, 2007年01月, 招待, 日本語
  33. Selective Formation of Oxetanes via Radical Ion Pairs and Triplet 1,4-Diradicals, 安倍 学, Lecture at Universit?t Siegen, Germany, 2007年01月, 招待, 日本語
  34. ビラジカル化学の新展開, 安倍 学, 第18回基礎有機化学連合討論会, 2006年10月, 招待, 日本語
  35. Heteroatom Effects on the Reactivity of Cyclopentane-1,3-diyls, 安倍 学, Porquerolles International Conference on Reactive Intermediates and Unusual Molecules, 2006年09月, 招待, 日本語
  36. 反応性中間体の化学:ビラジカルの場合, 安倍 学, 有機反応若手の会, 2006年07月, 招待, 日本語
  37. ビラジカル化学の新展開:スピン多重度制御と反応性, 安倍 学, 物理有機化学ミニシンポジウム「有機反応論の最近の動向」, 2006年03月, 招待, 日本語
  38. Role of Triplet 1,4-Diradical in the Selectivity of the Paterno-Buchi Reactions, 安倍 学, The 2005 International Chemical Congress of Pacific Basin Societies, 2005年12月, 招待, 日本語
  39. Substituent Effects on the Reactivity of Singlet Cyclopentane-1,3-diyld and the Denitrogenation Mechanism of 2,3-Diazabicyclo[2.2.1]hept-2-enes, 安倍 学, Kyusyu International Symposium on Physical Organic Chemistry (KISPOC-XI), 2005年09月, 招待, 日本語
  40. Experimental Evidence for the Hyperconjugative Resonance Stabilization in Singlet 1,3-diyls, 安倍 学, International Symposium on Reactive Intermediates and Unusual Molecules (2005) in Edingurg, 2005年08月, 招待, 日本語
  41. 反応性中間体の化学:ビラジカルの場合, 安倍 学, 九州大学工学部セミナー, 2005年03月, 招待, 日本語
  42. Heteroatom Effects on the Reactivity of Singlet 1,3-diyls, 安倍 学, International Symposium on Reactive Intermediates and Unusual Molecules, 2004年07月, 招待, 日本語
  43. Alkoxy Group Effect on the Singlet-Triplet Energy Gap in Cyclopentane-1,3-diyls, 安倍 学, International Symposium on Reactive Intermediates and Unusual Molecules in 2003, 2003年08月, 招待, 日本語
  44. 一重項1,3-ビラジカルの発生とその化学的性質-新規分子構造の創製-, 安倍 学, 日本化学会第82秋季年会・若い世代の特別講演, 2002年09月, 招待, 日本語
  45. 一重項ビラジカルの発生とその化学的性質, 安倍 学, 白鷺セミナー, 2001年11月, 招待, 日本語
  46. 局在化ビラジカル化学の新展開:一重項ビラジカルに魅せられて, 安倍 学, 第32回中部化学関係学協会支部連合秋季大会, 2001年10月, 招待, 日本語
  47. 2位上に酸素官能基を有する局在化1,3-ジラジカルの化学, 安倍 学, 有機素反応研究会, 2000年08月, 招待, 日本語
  48. 1,3-ビラジカルのスピン多重度に及ぼす酸素原子効果, 安倍 学, 京都工芸繊維大学学術講演会, 1998年07月, 招待, 日本語

受賞

  1. 2020年, 広島大学長賞, 広島大学
  2. 2020年03月23日, 公益社団法人日本化学会 学術賞, 公益社団法人日本化学会会長, 炭素-炭素π単結合の創製
  3. 2010年, オーストラリア化学会誌 Lectureship Award, オーストラリア化学会誌
  4. 2007年, The Zimmer Award, シンシナティ大学
  5. 2007年, 野副記念奨励賞, 基礎有機化学会, 長寿命一重項ビラジカルの発生:構造と反応性に関する研究
  6. 2007年, Chemistry Research Promotion Center, Taiwan Lectureship Award, Chemistry Research Promotion Center, Taiwan
  7. 2005年, 有機合成奨励賞, 有機合成化学協会, 反応性中間体の反応挙動精査に基づく合成反応の開発
  8. 2004年, The Award for the Best Presentation on the 1st International Symposium in Chemistry at Gumma (2004), 群馬国際化学会議実行委員長・西村淳, Heteroatom Effects on the Reactivity of Cyclopentane-1,3-Diyls

取得

  1. 特許権, 6366269, 2018年07月13日, ケージド化合物及びその製造方法
  2. 特許権, 6797410, 2020年11月20日, ケージドラジカルプローブ化合物及びその製造方法

外部資金

競争的資金等の採択状況

  1. 科学研究費助成事業(基盤研究(B)), 可視光応答性π単結合(C-π-C)化合物の長寿命化に基づく新しい分子素材の開発, 2021年, 2023年
  2. 戦略的創造研究推進事業(CREST), 電子触媒反応機構の解明, 2018年10月01日, 2024年03月31日
  3. 科学研究費助成事業(挑戦的研究(萌芽)), 近赤外2光子励起を用いた1細胞内での生物活性物質のin-situ合成, 2020年, 2021年
  4. 戦略的創造研究推進事業(新技術シーズ創出_CREST), 電子触媒反応機構の判明, 2018年10月01日, 2020年03月31日
  5. 戦略的創造研究推進事業(新技術シーズ創出_CREST), 電子触媒反応機構の判明, 2018年10月01日, 2021年03月31日
  6. 戦略的創造研究推進事業(CREST), 電子触媒反応機構の判明, 2018年10月01日, 2023年03月31日
  7. 科学研究費助成事業(基盤研究(B)), 近赤外2光子感応性新規光解離性保護基の合成と反応:ドラッグデリバリーへの基盤研究, 2017年, 2019年
  8. 科学研究費助成事業(特別研究員奨励費), 局在化1、3-ジラジカルの構造と反応性に関する研究, 2017年, 2019年
  9. 科学研究費助成事業(挑戦的萌芽研究), 最も曲がった曲面π電子系構造の合成とπ電子・光物性に及ぼす曲面効果の解明, 2016年, 2017年
  10. 科学研究費助成事業(新学術領域研究(研究領域提案型)), 光感応性π単結合化合物の創製と機能, 2012年, 2016年
  11. 科学研究費助成事業(新学術領域研究(研究領域提案型)), 炭素-炭素π単結合の創製・集積化による新規π電子空間の構築, 2011年, 2012年
  12. 戦略的創造研究推進事業(CREST), 光制御実験用分子合成, 2010年10月01日, 2016年03月31日
  13. 科学研究費助成事業(新学術領域研究(研究領域提案型)), 炭素―炭素π1重結合の創製・集積化による新規π電子系の構築, 2009年, 2010年
  14. 科学研究費助成事業(特定領域研究), ポリラジカルのスピン多重度制御とその機能に及ぼす元素相乗効果, 2008年, 2009年
  15. 科学研究費助成事業(特定領域研究), 小分子カルボニル化合物の活性化によるオキセタン類の選択的合成と高度分子変換反応, 2007年, 2008年
  16. 科学研究費助成事業(特定領域研究), 元素相乗効果に基づくポリラジカルのスピン整列とその機能化, 2007年, 2007年
  17. 科学研究費助成事業(基盤研究(B)), 開殻系分子の安定化に基づく新規分子変換反応の開発と機能化, 2007年, 2010年
  18. 民間からの助成金, 国際交流基金, 2006年
  19. 民間からの助成金, 光環化不斉非対称化に基づくオキセタン類の不斉合成, 2005年
  20. 科学研究費助成事業(基盤研究(B)), 高周期典型元素がもたらすビラジカル化学の新展開:新しい分子構造の構築, 2005年, 2006年
  21. 科学技術振興調整費, 新しい結合様式の創製:新規分子構造の構築, 2003年
  22. 科学研究費助成事業(特定領域研究(A)), 局在化ビラジカル種のスピン多重度制御, 2000年, 2001年
  23. 科学研究費助成事業(特定領域研究(C)), 1,2,4,5-テトラオキサシクロアルカンを標的とする新生血管産生阻害剤の開発, 2000年, 2000年
  24. 科学研究費助成事業(奨励研究(A)), 高反応性オキセタンの位置及び立体選択的合成法確立への挑戦, 2000年, 2001年
  25. 科学研究費助成事業(特定領域研究(A)), 新生血管産生阻害作用をもつ環状過酸化物の探索, 1999年, 1999年
  26. 科学研究費助成事業(特定領域研究(A)), 抗マラリア特性をもつ水溶性環状過酸化物の合成, 1999年, 1999年
  27. 科学研究費助成事業(特定領域研究(A)), 高次スピン分子のスピン多重度制御, 1999年, 1999年
  28. 科学研究費助成事業(奨励研究(A)), 高反応性オキセタン誘導体の立体選択的合成法の開発とその反応性に関する研究, 1998年, 1999年
  29. 科学研究費助成事業(特定領域研究(A)), 抗がん作用をもつ環状過酸化物の探索, 1998年, 1998年
  30. 科学研究費助成事業(特定領域研究(A)), 抗マラリア特性をもつ環状過酸化物の新規合成反応の開発, 1998年, 1998年

社会活動

委員会等委員歴

  1. 非常勤講師, 2022年11月, 2022年12月, 岡山大学
  2. 顧問, 2021年06月, 2022年03月, 一般社団法人広島県発明協会
  3. 広島の拠点性強化に向けた懇話会ワーキンググループ会議委員, 2021年04月, 2022年03月, 広島市企画総務局企画調整部
  4. 非常勤講師, 2020年09月, 2021年03月, 東京工業大学
  5. 非常勤講師, 2019年04月, 2020年03月, 大阪大学
  6. 非常勤講師, 2018年04月, 2018年09月, 大阪府立大学
  7. 光化学協会理事, 2017年09月01日, 光化学協会
  8. 2016年09月10日
  9. 2016年05月01日
  10. 非常勤講師, 2015年10月, 2016年03月, 大阪市立大学
  11. 基礎有機化学会理事, 2015年09月01日, 基礎有機化学会
  12. 2012年09月01日
  13. 分子情報ダイナミクス研究会会長, 2007年04月01日
  14. 反応性中間体の国際会議組織委員, 2003年09月01日, 反応性中間体の国際会議組織
  15. 非常勤講師, 大阪市立大学

学術会議等の主催

  1. 分子情報ダイナミクス研究会, 研究会事務局, 2007年08月
  2. 2014年04月, 2014年04月
  3. 第27会基礎有機化学討論会, 2016年09月, 2016年09月
  4. 2015年12月, 2015年12月
  5. 2016年04月, 2016年04月
  6. 有機反応若手の会, 2015年07月, 2015年07月
  7. 2016年04月, 2016年04月
  8. 2017年03月, 2017年03月
  9. 2016年12月, 2016年12月
  10. 2016年03月, 2016年03月
  11. 2014年12月, 2014年12月

その他社会貢献活動(広大・部局主催含)

  1. 原子間結合に基づく美しい分子の世界, 広島大学入学センター, 平成19年度広島大学模擬授業, 2007年/11月, 2007年/11月, 高校生

学術雑誌論文査読歴

  1. 2005年, ARKIVOC (Archive for Organic Chemistry), その他
  2. 2006年, ARKIVOC (Archive for Organic Chemistry), その他
  3. 2007年, ARKIVOC (Archive for Organic Chemistry), その他