安倍 学MANABU ABE

Last Updated :2018/11/01

所属・職名
大学院理学研究科 分子反応化学講座 教授
ホームページ
メールアドレス
mabehiroshima-u.ac.jp
その他連絡先
東広島市鏡山一丁目3番1号 C309広島大学大学院理学研究科化学専攻
TEL:082-424-7432 FAX:082-424-7432
自己紹介
光化学のエキスパート

基本情報

主な職歴

  • 1995年04月01日, 2000年08月01日, 大阪大学, 助手
  • 2000年08月01日, 2006年05月31日, 大阪大学, 講師
  • 2006年06月01日, 2007年03月31日, 大阪大学, 助教授
  • 2005年10月01日, 2006年03月31日, 九州大学, 先導物質化学研究所, 非常勤講師
  • 2003年10月01日, 2004年03月31日, 岐阜大学, 工学部, 非常勤講師
  • 2007年04月01日, 広島大学, 教授

学歴

  • 京都工芸繊維大学, 工芸科学研究科, 材料科学専攻, 日本, 1992年04月, 1995年03月

学位

  • 博士(工学) (京都工芸繊維大学)
  • 修士(工学) (京都工芸繊維大学)

研究分野

  • 化学 / 基礎化学 / 有機化学

研究キーワード

  • 量子化学計算
  • 軌道論
  • 反応論
  • 有機光化学

教育活動

授業担当

  1. 2018年, 学部専門, セメスター(後期), 卒業研究
  2. 2018年, 学部専門, 1ターム, 反応有機化学
  3. 2018年, 学部専門, セメスター(前期), 卒業研究
  4. 2018年, 学部専門, 3ターム, 有機化学III
  5. 2018年, 修士課程・博士課程前期, セメスター(後期), 光科学
  6. 2018年, 修士課程・博士課程前期, セメスター(前期), 5研究科共同セミナー
  7. 2018年, 修士課程・博士課程前期, セメスター(前期), 化学特別研究
  8. 2018年, 修士課程・博士課程前期, セメスター(後期), 化学特別研究
  9. 2018年, 修士課程・博士課程前期, セメスター(前期), 反応有機化学セミナー
  10. 2018年, 修士課程・博士課程前期, セメスター(後期), 反応有機化学セミナー
  11. 2018年, 博士課程・博士課程後期, セメスター(前期), 化学特別研究
  12. 2018年, 博士課程・博士課程後期, セメスター(後期), 化学特別研究
  13. 2018年, 博士課程・博士課程後期, セメスター(前期), 反応有機化学セミナー
  14. 2018年, 博士課程・博士課程後期, セメスター(後期), 反応有機化学セミナー

研究活動

学術論文(★は代表的な論文)

  1. ★, Notable effect of an electron-withdrawing group at C3 on the selective formation of alkylidenecyclobutanes in the thermal denitrogenation of 4-spirocyclopropane-1-pyrazolines. Nonstatistical dynamics effects in the denitrogenation reactions, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129巻, 43号, pp.12981-pp.12988, OCT 31 2007
  2. A novel non-metathetic behavior of Grubbs catalyst: Ruthenium-mediated intramolecular [3+2] cycloaddition of bis-1,3-dienes, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 723巻, pp.171-pp.175, JAN 1 2013
  3. Recent progress regarding regio-, site-, and stereoselective formation of oxetanes in Paterno-Buchi reactions., Journal of the Chinese Chemical Society (Taipei, Taiwan), 55巻, 3号, pp.479-pp.486, 20080901
  4. Site- and stereoselectivity in the photochemical oxetane formation reaction (Paterno-Buchi reaction) of tetrahydrobenzofuranols with benzophenone: hydroxy-directed diastereoselectivity?, Chemistry Letters, 37巻, 8号, pp.822-pp.823, 20080801
  5. ★, Oxidation of archaeal peroxiredoxin involves a hypervalent sulfur intermediate., Proceedings of the National Academy of Sciences of the United States of America, 105巻, 17号, pp.6238-pp.6242, 20080429
  6. First Direct Detection of 2,3-Dimethyl-2,3-diphenylcyclopropanone., Journal of Organic Chemistry, 72巻, 8号, pp.2777-pp.2784, 20070401
  7. New development of reactive intermediate chemistry: a case study of singlet biradicals, Yuki Gosei Kagaku Kyokaishi, 65巻, 1号, pp.16-pp.22, 20070101
  8. ★, An extremely long-lived singlet 4,4-dimethoxy-3,5-diphenylpyrazolidine-3,5-diyl derivative: a notable nitrogen-atom effect on intra- and intermolecular reactivity., Angewandte Chemie, International Edition, 45巻, 46号, pp.7828-pp.7831, 20061001
  9. Exo-selective formation of bicyclic oxetanes in the photocycloaddition reaction of carbonyl compounds with vinylene carbonate: The important role of intermediary triplet diradicals in the stereoselectivity, Arkivoc, 8号, pp.58-pp.65, 20070901
  10. A Matrix Isolation Study of 2-Isopropylidenecyclopentane-1,3-diyl (Berson-Type Diradical)., Journal of Organic Chemistry, 71巻, 17号, pp.6607-pp.6610, 20060401
  11. Experimental Probe for Hyperconjugative Resonance Contribution in Stabilizing the Singlet State of 2,2-Dialkoxy-1,3-diyls: Regioselective 1,2-Oxygen Migration., Journal of the American Chemical Society, 128巻, 24号, pp.8008-pp.8014, 20060601
  12. Notable temperature effect on the stereoselectivity in the photochemical [2+2] cycloaddition reaction (Paterno-Buechi reaction) of 2,3-dihydrofuran-3-ol derivatives with benzophenone., Tetrahedron Letters, 47巻, 15号, pp.2527-pp.2530, 20060301
  13. Alternative protocol for oxidation in water: an effective epoxidation system promoted by the combination of Oxone and an amphiphilic ketone., Tetrahedron Letters, 46巻, 2号, pp.213-pp.216, 20050108
  14. Novel Substituent Effects on the Mechanism of the Thermal Denitrogenation of 2,3-Diazabicyclo[2.2.1]hept-2-ene Derivatives, Stepwise versus Concerted., Journal of the American Chemical Society, 127巻, 1号, pp.10-pp.11, 20050101
  15. Selectivity Control in Electron Spin Inversion Processes: Regio- and Stereochemistry of Paterno-Buechi Photocycloadditions as a Powerful Tool for Mapping Intersystem Crossing Processes., Accounts of Chemical Research, 37巻, 12号, pp.919-pp.928, 20041201
  16. Theoretical Calculations of the Effects of 2-Heavier Group 14 Element and Substituents on the Singlet-Triplet Energy Gap in Cyclopentane-1,3-diyls and Computational Prediction of the Reactivity of Singlet 2-Silacyclopentane-1,3-diyls., Journal of Organic Chemistry, 69巻, 21号, pp.7250-pp.7255, 20040501
  17. 2-Silyl Group Effect on the Reactivity of Cyclopentane-1,3-diyls. Intramolecular Ring-Closure versus Silyl Migration., Journal of Organic Chemistry, 69巻, 17号, pp.5622-pp.5626, 20040401
  18. Mechanism of Stereo- and Regioselectivity in the Paterno-Buechi Reaction of Furan Derivatives with Aromatic Carbonyl Compounds: Importance of the Conformational Distribution in the Intermediary Triplet 1,4-Diradicals., Journal of the American Chemical Society, 126巻, 9号, pp.2838-pp.2846, 20040301
  19. Effects of Spiroconjugation on the Calculated Singlet-Triplet Energy Gap in 2,2-Dialkoxycyclopentane-1,3-diyls and on the Experimental Electronic Absorption Spectra of Singlet 1,3-Diphenyl Derivatives. Assignment of the Lowest-Energy ElectronicTransition of Singlet Cyclopentane-1,3-diyls., Journal of the American Chemical Society, 126巻, 2号, pp.574-pp.582, 20040101
  20. DFT Calculations on the Effects of Para Substituents on the Energy Differences between Singlet and Triplet States of 2,2-Difluoro-1,3-diphenylcyclopentane-1,3-diyls., Journal of the American Chemical Society, 125巻, 42号, pp.12823-pp.12828, 20031001
  21. Synthesis of Antimalarial Yingzhaosu A Analogues by the Peroxidation of Dienes with Co(II)/O2/Et3SiH., Journal of Organic Chemistry, 68巻, 19号, pp.7361-pp.7367, 20030501
  22. DFT Prediction of Ground-State Spin Multiplicity of Cyclobutane-1,3-diyls: Notable Effects of Two Sets of Through-Bond Interactions., Journal of Organic Chemistry, 68巻, 4号, pp.1618-pp.1621, 20030201
  23. Mechanism of an Alcohol-Trapping Reaction in the Direct and Benzophenone-Sensitized Photodenitrogenation of a Spiroepoxy-Substituted Azoalkane: Solvent Effects and Stereochemical Deuterium Labeling., Journal of Organic Chemistry, 68巻, 5号, pp.1796-pp.1803, 20030201
  24. Reaction of 7,7-diphenyl-6-oxabicyclo[3.2.0]hept-1-ene with ROH; controlling factors on the regioselectivity in the nucleophilic addition reaction., Tetrahedron, 58巻, 35号, pp.7043-pp.7047, 20020901
  25. Multifunctional anti-angiogenic activity of the cyclic peroxide ANO-2 with antitumor activity., International Journal of Cancer, 100巻, 2号, pp.220-pp.227, 20020201
  26. On the Electronic Character of Localized Singlet 2,2-Dimethoxycyclopentane-1,3-diyl Diradicals: Substituent Effects on the Lifetime., Journal of the American Chemical Society, 124巻, 23号, pp.6540-pp.6541, 20020601
  27. Ozonolyses of 1-alkyl-substituted 1-tert-butylethylenes and highly methylated methylenecycloalkanes. The influence of the substituent steric bulk on the direction of cleavage of the primary ozonides., Tetrahedron, 58巻, 5号, pp.891-pp.896, 20020201
  28. Paterno-Buchi [2+2] photocycloaddition reactions of silyl ketene acetals: Controlling factors on the regio- and stereoselectivity in the oxetane formations., Yuki Gosei Kagaku Kyokaishi, 59巻, 9号, pp.855-pp.865, 20010901
  29. Memory of chirality in photochemical reactions., Kokagaku, 31巻, 1号, pp.28-pp.29, 20000101
  30. Regioselective formation of 3-selanyl-3-siloxyoxetanes in the Paterno-Buchi reaction of silyl O,Se-ketene acetals (O,Se-SKA)., Synthesis, 8号, pp.1243-pp.1247, 20010801
  31. Regioselective Oxygenations of S-Trans Dienes, Silyl Dienol Ethers (SDEs), by Triphenyl Phosphite Ozonide (TPPO) and Its Mechanistic Study., Journal of Organic Chemistry, 66巻, 10号, pp.3548-pp.3553, 20010301
  32. New development of localized 1,3-biradicals. Oxygen atom effects on most stable spin multiplicity and reactivity., Kagaku to Kogyo, 54巻, 2号, pp.164-pp.167, 20010201
  33. Lewis acid promoted ring-opening reactions of 2-methoxy-2-siloxyoxetane in the presence of allylsilane: notable lewis acid effect on the ring-opening regioselectivity of the oxetane., Main Group Metal Chemistry, 23巻, 11号, pp.651-pp.654, 20000301
  34. Stereochemical Deuterium Labeling as Mechanistic Probe for Differentiating the Singlet- and Triplet-Diradical Spin States in the Rearrangement of the 2-Spiroepoxy-1,3-cyclopentanediyl to Oxetanes., Journal of the American Chemical Society, 122巻, 27号, pp.6508-pp.6509, 20000701
  35. Paterno-Buechi Photocyclization of 2-Siloxyfurans and Carbonyl Compounds. Notable Substituent and Carbonyl (Aldehyde vs Ketone and Singlet- vs Triplet-Excited State) Effects on the Regioselectivity (Double-Bond Selection) in the Formation of Bicyclic exo-Oxetanes., Journal of Organic Chemistry, 65巻, 11号, pp.3426-pp.3431, 20000401
  36. Notable Sulfur Atom Effects on the Regio- and Stereoselective Formation of Oxetanes in Paterno-Buechi Photocycloaddition of Aromatic Aldehydes with Silyl O,S-Ketene Acetals., Journal of the American Chemical Society, 122巻, 17号, pp.4005-pp.4010, 20000401
  37. Intramolecular and Intermolecular Reactivity of Localized Singlet Diradicals: The Exceedingly Long-Lived 2,2-Diethoxy-1,3-diphenylcyclopentane-1,3-diyl., Journal of the American Chemical Society, 122巻, 9号, pp.2019-pp.2026, 20000301
  38. Photooxygenation (Electron transfer) of silyl enol ethers derived from 1-indanone: silyl group and medium effects on the competitive formation of 3-siloxy-1,2-dioxetane and ? -peroxy ketone., Main Group Metal Chemistry, 22巻, 9号, pp.539-pp.543, 19990901
  39. Photooxygenation (1O2) of silyl enol ethers derived from indan-1-ones: competitive formation of tricyclic 3-siloxy-1,2-dioxetane and ? -silylperoxy ketone., Journal of the Chemical Society, Perkin Transactions 1, 17号, pp.2507-pp.2512, 19990801
  40. 18O-Tracer Studies of Fe(II)-Induced Decomposition of 1,2,4-Trioxolanes (Ozonides) Derived from Cyclopentenes and Indenes. Inner-Sphere Electron Transfer Reduction of the Peroxide Linkage., Journal of the American Chemical Society, 121巻, 28号, pp.6556-pp.6562, 19991001
  41. Donor-Acceptor Binary Photocatalysis System Illustrated by the Intramolecular Cyclization of a Cyclopropanone Acetal Tethered to Cyclohexen-2-one., Bulletin of the Chemical Society of Japan, 72巻, 3号, pp.511-pp.517, 19990301
  42. Photochemical Generation and Methanol Trapping of Localized 1,3 and 1,4 Singlet Diradicals Derived from a Spiroepoxy-Substituted Cyclopentane-1,3-diyl., Journal of the American Chemical Society, 120巻, 44号, pp.11304-pp.11310, 19981201
  43. A stereoselective, tandem [2+2] photocycloaddition-hydrolysis route to aldol-type adducts., Journal of the Chemical Society, Perkin Transactions 1, 19号, pp.3261-pp.3266, 19980901
  44. Regioselective formation of 2-alkoxyoxetanes in the photoreaction of aromatic carbonyl compounds with ? ,? -dimethyl ketene silyl acetals: notable solvent and silyl group effects., Journal of the Chemical Society, Perkin Transactions 1, 19号, pp.3253-pp.3260, 19980901
  45. Regioselective formation of 2-alkoxyoxetanes in the photoreaction of aromatic carbonyl compounds with ? ,? -dimethyl ketene silyl acetals: notable solvent and silyl group effects., Journal of the Chemical Society, Perkin Transactions 1, 19号, pp.3253-pp.3260, 19980901
  46. Electronic substituent effects on the EPR-spectral D parameter of trimethylenemethane (TMM) triplet diradicals compared with localized cyclopentane-1,3-diyls., Journal of the Chemical Society, Perkin Transactions 2, 5号, pp.1063-pp.1068, 19980501
  47. Notable Substituent Electronic Effects on the Regioselectivity of an Oxygen-Atom Abstraction in the Reaction of Unsymmetrically Substituted Monocyclic 1,2-Dioxolanes with Triphenylphosphine., Journal of Organic Chemistry, 62巻, 3号, pp.752-pp.754, 19970201
  48. Photoinduced electron transfer reactions of cyclopropanone acetal with conjugated enones in the presence of a redox-type photosensitizer., Tetrahedron Letters, 37巻, 11号, pp.1833-pp.1836, 19961101
  49. Selectivity in the ring-expansion and ring-switching reactions of bicyclooxonium ions., Journal of the Chemical Society, Perkin Transactions 1, 5号, pp.413-pp.416, 19960501
  50. Oxidative Ring-Opening Reaction of Cyclopropanone Acetals with Carbonyl Compounds via Photoinduced Electron Transfer. Generation of a ? -Carbonyl Radical Species and Its Application to the Synthesis of ? -Hydroxy Ester Derivatives., Journal of Organic Chemistry, 60巻, 10号, pp.3065-pp.3073, 19950301
  51. Photoinduced electron transfer reaction of cyclpropanone acetals with arylmethyl methanesulfonate: generation of ? -keto radical species and application to C-C bond formation., Journal of the Chemical Society, Chemical Communications, 14号, pp.1673-pp.1674, 19940701
  52. Electron Transfer Profile of Cyclopropanone Acetals in the Nonirradiated Reaction with Tetracyanoethylene, Chloranil, and Dicyanodichlorobenzoquinone., Journal of Organic Chemistry, 59巻, 24号, pp.7445-pp.7452, 19941201
  53. Formation of unsaturated esters in the single electron transfer reaction of cyclopropanone acetals with quinones under non-irradiation conditions., Tetrahedron Letters, 35巻, 21号, pp.3551-pp.3554, 19941101
  54. Ring-opening addition reaction of cyclopropanol derivatives with carbenes., Tetrahedron Letters, 33巻, 47号, pp.7169-pp.7172, 19921201
  55. Bis(2-acetoxyacrylonitrile) and its phenylene and alkylene bis homologs. Preparation, isomerization, and intramolecular [2 + 2] photocycloaddition., Journal of Organic Chemistry, 57巻, 8号, pp.2263-pp.2266, 19920401
  56. Notable Effect of an Electron-Withdrawing Group at C3 on the Selective Formation of Alkylidenecyclobutanes in the Thermal Denitrogenation of 4-Spirocyclopropane-1-Pyrazolines., Journal of the American Chemical Society, 129巻, 43号, pp.12981-pp.12988, 20071001
  57. Concentration and Temperature Dependency of Regio- and Stereoselectivity in a Photochemical [2+2] Cycloaddition Reaction (the Paternó -Büchi Reaction): Origin of the Hydroxy-GroupDirectivity., J. Am. Chem. Soc., 133巻, pp.2592-pp.2604, 20110201
  58. Stereochemical deuterium-labeling study on the denitrogenation of 7,7-diethoxy-2,3-diazabicyclo[2.2.1]hept-2-ene, Journal of Physical Organic Chemistry, 24巻, pp.894-pp.901, 20111001
  59. Concentration and Temperature Dependency of Regio- and Stereoselectivity in a Photochemical [2+2] Cycloaddition Reaction (the Paternó -Büchi Reaction): Origin of the Hydroxy-GroupDirectivity., J. Am. Chem. Soc, 133巻, pp.2592–2604, 20110201
  60. Recent progress regarding regio-, site-, and stereoselective formation of oxetanes in Paterno-Buchi reactions, JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 55巻, 3号, pp.479-pp.486, JUN 2008
  61. Site- and stereoselectivity in the photochemical oxetane formation reaction (Paterno-Buchi reaction) of tetrahydrobenzofuranols with benzophenone: Hydroxy-directed diastereoselectivity?, CHEMISTRY LETTERS, 37巻, 8号, pp.822-pp.823, AUG 5 2008
  62. Computational study of the cooperative effects of nitrogen and silicon atoms on the singlet-triplet energy spacing in 1,3-diradicals and the reactivity of their singlet states, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 23巻, 4号, pp.300-pp.307, APR 2010
  63. Generation and Intermolecular Trapping of 1,2-Diaza-4-silacyclopentane-3,5-diyls in the Denitrogenation of 2,3,5,6-Tetraaza-7-silabicyclo[2.2.1]hept-2-ene: An Experimental and Computational Study, JOURNAL OF ORGANIC CHEMISTRY, 75巻, 6号, pp.1956-pp.1960, MAR 19 2010
  64. Stereoselective Triplet-Sensitised Radical Reactions of Furanone Derivatives, CHEMISTRY-A EUROPEAN JOURNAL, 16巻, 11号, pp.3341-pp.3354, 2010
  65. Novel cyclic beta-aminophosphonate derivatives as efficient organocatalysts for the asymmetric Michael addition reactions of ketones to nitrostyrenes, TETRAHEDRON-ASYMMETRY, 21巻, 15号, pp.1861-pp.1868, AUG 4 2010
  66. COMPUTATIONAL STUDY ON THE CYCLOPROPANATION REACTION OF YLIDES GENERATED FROM alpha-PYRIDINIUMACETATES, HETEROCYCLES, 81巻, 11号, pp.2479-pp.2495, NOV 1 2010
  67. Notable Substituent Effects on the Rate Constant of Thermal Denitrogenation of Cyclic Azoalkanes: Strong Evidence for a Stepwise Denitrogenation Mechanism, AUSTRALIAN JOURNAL OF CHEMISTRY, 63巻, 12号, pp.1615-pp.1618, 2010
  68. Formation of macrocyclic lactones in the Paterno-Buchi dimerization reaction, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 7巻, pp.265-pp.269, FEB 28 2011
  69. Concentration and Temperature Dependency of Regio- and Stereoselectivity in a Photochemical [2+2] Cycloaddition Reaction (the Paterno Buchi Reaction): Origin of the Hydroxy-Group Directivity, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133巻, 8号, pp.2592-pp.2604, MAR 2 2011
  70. The cooperative effect of a hydroxyl and carboxyl group on the catalytic ability of novel beta-homoproline derivatives on direct asymmetric aldol reactions, TETRAHEDRON-ASYMMETRY, 22巻, 2号, pp.226-pp.237, JAN 31 2011
  71. Stereochemical deuterium-labeling study on the denitrogenation of 7,7-diethoxy-2, 3-diazabicyclo[2.2.1]hept-2-ene, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 24巻, 10号, pp.894-pp.901, OCT 2011
  72. Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser, CHEMICAL PHYSICS LETTERS, 527巻, pp.79-pp.83, FEB 27 2012
  73. The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a pi-single bonded character, CHEMICAL SOCIETY REVIEWS, 41巻, 10号, pp.3808-pp.3820, 2012
  74. Stretch Effects Induced by Molecular Strain on Weakening sigma-Bonds: Molecular Design of Long-Lived Diradicals (Biradicals), JOURNAL OF ORGANIC CHEMISTRY, 77巻, 17号, pp.7612-pp.7619, SEP 7 2012
  75. Substituent Effect on Reactivity of Triplet Excited State of 2,3-Diazabicyclo[2.2.1]hept-2-enes, DBH Derivatives: alpha C-N Bond Cleavage versus beta C-C Bond Cleavage, JOURNAL OF ORGANIC CHEMISTRY, 78巻, 5号, pp.1940-pp.1948, MAR 1 2013
  76. Substituent effect on the energy barrier for sigma-bond formation from pi-single-bonded species, singlet 2,2-dialkoxycyclopentane-1,3-diyls, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 9巻, pp.925-pp.933, MAY 14 2013
  77. On the decarboxylation of 2-methyl-1-tetralone-2-carboxylic acid - oxidation of the enol intermediate by triplet oxygen, NEW JOURNAL OF CHEMISTRY, 37巻, 8号, pp.2245-pp.2249, 2013
  78. Kinetic Stabilization and Reactivity of Single-Bonded Species: Effect of the Alkoxy Group on the Lifetime of Singlet 2,2-Dialkoxy-1,3-diphenyloctahydropentalene-1,3-diyls, CHEMISTRY-A EUROPEAN JOURNAL, 19巻, 31号, pp.10395-pp.10404, JUL 29 2013
  79. Diradicals, CHEMICAL REVIEWS, 113巻, 9号, pp.7011-pp.7088, SEP 2013
  80. Scope and Limitation for FeSO4-Mediated Direct Arylation of Heteroarenes with Arylboronic Acids and Its Synthetic Applications, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 87巻, 2号, pp.301-pp.313, FEB 15 2014
  81. Time-Resolved IR Spectroscopy of 1,3-Dicyanophenylcyclopentane-1,3-diyl Diradicals: CN Stretching Wavenumber as a Vibrational Signature of Radical Character, JOURNAL OF PHYSICAL CHEMISTRY B, 118巻, 14号, pp.3991-pp.3997, APR 10 2014
  82. Mode Switching of a Self-Propelled Camphor Disk Sensitive to the Photoisomerization of a Molecular Layer on Water, LANGMUIR, 30巻, 25号, pp.7353-pp.7357, JUL 1 2014
  83. Caged Glutamates with pi-Extended 1,2-Dihydronaphthalene Chromophore: Design, Synthesis, Two-Photon Absorption Property, and Photochemical Reactivity, JOURNAL OF ORGANIC CHEMISTRY, 79巻, 17号, pp.7822-pp.7830, SEP 5 2014
  84. 1,8-Disubstituted Xanthylidene-Based Remote Carbenes: Photolytic Generation and Isolation of Low-Coordinate Palladium(II) Complex, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 3号, pp.534-pp.541, JAN 2015
  85. Electron-spin resonance (ESR) characterization of quintet spin-state bis-nitroxide-bearing cyclopentane-1,3-diyl diradicals, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 28巻, 2号, pp.116-pp.120, FEB 2015
  86. Photolysis of acetophenone derivatives with alpha-cyclopropyl substituents, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 28巻, 2号, pp.137-pp.146, FEB 2015
  87. Oxidation of an allene compound bearing 1,8-dichloroacridene moieties and photolysis of the halogenated allene compound for the generation of triplet carbenes, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 28巻, 2号, pp.79-pp.87, FEB 2015
  88. Organocatalyzed Asymmetric Aldol Reactions of Ketones and beta,gamma-Unsaturated alpha-Ketoesters and Phenylglyoxal Hydrates, JOURNAL OF ORGANIC CHEMISTRY, 80巻, 2号, pp.806-pp.815, JAN 16 2015
  89. Theoretical Study on Diradical Characters and Nonlinear Optical Properties of 1,3-Diradical Compounds, JOURNAL OF PHYSICAL CHEMISTRY A, 118巻, 45号, pp.10837-pp.10848, NOV 13 2014
  90. Formation of Isomerized E,Z-Configured 1,3-Dienes in Construction of Macrocyclic Trienes by Diene-Ene RCM, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 88巻, 1号, pp.146-pp.148, JAN 15 2015
  91. Direct Detection of a Triplet Vinylnitrene, 1,4-Naphthoquinone-2-ylnitrene, in Solution and Cryogenic Matrices, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137巻, 12号, pp.4207-pp.4214, APR 1 2015
  92. Multiple crystal forms of N,N '-diacetylchitobiose deacetylase from Pyrococcus furiosus, ACTA CRYSTALLOGRAPHICA SECTION F-STRUCTURAL BIOLOGY COMMUNICATIONS, 71巻, pp.657-pp.662, JUN 2015
  93. Simultaneous Observation of Triplet and Singlet Cyclopentane-1,3-diyl Diradicals in the Intersystem Crossing Process, AUSTRALIAN JOURNAL OF CHEMISTRY, 68巻, 11号, pp.1700-pp.1706, 2015
  94. Intra- and Intermolecular Reactivity of Triplet Sumanenetrione, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 88巻, 11号, pp.1612-pp.1617, NOV 15 2015
  95. Design and synthesis of a new chromophore, 2-(4-nitrophenyl)benzofuran, for two-photon uncaging using near-IR light, CHEMICAL COMMUNICATIONS, 52巻, 2号, pp.331-pp.334, 2016
  96. A Puckered Singlet Cyclopentane-1,3-diyl: Detection of the Third Isomer in Homolysis, CHEMISTRY-A EUROPEAN JOURNAL, 22巻, 7号, pp.2299-pp.2306, FEB 12 2016
  97. Biphenalenylidene: Isolation and Characterization of the Reactive Intermediate on the Decomposition Pathway of Phenalenyl Radical, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138巻, 7号, pp.2399-pp.2410, FEB 24 2016
  98. Computational Study of Cyclobutane-1,3-diylidene Dicarbenes: Ground-State Spin Multiplicity and New Strategy toward the Synthesis of Bicyclo[1.1.0]but-1(3)-enes, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 89巻, 7号, pp.770-pp.778, JUL 15 2016
  99. Impact of Diradical Spin State (Singlet vs Triplet) and Structure (Puckered vs Planar) on the Photodenitrogenation Stereoselectivity of 2,3-Diazabicyclo[2.2.1]heptanes, JOURNAL OF PHYSICAL CHEMISTRY B, 120巻, 29号, pp.7217-pp.7226, JUL 28 2016
  100. Design, Synthesis, and Reaction of pi-Extended Coumarin-based New Caged Compounds with Two-photon Absorption Character in the Near-IR Region, CHEMISTRY LETTERS, 45巻, 10号, pp.1186-pp.1188, OCT 5 2016
  101. The structure of electronically excited ,-unsaturated lactones, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 29巻, 12号, pp.718-pp.724, DEC 2016
  102. Using Molecular Architecture to Control the Reactivity of a Triplet Vinylnitrene, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138巻, 45号, pp.14905-pp.14914, NOV 16 2016
  103. Design and Synthesis of a 4-Nitrobromobenzene Derivative Bearing an Ethylene Glycol Tetraacetic Acid Unit for a New Generation of Caged Calcium Compounds with Two-Photon Absorption Properties in the Near-IR Region and Their Application in Vivo, ACS OMEGA, 1巻, 2号, pp.193-pp.201, AUG 2016
  104. Control of the Termination Mechanism in Radical Polymerization by Viscosity: Selective Disproportionation in Viscous Media, CHEMISTRY-A EUROPEAN JOURNAL, 23巻, 6号, pp.1299-pp.1305, JAN 2017
  105. Light-harvesting organogel based on tris(phenylisoxazolyl)benzene, SUPRAMOLECULAR CHEMISTRY, 29巻, 6号, pp.471-pp.476, 2017
  106. Direct Detection of a Chemical Equilibrium between a Localized Singlet Diradical and Its sigma-Bonded Species by Time-Resolved UV/Vis and IR Spectroscopy, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56巻, 11号, pp.2984-pp.2988, MAR 6 2017
  107. Photolysis of 3,5-diphenylisoxazole in argon matrices, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 30巻, 4号, APR 2017
  108. Paterno-Buchi photochemical [2+2] cycloaddition of aromatic carbonyl compounds with 2-siloxy-1H-pyrrole derivatives(dagger), JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 30巻, 4号, APR 2017
  109. Direct observation of methoxycarbonylnitrene, CHEMICAL COMMUNICATIONS, 53巻, 35号, pp.4783-pp.4786, MAY 1 2017
  110. Suplatast tosilate protects the lung against hyperoxic lung injury by scavenging hydroxyl radicals, FREE RADICAL BIOLOGY AND MEDICINE, 106巻, pp.1-pp.9, MAY 2017
  111. Design and Synthesis of a Caged Carboxylic Acid with a Donor-pi-Donor Coumarin Structure: One-photon and Two-photon Uncaging Reactions Using Visible and Near-Infrared Lights, ORGANIC LETTERS, 19巻, 10号, pp.2622-pp.2625, MAY 19 2017
  112. Mechanistic study of stereoselectivity in azoalkane denitrogenations, PURE AND APPLIED CHEMISTRY, 89巻, 6号, pp.759-pp.764, JUN 2017
  113. 5配位リン試薬を用いた選択的Wittig反応, 基礎有機化学討論会要旨集(基礎有機化学連合討論会予稿集), 2009巻, 0号, pp.267-pp.267, 2009
  114. 一重項1,3-ジラジカルの寿命に及ぼす2位の置換基効果, 基礎有機化学討論会要旨集(基礎有機化学連合討論会予稿集), 2009巻, 0号, pp.277-pp.277, 2009
  115. Formation of Isomerized E,Z-Configured 1,3-Dienes in Construction of Macrocyclic Trienes by Diene-Ene RCM, Bulletin of the Chemical Society of Japan, 88巻, 1号, pp.146-pp.148, 2015
  116. Design and Synthesis of Two-Photon Responsive Chromophores for Near-Infrared Light-Induced Uncaging Reactions, SYNTHESIS-STUTTGART, 49巻, 15号, pp.3337-pp.3346, AUG 2017
  117. N-Methylcarbamoyl azide: spectroscopy, X-ray structure and decomposition via methylcarbamoyl nitrene, ORGANIC CHEMISTRY FRONTIERS, 4巻, 9号, pp.1839-pp.1848, SEP 1 2017
  118. Computational study on 1,3-disilacyclobutane-1,3-diylidene disilylenes: A synthetic strategy for cis-bent disilenes, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 30巻, 9号, SEP 2017
  119. Laser flash photolysis of nanocrystalline alpha-azidop-methoxy-p-acetophenone, ORGANIC & BIOMOLECULAR CHEMISTRY, 15巻, 35号, pp.7380-pp.7386, SEP 21 2017
  120. Two ring opened oxetane taxoids containing a C-20 benzoyloxy group from the roots of Taxus wallichiana Zucc., TETRAHEDRON LETTERS, 58巻, 40号, pp.3897-pp.3900, OCT 4 2017
  121. Is pi-Single Bonding (C-pi-C) Possible? A Challenge in Organic Chemistry, CHEMISTRY LETTERS, 46巻, 11号, pp.1586-pp.1592, NOV 2017
  122. Contrasting Photolytic and Thermal Decomposition of Phenyl Azidoformate: The Curtius Rearrangement Versus Intramolecular C-H Amination, JOURNAL OF PHYSICAL CHEMISTRY A, 121巻, 45号, pp.8604-pp.8613, NOV 16 2017
  123. Fast Heavy-Atom Tunneling in Trifluoroacetyl Nitrene, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56巻, 49号, pp.15672-pp.15676, DEC 4 2017
  124. Artocarmins G-M, Prenylated 4-Chromenones from the Stems of Artocarpus rigida and Their Tyrosinase Inhibitory Activities, JOURNAL OF NATURAL PRODUCTS, 80巻, 12号, pp.3173-pp.3179, DEC 2017
  125. B(MIDA)-Containing Diborons, ACS OMEGA, 2巻, 9号, pp.5911-pp.5916, SEP 2017
  126. Magnetically Bistable Nitrenes: Matrix Isolation of Furoylnitrenes in Both Singlet and Triplet States and Triplet 3-Furylnitrene, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140巻, 1号, pp.10-pp.13, JAN 10 2018
  127. Experimental Observation of Thermally Excited Triplet States of Heavier Group 15 Element Centered Diradical Dianions, CHEMISTRY-A EUROPEAN JOURNAL, 24巻, 13号, pp.3156-pp.3160, MAR 2 2018
  128. Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 57巻, 12号, pp.3212-pp.3216, MAR 12 2018
  129. Photochemically Induced Intramolecular Radical Cyclization Reactions with Imines, JOURNAL OF ORGANIC CHEMISTRY, 83巻, 4号, pp.1867-pp.1875, FEB 16 2018
  130. Selective Probing of Potassium Ion in Solution by Intramolecular Excimer Fluorescence of Dibenzo-Crown Ethers, CHEMPHYSCHEM, 19巻, 11号, pp.1331-pp.1335, JUN 5 2018
  131. Unusually Long-Wavelength Emissions of Cyclopropanes: New Insight into C-C Bond Homolysis, CHEMISTRY-A EUROPEAN JOURNAL, 24巻, 30号, pp.7595-pp.7600, MAY 28 2018
  132. Sulfamoyl nitrenes: singlet or triplet ground state?, CHEMICAL COMMUNICATIONS, 54巻, 48号, pp.6136-pp.6139, JUN 18 2018

著書等出版物

  1. 2015年, 2015年
  2. 2014年, 2014年
  3. 2010年, 2010年

招待講演、口頭・ポスター発表等

  1. 2016年08月01日, 招待, 英語
  2. 2016年07月03日, 招待, 英語

受賞

  1. 2005年02月, 2005年度有機合成奨励賞, 有機合成化学協会, 反応性中間体の反応挙動精査に基づく合成反応の開発
  2. The Zimmer Award
  3. 2004年10月, The Award for the Best Presentation on the 1st International Symposium in Chemistry at Gumma (2004), 群馬国際化学会議実行委員長・西村淳, Heteroatom Effects on the Reactivity of Cyclopentane-1,3-Diyls
  4. 2007年09月, 第3回野副記念奨励賞, 基礎有機連合討論会・野副記念奨励賞委員会, 長寿命一重項ビラジカルの発生:構造と反応性に関する研究

外部資金

競争的資金等の採択状況

  1. 戦略的創造研究推進事業(CREST), 光制御実験用分子合成, 2010年10月01日, 2016年03月31日
  2. 民間からの助成金, 国際交流基金, 2006年
  3. 科学技術振興調整費, 新しい結合様式の創製:新規分子構造の構築, 2003年
  4. 民間からの助成金, 光環化不斉非対称化に基づくオキセタン類の不斉合成, 2005年
  5. 科学研究費助成事業(新学術領域研究(研究領域提案型)), 光感応性π単結合化合物の創製と機能, 2012年, 2016年
  6. 科学研究費助成事業(新学術領域研究(研究領域提案型)), 炭素-炭素π単結合の創製・集積化による新規π電子空間の構築, 2011年, 2012年
  7. 科学研究費助成事業(新学術領域研究(研究領域提案型)), 炭素―炭素π1重結合の創製・集積化による新規π電子系の構築, 2009年, 2010年
  8. 科学研究費助成事業(特定領域研究), ポリラジカルのスピン多重度制御とその機能に及ぼす元素相乗効果, 2008年, 2009年
  9. 科学研究費助成事業(特定領域研究), 小分子カルボニル化合物の活性化によるオキセタン類の選択的合成と高度分子変換反応, 2007年, 2008年
  10. 科学研究費助成事業(特定領域研究), 元素相乗効果に基づくポリラジカルのスピン整列とその機能化, 2007年, 2007年
  11. 科学研究費助成事業(基盤研究(B)), 開殻系分子の安定化に基づく新規分子変換反応の開発と機能化, 2007年, 2010年
  12. 科学研究費助成事業(基盤研究(B)), 高周期典型元素がもたらすビラジカル化学の新展開:新しい分子構造の構築, 2005年, 2006年
  13. 科学研究費助成事業(特定領域研究(A)), 局在化ビラジカル種のスピン多重度制御, 2000年, 2001年
  14. 科学研究費助成事業(特定領域研究(C)), 1,2,4,5-テトラオキサシクロアルカンを標的とする新生血管産生阻害剤の開発, 2000年, 2000年
  15. 科学研究費助成事業(奨励研究(A)), 高反応性オキセタンの位置及び立体選択的合成法確立への挑戦, 2000年, 2001年
  16. 科学研究費助成事業(特定領域研究(A)), 新生血管産生阻害作用をもつ環状過酸化物の探索, 1999年, 1999年
  17. 科学研究費助成事業(特定領域研究(A)), 抗マラリア特性をもつ水溶性環状過酸化物の合成, 1999年, 1999年
  18. 科学研究費助成事業(特定領域研究(A)), 高次スピン分子のスピン多重度制御, 1999年, 1999年
  19. 科学研究費助成事業(奨励研究(A)), 高反応性オキセタン誘導体の立体選択的合成法の開発とその反応性に関する研究, 1998年, 1999年
  20. 科学研究費助成事業(特定領域研究(A)), 抗がん作用をもつ環状過酸化物の探索, 1998年, 1998年
  21. 科学研究費助成事業(特定領域研究(A)), 抗マラリア特性をもつ環状過酸化物の新規合成反応の開発, 1998年, 1998年
  22. 戦略的創造研究推進事業(CREST), 光制御実験用分子合成, 2010年10月01日, 2016年03月31日
  23. 科学研究費助成事業(挑戦的萌芽研究), 最も曲がった曲面π電子系構造の合成とπ電子・光物性に及ぼす曲面効果の解明, 2016年, 2017年
  24. 科学研究費助成事業(基盤研究(B)), 近赤外2光子感応性新規光解離性保護基の合成と反応:ドラッグデリバリーへの基盤研究, 2017年, 2019年
  25. 科学研究費助成事業(特別研究員奨励費), 局在化1、3-ジラジカルの構造と反応性に関する研究, 2017年, 2019年

社会活動

学術会議等の主催

  1. 分子情報ダイナミクス研究会, 研究会事務局, 2007年08月
  2. 2014年04月, 2014年04月
  3. 第27会基礎有機化学討論会, 2016年09月, 2016年09月
  4. 2015年12月, 2015年12月
  5. 2016年12月, 2016年12月
  6. 2016年03月, 2016年03月

学術雑誌論文査読歴

  1. 2005年, ARKIVOC (Archive for Organic Chemistry), その他
  2. 2006年, ARKIVOC (Archive for Organic Chemistry), その他
  3. 2007年, ARKIVOC (Archive for Organic Chemistry), その他