Hiroshi Fukuoka

Last Updated :2024/04/03

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Assistant Professor
E-mail
hfukuokahiroshima-u.ac.jp
Self-introduction
Hiroshi Fukuoka received PH.D. Degree from The University of Tokyo in 1996. He joined the Professor Yamanaka group at the Hiroshima University as an Assistant Professor in 1996. He currently belongs to the Graduate School of Advanced Science and Engineering at Hiroshima University. His research area includes inorganic chemistry, high-pressure chemistry, crystallography, and functional material science. His research focuses on superconductors having highly covalent networks such as clathrate and skutterudite compounds. He also studies a new type of proton conductor for the use of fuel cells.

Basic Information

Academic Degrees

  • Doctor of Science, The University of Tokyo
  • Master of Science, The University of Tokyo

Educational Activity

  • [Bachelor Degree Program] School of Engineering : Cluster 3(Applied Chemistry, Biotechnology and Chemical Engineering) : Program of Applied Chemistry
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Applied Chemistry Program
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Smart Innovation Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Applied Chemistry Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Smart Innovation Program

Research Fields

  • Chemistry;Materials chemistry;Inorganic industrial materials

Research Keywords

  • Superconductor
  • High pressure synthesis
  • fuel cell
  • proton conductor

Affiliated Academic Societies

Educational Activity

Course in Charge

  1. 2024, Liberal Arts Education Program1, 2Term, General Chemistry
  2. 2024, Liberal Arts Education Program1, 2Term, General Chemistry
  3. 2024, Undergraduate Education, Second Semester, Basic Experiments in Chemistry
  4. 2024, Undergraduate Education, 4Term, Exercises in Physical Chemistry
  5. 2024, Undergraduate Education, Year, Graduation Thesis
  6. 2024, Graduate Education (Master's Program) , 1Term, Special Exercises on Applied Chemistry A
  7. 2024, Graduate Education (Master's Program) , 1Term, Special Exercises on Applied Chemistry A
  8. 2024, Graduate Education (Master's Program) , 2Term, Special Exercises on Applied Chemistry A
  9. 2024, Graduate Education (Master's Program) , 2Term, Special Exercises on Applied Chemistry A
  10. 2024, Graduate Education (Master's Program) , 3Term, Special Exercises on Applied Chemistry B
  11. 2024, Graduate Education (Master's Program) , 3Term, Special Exercises on Applied Chemistry B
  12. 2024, Graduate Education (Master's Program) , 4Term, Special Exercises on Applied Chemistry B
  13. 2024, Graduate Education (Master's Program) , 4Term, Special Exercises on Applied Chemistry B
  14. 2024, Graduate Education (Master's Program) , Academic Year, Special Study on Applied Chemistry
  15. 2024, Graduate Education (Master's Program) , Academic Year, Special Study on Applied Chemistry

Research Activities

Academic Papers

  1. High-pressure synthesis and transport properties of a new binary germanide, SrGe6-delta (delta congruent to 0.5), with a cagelike structure, INORGANIC CHEMISTRY, 44(5), 1460-1465, 20050307
    Link to Paper Search Results by DOI
  2. Preparation and single-crystal structure of a new high-pressure modification of BaAl2Si2, HIGH PRESSURE RESEARCH, 24(4), 481-490, 200412
    Link to Paper Search Results by DOI
  3. High-pressure Raman study of the ba-doped silicon clathrate Ba24Si100 up to 27 GPa, PHYSICAL REVIEW B, 71(9), 200503
    Link to Paper Search Results by DOI
  4. Compton scattering study of the silicon clathrate Ba(8)Si(46): Experiment and theory, PHYSICAL REVIEW B, 71(12), 200503
    Link to Paper Search Results by DOI
  5. Role of Ag doping in Ba8Si46 compounds, PHYSICAL REVIEW B, 72(1), 200507
    Link to Paper Search Results by DOI
  6. Superconductivity and physical properties of Ba24Si100 determined from electric transport, specific-heat capacity, and magnetic susceptibility measurements, PHYSICAL REVIEW B, 72(14), 200510
    Link to Paper Search Results by DOI
  7. Electronic structure and vibrational properties of Ba8Si46-n, Ba8AgnSi46-n, and Ba8AunSi46-n, PHYSICAL REVIEW B, 72(15), 200510
    Link to Paper Search Results by DOI
  8. Specific heat capacity and magnetic susceptibility of superconducting Ba24Si100, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 67(5-6), 1334-1337, 2006
    Link to Paper Search Results by DOI
  9. High-Pressure Synthesis, Structure, and Electrical Property of Iodine-Filled Skutterudite I0.9Rh4Sb12-First Anion-Filled Skutterudite, CHEMISTRY OF MATERIALS, 22(1), 47-51, 20100112
    Link to Paper Search Results by DOI
  10. Sp(3)-network superconductors made from IVth-group elements, SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 7, S88-S93, 2006
    Link to Paper Search Results by DOI
  11. Raman study of semiconductor clathrates under high pressure, PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 244(1), 352-356, 200701
    Link to Paper Search Results by DOI
  12. High-pressure Raman study on type-I germanium clathrate, PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 244(1), 392-396, 200701
    Link to Paper Search Results by DOI
  13. Missing superconductivity in BaAlSi with the AlB2 type structure, PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 451(1), 19-23, 20070101
    Link to Paper Search Results by DOI
  14. High-pressure Raman study of Ba doped type-III germanium clathrate Ba24Ge100 up to 26 GPa, JOURNAL OF APPLIED PHYSICS, 101(11), 20070601
    Link to Paper Search Results by DOI
  15. Raman and x-ray diffraction studies of Ba doped germanium clathrate Ba8Ge43 at high pressures, JOURNAL OF APPLIED PHYSICS, 101(6), 20070315
    Link to Paper Search Results by DOI
  16. High-pressure synthesis and structures of new barium chromium sulfides, BaCr4S7 and Ba2Cr5S10, with new type face-sharing CrS6 structure units, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 80(11), 2170-2176, 20071115
    Link to Paper Search Results by DOI
  17. High-pressure synthesis and structure of new filled skutterudite compounds with Ge-substituted host network; LnRh(4)Sb(9)Ge(3), Ln = La, Ce, Pr, and Nd, JOURNAL OF ALLOYS AND COMPOUNDS, 461(1-2), 547-550, 20080811
    Link to Paper Search Results by DOI
  18. High-pressure synthesis and structures of lanthanide germanides of LnGe(5) (Ln = Ce, Pr, Nd, and Sm) isotypic with LaGe5, JOURNAL OF SOLID STATE CHEMISTRY, 182(8), 2024-2029, 200908
    Link to Paper Search Results by DOI
  19. Mechanofluorochromism of a Series of Benzofuro[2,3-c]oxazolo[4,5-a]-carbazole-Type Fluorescent Dyes, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 5321-5326, 200911
    Link to Paper Search Results by DOI
  20. Synthesis and structures of samarium platinum germanides: SmPtGe2 and Sm2Pt3Ge5, JOURNAL OF ALLOYS AND COMPOUNDS, 487(1-2), 712-715, 20091113
    Link to Paper Search Results by DOI
  21. Interplay between thermoelectric and structural properties of type-I clathrate K8Ga8Sn38 single crystals, PHYSICAL REVIEW B, 81(16), 20100415
    Link to Paper Search Results by DOI
  22. Preparation and Structures of Lanthanoid Germanides, PrGe3.36, NdGe3.25, and TmGe3 with Double Square Ge-Mesh Structures, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 83(4), 323-327, 20100415
    Link to Paper Search Results by DOI
  23. Electron-Phonon Interactions of Si-100 and Ge-100 Superconductors with Ba Atoms Inside, PHYSICAL REVIEW LETTERS, 105(17), 20101020
    Link to Paper Search Results by DOI
  24. ★, High-Pressure Synthesis and Superconductivity of a New Binary Lanthanum Germanide LaGe3 with Triangular Ge-3 Cluster Units, INORGANIC CHEMISTRY, 50(9), 3901-3906, 20110502
    Link to Paper Search Results by DOI
  25. ★, High-Pressure Synthesis and Superconductivity of a New Binary Barium Germanide BaGe3, INORGANIC CHEMISTRY, 50(13), 6372-6377, 20110704
    Link to Paper Search Results by DOI
  26. Quasi One-Dimensional Organic Superconductor MDT-TSFoAuI2 with Tc = 4.5 K at Ambient Pressure, Angew. Chem. Int. Ed., 40(6), 1122-1125, 20010301
  27. Structural properties and thermodynamic stability of Ba-doped silicon type-I clathrates systnesized under high pressures, Phys. Rev. B, 64, 045206, 20010401
  28. Preparation and crystal structure of chromium silicon selecide containing a B12 icosahedron with a tunnel structure, J.Org. Met. Chem., 611, 547, 20000401
  29. Preparation and Structural Study of a New Ternary Gold Chromium Sulfide, AuCrS2, J.Solid State Chem.=, 148, 487, 19990401
  30. ★, Superconductivity of Alkali Metal Intercalated Niobate with a Layered Perovskite Structure, Chemistry Letters, 8, 703, 19970401
  31. Preparation and Crystal Structure of Ruthenium Metaphosphate Ru(PO3)3 with an 8-fold Superstructure.Analysis of Structural Frustration with a Simple Model, Inorganic Chemistry, 36, 4172, 19970401
  32. Mixed-Valence Ruthenium Diphosphates with a Tunnel Structure : ARu(P2O7)2 (A = Li,Na,Ag,and Cu) and Ru2(P2O7)2, Bulletin of the Chemical Society of Japan, 70, 2703, 19970401
  33. Synthesis and Crystal Structure of a New Ruthenium Silicophosphate : RuP3SiO11, Journal of Solid State Chemistry, 121, 247, 19960401
  34. New Polymorphs of RuP3O9 : Cyclo-hexaphosphate Ru2P6O18 and Metaphosphate Ru(PO3)3 with a Novel Structure, J.Solid State Chem.=, 119, 107, 19950401
  35. Preparation of Cubic Niobium Pyrophosphate Containing Nb(V) and Topotactic Extraction of Phosphorus Atoms, Journal of Solid State Chemistry, 119, 98, 19950401
  36. An X-ray and Electron Diffraction Study of the Channel-Type Composite Crystal Sn1-pCr2S4-p, J.Solid State Chem.=, 115, 7, 19950401
  37. Diffuse Scattering from the Channel-Type Composite Crystals Pb1-pCr2S4-p, Sr1-pCr2S4-p and Ba1-pCr2S4-p (p ~ 0.3), Jpn.J.Appl.Phy, 32, 423, 19930401
  38. High-Pressure Synthesis and Crystal Structures of b-MNX (M = Zr, Hf; X = Br, I), J.Solid State Chem.=, 162, in press, 20010401
  39. New Strontium Polysulfides, SrS3, and Sr2(OH)2S4-10H2O, obtained by the high-pressure treatment of a Sr-S mixture, Inorganic Chemistry, 43, 5780-5784, 20040401
  40. High-pressure synthesis and properties of a cerium germanide CeGe3 with the cubic Cu3Au type structure, Chemistry Letters, 33(10), 1334-1335, 20040401
  41. Synthesis and superconductivity of barium deficient type I silicon clathrate compounds, Ba8-xSi46, Journal of Physics and Chemistry of Solids, 65, 333-336, 20040401
  42. High-pressure synthesis of a new silicon clathrate superconductor, Ba8Si46, INORGANIC CHEMISTRY, 39(1), 56-58, 20000110
    Link to Paper Search Results by DOI
  43. High-pressure synthesis of the polymorph of layer structured compounds MNX (M = Zr, Hf; X = Cl, Br, I), INORGANIC CHEMISTRY, 39(4), 806-809, 20000221
    Link to Paper Search Results by DOI
  44. Crystal structure of a layered perovskite niobate KCa2Nb3O10, JOURNAL OF SOLID STATE CHEMISTRY, 151(1), 40-45, 200004
    Link to Paper Search Results by DOI
  45. ★, Preparation and structure of a new germanium clathrate, Ba24Ge100, JOURNAL OF SOLID STATE CHEMISTRY, 151(1), 117-121, 200004
    Link to Paper Search Results by DOI
  46. ★, High-pressure synthesis and structure of a new silicon clathrate Ba24Si100, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 611(1-2), 543-546, 20001006
    Link to Paper Search Results by DOI
  47. Substitution and cointercalation effects on superconducting electron-doped layer structured metal nitride halides, PHYSICA C, 341, 699-702, 200011
    Link to Paper Search Results by DOI
  48. Electronic structure and superconducting gap of silicon clathrate Ba8Si46 studied with ultrahigh-resolution photoemission spectroscopy, PHYSICAL REVIEW B, 64(17), 20011101
    Link to Paper Search Results by DOI
  49. Crystal structure and ionic conductivity of ruthenium diphosphate ARu(2)(P2O7)(2), A = Li, Na, and Ag, with a tunnel structure, MATERIALS RESEARCH BULLETIN, 38(6), 991-1001, 20030526
    Link to Paper Search Results by DOI
  50. ★, High-pressure synthesis and superconductivity of LaGe5 containing a tunnel germanium network, PHYSICAL REVIEW B, 67(9), 20030301
    Link to Paper Search Results by DOI
  51. High-pressure Raman study of Ba doped silicon clathrate, PHYSICAL REVIEW LETTERS, 90(15), 20030418
    Link to Paper Search Results by DOI
  52. Superconductivity of metal deficient silicon clathrate compounds, Ba8-xSi46 (0 < x <= 1.4), INORGANIC CHEMISTRY, 42(9), 2933-2937, 20030505
    Link to Paper Search Results by DOI
  53. ★, Superconductivity and crystal structure of the solid solutions of Ba8-delta Si46-xGex (0 <= x <= 23) with Type I clathrate structure, JOURNAL OF SOLID STATE CHEMISTRY, 175(2), 237-244, 200311
    Link to Paper Search Results by DOI
  54. High-pressure synthesis and structures of novel chromium sulfides, Ba3CrS5 and Ba3Cr2S6 with one-dimensional chain structures, JOURNAL OF SOLID STATE CHEMISTRY, 176(1), 206-212, 20031115
    Link to Paper Search Results by DOI
  55. High-pressure Raman study of the iodine-doped silicon clathrate I8Si44I2, PHYSICAL REVIEW B, 68(21), 200312
    Link to Paper Search Results by DOI
  56. Mechanofluorochromism of carbazole-type D-pi-A fluorescent dyes, TETRAHEDRON, 68(2), 529-533, 20120114
    Link to Paper Search Results by DOI
  57. Structure and Chemical Bonding of Binary Ytterbium Germanides, Yb3Ge5 and YbGe3, Prepared by High-Pressure and High-Temperature Reactions, JOURNAL OF PHYSICAL CHEMISTRY C, 116(3), 2153-2158, 20120126
    Link to Paper Search Results by DOI
  58. Synthesis of Carbazole-Type D-pi-A Fluorescent Dyes Possessing Solid-State Red Fluorescence Properties, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 4853-4859, 201209
    Link to Paper Search Results by DOI
  59. Magnetization of conductive polymer polyaniline during the electro-oxidation in the presence of chloranil, MATERIALS LETTERS, 84, 162-164, 20121001
    Link to Paper Search Results by DOI
  60. Structural and thermoelectric properties of Cu6Fe4Sn12Se32 single crystal, JOURNAL OF ALLOYS AND COMPOUNDS, 564, 91-94, 20130705
    Link to Paper Search Results by DOI
  61. Photocatalytic decomposition of 2-propanol and acetone in air by nanocomposites of pre-formed TiO2 particles and mesoporous silica, JOURNAL OF POROUS MATERIALS, 20(4), 693-699, 201308
    Link to Paper Search Results by DOI
  62. Solid-state fluorescence properties and mechanofluorochromism of D-pi-A pyridinium dyes bearing various counter anions, TETRAHEDRON, 69(29), 5818-5822, 20130722
    Link to Paper Search Results by DOI
  63. New Polymorph of Mo3S4 Prepared using a High-pressure Synthesis Technique: Crystal Structure, Electronic Property, and Band Calculation, INORGANIC CHEMISTRY, 52(14), 7918-7922, 20130715
    Link to Paper Search Results by DOI
  64. Synthesis of Biodegradable Thermoplastic Elastomers from epsilon-Caprolactone and Lactide, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 53(3), 489-495, 20150201
    Link to Paper Search Results by DOI
  65. Cobalt-catalyzed intermolecular stereoselective bisbenzylation of alkynes, TETRAHEDRON LETTERS, 56(13), 1735-1737, 20150325
    Link to Paper Search Results by DOI
  66. BODIPY dye possessing solid-state red fluorescence and green metallic luster properties in both crystalline and amorphous states, RSC ADVANCES, 4(3), 1163-1167, 201401
    Link to Paper Search Results by DOI
  67. High-Pressure Synthesis, Structures, and Properties of New Germanides, Na3Pt4Ge13 and Na3Pt2Ge14, JOURNAL OF NANOELECTRONICS AND OPTOELECTRONICS, 10(1), 147-150, 201502
    Link to Paper Search Results by DOI
  68. High-Pressure Synthesis and Electronic Structure of a New Superconducting Strontium Germanide (SrGe3) Containing Ge-2 Dumbbells, INORGANIC CHEMISTRY, 54(15), 7433-7437, 20150803
    Link to Paper Search Results by DOI
  69. Electro-oxidation of polyaniline in the presence of electronic acceptors and the magnetic properties of the resulting polyaniline, THIN SOLID FILMS, 618, 165-171, 20161101
    Link to Paper Search Results by DOI
  70. NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 13, 1816-1822, 20170830
    Link to Paper Search Results by DOI
  71. High-Pressure Synthesis, Structure, and Magnetic Properties of Ge-Substituted Filled Skutterudite Compounds; Ln(x)Co(4)Sb(12-y)Ge(y), Ln = La, Ce, Pr, and Nd, CRYSTALS, 7(12), 381-381, 201712
    Link to Paper Search Results by DOI
  72. High-pressure Synthesis of an Anion-filled Skutterudite Compound I0.9Ir4Sb12, CHEMISTRY LETTERS, 47(4), 408-410, 201804
    Link to Paper Search Results by DOI
  73. Metamagnetic crossover in the quasikagome Ising Kondo-lattice compound CeIrSn, PHYSICAL REVIEW B, 98(15), 20181029
    Link to Paper Search Results by DOI

Invited Lecture, Oral Presentation, Poster Presentation

  1. Structure and Electrical Properties of Ge-substituted Rhodium and Cobalt Antimony Skutterudites, Hiroshi Fukuoka, CC3DMR 2016 (Collaborative Conference on 3D and Materials Research 2016), 2016/06/20, With Invitation, English, Incheon Seoul Korea
    Related URL
  2. Bonding and Electronic Structures of Electropositive metal Germanides Prepared by High-pressure Synthesis Containing Germanium with Unusual Coordination Numbers, Hiroshi. Fukuoka, Kazuya Baba, Mayumi Yoshikawa, Fumiko Ohotsu, Daisuke Saito, and Momoko Harada, PACIFICHEM 2015, 2015/12/15, Without Invitation, English
    Related URL
  3. High-Pressure Synthesis and Electrical Properties of Ternary Electropositive Metal Germanides, T. Nishikawa, H. Fukuoka, and K. Inumaru, PACIFICHEM 2015, 2015/12/15, Without Invitation, English
    Related URL
  4. Crystal Structures, Band Structures and Electrical Properties of Binary Germanides of Electropositive Elements Prepared by High-Pressure and High-Temperature Synthesis, H. Fukuoka, K. Baba, M. Yoshikawa, F. Ohtsu, D. Saito, D. Matsumura, K. Yoshii, International Conference on High-pressure science and Technology: Joint AIRAPT-25 & EHPRG-53, 2015/08/31, Without Invitation, English, Madrid, Spain
  5. High-Pressure Synthesis and Electronic Structure of a Superconducting Binary Strontium Germanide SrGe3, T. Nishikawa, H. Fukuoka, K. Inumaru, International Conference on High-Pressure Science and Technology, Joint AIRAPT-25 & EHPRG-53, 2015/08/31, Without Invitation, English, Madrid Spain
  6. High-pressure synthesis, structures, and properties of new germanides, H. Fukuoka, D. Saito, Collaborative Conference on 3D and Materials Research (CC3DMR) 2014, 2014/06/24, With Invitation, English, Inchon, Korea
  7. High-Pressure Synthesis and Properties of Rhodium and Cobalt Antimony Skutterudite Compounds, Hiroshi Fukuoka, CCMR2017, 2017/06/26, With Invitation, English, Jeju, South Korea
  8. Synthesis, Crystal Structures, and Band Structures of Ternary Chromium Sulfides Prepared by High-Pressure Synthesis, Hiroshi Fukuoka, Collaborative Conference on Materials Research 2018, 2018/06/25, With Invitation, English, Incheon/Seoul, South Korea
    Related URL
  9. Synthesis, Crystal Structures, and Band Structures of Ternary Chromium Sulfides Prepared by High-Pressure Synthesis, Hiroshi Fukuoka, CCMR2018, 2018/06/27, With Invitation, English, CCMR2018, Korea Seoul / incheon
    Related URL
  10. High-Pressure Synthesis and Structure of Chromium Sulfides, Hiroshi Fukuoka, 2019/03/04, Without Invitation, English

Awards

  1. 2010/04/15, BCSJ Award Article, Chemical Society of Japan, Preparation and Structures of Lanthanoid Germanides, PrGe3.36, NdGe3.25 and TmGe3 with Double Square Ge?Mesh Structures

Patented

  1. Patent, JP4932774, 2012/02/24

External Funds

Acceptance Results of Competitive Funds

  1. KAKENHI, 2012, 2014
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  2. KAKENHI, Development of function-hierarchical materials under unique reaction fields and application of their electronic and molecular functions, 2008, 2011
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  3. KAKENHI, Synthesis and properties of novel metallic compounds composed of covalent networks, 2008, 2010
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  4. KAKENHI, 2006, 2007
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  5. KAKENHI, 2006, 2007
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  6. KAKENHI, 2004, 2005
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  7. KAKENHI, 2004, 2005
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  8. KAKENHI, 1997, 1998
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  9. KAKENHI, 2016, 2018

Social Activities

Organizing Academic Conferences, etc.

  1. 2017 annual meating　of the crystallographic society of Japan, 2017/01, 2018/03
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  2. 2017/07, 2018/03
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