MANABU ABE

Last Updated :2025/10/02

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Professor
Web Site
https://hiu-roc.webnode.jp
E-mail
mabehiroshima-u.ac.jp
Other Contact Details
1-3-1，Kagamiyama，Higashi-Hiroshima, Japan
TEL : (+81)82-424-7432 FAX : (+81)82-424-7432
Self-introduction
Development of chemical reactions using light energy, which exists abundantly in nature. Development of drugs that deliver biologically active substances such as anticancer drugs by light irradiation. Elucidation of chemical reaction mechanisms based on direct observation of unstable chemical species intervening in chemical reactions.

Basic Information

Major Professional Backgrounds

  • 2024/04/01, Kyoto University, Visiting Professor
  • 2021, 2021, Kwansei University, Faculty of Science and Engineering, Visiting Professor
  • 2021, Tokyo Insitute of Technology, Graduate School of Science and Technology, Visiting Professor
  • 2021, Kyoto University, Graduate School of Engineering, Visiting Professor
  • 2020, Hiroshima University, Graduate School of Advanced Science and Engineering, Professor
  • 2018, 2018, Osaka Prefecture University, Faculty of Engineering, Visiting Professor
  • 2018, 2018, Osaka University, Faculty of Engineering Science, Visiting Professor
  • 2015, 2015, Osaka City University, Faculty of Science, Visiting Professor
  • 2012, 2012, Kyushu University, Faculty of Science, Visiting Professor
  • 2008, 2008, Gunma UNiversity, Faculty of Engineering, Visintg Professor
  • 2008, 2008, Mie University, Faculty of Engineering, Visiting Professor
  • 2007, 2020/03/31, Hiroshima University, Graduate School of Science, Professor
  • 2006, 2007, Osaka University, Associate Professor
  • 2003, 2003, Gifu University, Faculty of Engineering, Visiting Professor
  • 2000, 2006, Osaka University, Lecturer
  • 1995, 2000, Osaka University, Assistant Professor

Educational Backgrounds

  • Kyoto Institute of Technology, Graduate School, Division of Engineering and Design Science, Deaprtment of Materials Chemistry, Japan, 1992/04, 1995/03
  • Kyoto Institute of Technology, Faculty of Engineering and Design, Department of Engineering Chemistry, Japan, 1986/04, 1990/03

Academic Degrees

  • PhD, Kyoto Institute of Technology
  • Master of Engineering, Kyoto Institute of Technology

Educational Activity

  • [Bachelor Degree Program] School of Science : Chemistry : Chemistry
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program

Research Fields

  • Chemistry;Basic chemistry;Organic chemistry
  • Chemistry;Applied chemistry;Synthetic chemistry
  • Chemistry;Applied chemistry;Functional solid state chemistry
  • Complex systems;Biomolecular science;Chemical biology

Research Keywords

  • Quantum Chemical Calculations
  • Orbital Theory
  • Reaction Mechanism
  • Organic Photochemistry

Affiliated Academic Societies

  • The Chemical Society of Japan, 1990/10
  • The Society of Physical Organic Chemistry, Japan
  • The Japanese Photochemistry Association, 1995/04
  • The Society of Silicon Chemistry, Japan, 2006/10
  • The Society of Electron Spin Science and Technology, 2006/10

Educational Activity

Course in Charge

  1. 2025, Liberal Arts Education Program1, 2Term, Modern Chemistry
  2. 2025, Undergraduate Education, First Semester, Special Study for Graduation
  3. 2025, Undergraduate Education, Second Semester, Special Study for Graduation
  4. 2025, Undergraduate Education, 1Term, Organic Reaction Chemistry
  5. 2025, Undergraduate Education, 4Term, Organic Chemistry III
  6. 2025, Undergraduate Education, Year, Advanced Subject Research
  7. 2025, Graduate Education (Master's Program) , 1Term, Organic Reaction Chemistry
  8. 2025, Graduate Education (Master's Program) , First Semester, Exercises in Chemistry A
  9. 2025, Graduate Education (Master's Program) , Second Semester, Exercises in Chemistry B
  10. 2025, Graduate Education (Master's Program) , Year, Master's Thesis in Chemistry
  11. 2025, Graduate Education (Doctoral Program) , Year, Doctoral Thesis in Chemistry

Research Activities

Academic Papers

  1. Synthesis and Physical Properties of [n]Cycloparaphenylene Ketone (n=6, 7, 8, and 10), ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 64(33), 20250811
    Link to Paper Search Results by DOI
  2. Click Chemistry-Aided Synthesis of Triazole-Tethered Benzothiazoles as Novel Multifunctional Agents Against Alzheimer's Disease, ARCHIV DER PHARMAZIE, 358(7), 202507
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  3. Triazole-functionalized benzofuran and benzothiophene semicarbazides as novel VEGFR-2-targeted anti-cancer agents, BIOORGANIC CHEMISTRY, 163, 202508
    Link to Paper Search Results by DOI
  4. Discovery of 1-phenyl-1,2,3-triazole ureas as dual VEGFR-2/JNK-1 type II kinase inhibitors targeting pancreatic cancer, INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 308, 202505
    Link to Paper Search Results by DOI
  5. Design, Synthesis, and Biological Evaluation of BODIPY-Caged Resiquimod as a Dual-Acting Phototherapeutic, JOURNAL OF MEDICINAL CHEMISTRY, 68(4), 4561-4581, 20250217
    Link to Paper Search Results by DOI
  6. Photochemical transformations of glycosyl bromides in the presence of amines, CARBOHYDRATE RESEARCH, 552, 202506
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  7. Temperature-Dependent Photoreactivity of 2-Azidomethylbenzophenone: Insights into the Triplet Imine Biradical Pathway, JOURNAL OF ORGANIC CHEMISTRY, 90(9), 3349-3358, 20250227
    Link to Paper Search Results by DOI
  8. Organophotocatalytic access to C-glycosides: multicomponent coupling reactions using glycosyl bromides, CHEMICAL COMMUNICATIONS, 60(66), 20240813
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  9. Photo- and Ca2+- induced acceleration of uncaging process from hemiacetal intermediate formed in the photolysis of an o-nitrobenzyl type of photoremovable protecting group (photocage), JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 462, 20250501
    Link to Paper Search Results by DOI
  10. Influence of Curvature on the Physical Properties and Reactivity of Triplet Corannulene Nitrene, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 146(51), 35064-35076, 20241210
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  11. Impact of Transition-State Aromaticity on Selective Radical-Radical Coupling of Triarylimidazolyl Radicals, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 147(3), 2559-2570, 20241128
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  12. Design and synthesis of a 2,5-Diarylthiophene chromophore for enhanced near-infrared two-photon uncaging efficiency of calcium ions, PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 23(10), 1811-1827, 202410
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  13. Molecular engineering of coumarins for enhanced 2-photon absorption property, CHEMISTRY LETTERS, 53(7), 20240718
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  14. Temporal-Focusing Multiphoton Excitation Single-Molecule Localization Microscopy Using Spontaneously Blinking Fluorophores, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 63(27), 20240701
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  15. CO2 Capture and Electrochemical Reduction of Low-Concentration CO2 Using a Re(I)-Complex Catalyst in Ethanol, ACS CATALYSIS, 14(13), 10403-10411, 20240625
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  16. Study on factors affecting quantum yield for the design of improved ortho-nitrobenzyl photoremovable protecting groups, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 97(6), 20240628
    Link to Paper Search Results by DOI
  17. Sulfur atom effect on the photochemical release of benzylamine from caged amines, CHEMISTRY LETTERS, 53(6), 20240628
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  18. α-Cleavage of 2,2-Diazido-2,3-dihydroinden-1-one in Solution and Cryogenic Matrices, JOURNAL OF ORGANIC CHEMISTRY, 89(10), 7125-7137, 20240508
    Link to Paper Search Results by DOI
  19. Sequential C-F Bond Transformation of the Difluoromethylene Unit in Perfluoroalkyl Groups: A Combination of Fine-Tuned Phenothiazine Photoredox Catalyst and Lewis Acid, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 63(14), 20240402
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  20. Optochemical control of slow-wave sleep in the nucleus accumbens of male mice by a photoactivatable allosteric modulator of adenosine A2A receptors, NATURE COMMUNICATIONS, 15(1), 20240430
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  21. Generation and Characterization of a Tetraradical Embedded in a Curved Cyclic Paraphenylene Unit, CHEMISTRY-A EUROPEAN JOURNAL, 29(42), 20230726
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  22. Photoinduced α-Aminoalkylation of Sulfonylarenes with Alkylamines, CHEMISTRY-A EUROPEAN JOURNAL, 29(68), 20231206
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  23. Molecular and Crystal Structure, Spectroscopy, and Photochemistry of a Dispiro Compound Bearing the Tetraoxane Pharmacophore, CHEMISTRY-A EUROPEAN JOURNAL, 29(48), 20230825
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  24. Formation of Sterically Congested C-N Bonds by Electrochemical Reductive Coupling of Amines and α-Bromocarboxamides, CHEMELECTROCHEM, 11(5), 20240301
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  25. Bidirectional Neuronal Actuation by Uncaging with Violet and Green Light, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 63(13), 20240322
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  26. Development of a Two-Photon-Responsive Chromophore, 2-(p-Aminophenyl)-5,6-dimethoxy-1-(hydroxyinden-3-yl)methyl Derivative, as a Photoremovable Protecting Group, JOURNAL OF ORGANIC CHEMISTRY, 89(7), 4691-4701, 20240319
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  27. Crucial Roles of Leaving Group and Open-Shell Cation in Photoreaction of (Coumarin-4-yl)methyl Derivatives, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 146(15), 10993-11001, 20240405
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  28. The isotopic signature of UV during bacterial reduction, GEOCHEMICAL PERSPECTIVES LETTERS, 29, 45-50, 20240409
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  29. Substituent Effects on the Electronic Ground State (Singlet versus Triplet) of Indenyl Cations: DFT and CASPT2 Studies, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 27(7), 20240219
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  30. Substituted effects on bonding characteristics of cyclopentane-1,3-diyl diradicals monitored by time-resolved infrared spectroscopy, JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 37(2), 202402
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  31. Photoexcitation of (diarylmethylene)amino benziodoxolones for alkylamination of styrene derivatives with carboxylic acids, CHEMICAL SCIENCE, 15(3), 1068-1076, 20240117
    Link to Paper Search Results by DOI
  32. Energetically More Stable Singlet Cyclopentane-1,3-diyl Diradical with π-Single Bonding Character than the Corresponding σ-Single Bonded Compound, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 145(49), 27089-27094, 20231115
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  33. Photochemically Induced Hydrogen Atom Transfer and Intramolecular Radical Cyclization Reactions with Oxazolones, JOURNAL OF ORGANIC CHEMISTRY, 88(23), 16435-16455, 20231120
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  34. Synthesis, Characterization, and Application of a Cyclic Stilbene Derivative with Simultaneous Two-photon Absorption Character, CHEMISTRY LETTERS, 52(11), 846-849, 202311
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  35. Development of Photoremovable Protecting Groups Responsive to Near-Infrared Two-Photon Excitation and Their Application to Drug Delivery Research, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 96(9), 899-906, 202309
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  36. Contribution of the nuclear field shift to kinetic uranium isotope fractionation, GEOCHEMICAL PERSPECTIVES LETTERS, 27, 43-47, 20230920
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  37. Light-Mediated Synthesis of 2-(4-Methoxyphenyl)-1-pyrroline via Intramolecular Reductive Cyclization of a Triplet Alkylnitrene, ORGANIC LETTERS, 25(23), 4345-4349, 20230605
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  38. Manipulation of an electron by photoirradiation in the electron-catalyzed cross-coupling reaction, SCIENCE ADVANCES, 9(22), 20230602
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  39. One-Electron Injection-triggered Radical Reaction of Alkyl Benzoates Promoted by 1,4-Bis(diphenylamino)benzene Photocatalysis, CHEMCATCHEM, 15(3), 20230208
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  40. Excited-State Intramolecular Proton Transfer in Salicylidene-?- Hydroxy Carboxylate Derivatives: Direct Detection of the Triplet Excited State of the cis-Keto Tautomer, JOURNAL OF PHYSICAL CHEMISTRY A, 127(12), 2765-2778, 20230330
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  41. Tris(4?-Nitrobiphenyl)amine-An Octupolar Chromophore with High Two-Photon Absorption Cross-Section and Its Application for Uncaging of Calcium Ions in the Near-Infrared Region, JOURNAL OF ORGANIC CHEMISTRY, 87(23), 15888-15898, 20221202
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  42. DMPO Spin Trapping Study of the Photolysis of 2-(4-Nitrophenyl)-1H-indolyl-3-methyl Derivatives, CHEMISTRY LETTERS, 52(1), 10-12, 202301
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  43. Pyrrolo[2,1-a]isoquinolines as multitasking organophotocatalysts in chemical synthesis, CHEM CATALYSIS, 2(10), 2726-2749, 20221020
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  44. Photolysis of 3-Azido-3-phenyl-3H-isobenzofuran-1-one at Ambient and Cryogenic Temperatures(dagger), PHOTOCHEMISTRY AND PHOTOBIOLOGY, 97(6), 1397-1406, 202111
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  45. Assemblies of 1,4-Bis(diarylamino)naphthalenes and Aromatic Amphiphiles: Highly Reducing Photoredox Catalysis in Water, SYNLETT, 33(12), 1184-1188, 20220721
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  46. Photoreaction of 4-(Bromomethyl)-7-(diethylamino)coumarin:Generation of a Radical and Cation Triplet Diradical during the C-BrBond Cleavage br, ORGANIC LETTERS, 24(15), 2804-2808, 20220422
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  47. Thermal Reaction Behavior of Triphenylimidazolyl Radical with a Bulky Substituent, JOURNAL OF ORGANIC CHEMISTRY, 87(10), 6877-6885, 20220520
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  48. A stable silylborane with diminished boron Lewis acidity, DALTON TRANSACTIONS, 51(17), 6543-6546, 20220503
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  49. Protonation-Enhanced Reactivity of Triplet State in Dearomative Photocycloaddition of Quinolines to Olefins, ORGANIC LETTERS, 23(16), 6257-6261, 20210820
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  50. 2-(4-Nitrophenyl)-1H-indolyl-3-methyl Chromophore: A Versatile Photocage that Responds to Visible-light One-photon and Near-infrared-light Two-photon Excitations, CHEMISTRY LETTERS, 51(2), 153-156, 202202
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  51. Impacts of Solvent and Alkyl Chain Length on the Lifetime of Singlet Cyclopentane-1,3-diyl Diradicaloids with pi-Single Bonding, JOURNAL OF ORGANIC CHEMISTRY, 87(3), 1858-1866, 20220204
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  52. Long-lived localised singlet diradicaloids with carbon-carbon pi-single bonding (C-pi-C), CHEMICAL COMMUNICATIONS, 57(86), 11301-11309, 20211028
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  53. Impact of Five-membered Heterocyclic Rings on Photophysical Properties Including Two-photon Absorption Character, CHEMISTRY LETTERS, 50(10), 1810-1813, 202110
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  54. SOMO-HOMO Conversion in Triplet Cyclopentane-1,3-diyl Diradicals, ACS OMEGA, 6(35), 22773-22779, 20210907
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  55. Direct Detection of Singlet Cyclopentane-1,3-diyl Diradicals By Infrared and Ultraviolet-Visible Spectroscopy at Cryogenic Temperature and Their Photoreactivity, JOURNAL OF ORGANIC CHEMISTRY, 86(17), 12046-12053, 20210903
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  56. Structural Investigation of Photochemical Intermediates in Solution by Cold UV Spectroscopy in the Gas Phase: Photosubstitution of Dicyanobenzenes by Allylsilanes, JOURNAL OF PHYSICAL CHEMISTRY A, 125(28), 6238-6245, 20210722
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  57. New aspect of photophysics of 7,7,8,8-tetracyanoquinodimethane and its solvated complexes: intra- vs. inter-molecular charge-transfer, RSC ADVANCES, 11(36), 22381-22389, 20210703
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  58. SOMO-HOMO Conversion in Triplet Carbenes, ORGANIC LETTERS, 23(13), 4955-4959, 20210702
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  59. 1,3-Diradicals Embedded in Curved Paraphenylene Units: Singlet versus Triplet State and In-Plane Aromaticity, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(19), 7426-7439, 20210519
    Link to Paper Search Results by DOI
  60. Discovery of 4-alkoxy-2-aryl-6,7-dimethoxyquinolines as a new class of topoisomerase I inhibitors endowed with potent in vitro anticancer activity, EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 215, 20210405
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  61. p-Nitroterphenyl units for near-infrared two-photon uncaging of calcium ions, JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 409, 20210315
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  62. Simple generation of various alpha-monofluoroalkyl radicals by organic photoredox catalysis: modular synthesis of beta-monofluoroketones, CHEMICAL COMMUNICATIONS, 57(21), 2609-2612, 20210314
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  63. Light-triggered elimination of CO2 and absorption of O-2 (artificial breathing reaction) in photolysis of 2-(4-nitrophenyl)-1H-indole derivatives, PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 20(3), 421-434, 202103
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  64. Chemistry of Tertiary Carbon Center in the Formation of Congested C-O Ether Bonds, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 60(8), 4329-4334, 20210219
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  65. Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with pi-single bonding character, CHEMICAL SCIENCE, 12(2), 613-625, 20210114
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  66. Dynamic solvent effects in radical-radical coupling reactions: an almost bottleable localised singlet diradical, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 22(48), 20201228
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  67. Conformation of K+(Crown Ether) Complexes Revealed by Ion Mobility-Mass Spectrometry and Ultraviolet Spectroscopy, JOURNAL OF PHYSICAL CHEMISTRY A, 124(48), 9980-9990, 20201203
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  68. Structural Transformation of the 2-(p-Aminophenyl)-1-hydroxyinden-3-ylmethyl Chromophore as a Photoremovable Protecting Group, CHEMPHOTOCHEM, 4(12), 5392-5398, 202012
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  69. Photoinduced alpha-Cleavage of 2-Azido-2-phenyl-1,3-indandione at Cryogenic Temperatures, ORGANIC LETTERS, 22(20), 7885-7890, 20201016
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  70. Heavy-Atom Tunneling Processes during Denitrogenation of 2,3-Diazabicyclo[2.2.1]hept-2-ene and Ring Closure of Cyclopentane-1,3-diyl Diradical. Stereoselectivity in Tunneling and Matrix Effect, JOURNAL OF ORGANIC CHEMISTRY, 85(14), 8881-8892, 20200717
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  71. Photochemical [2+2] cycloaddition reaction of carbonyl compounds with Danishefsky diene, ORGANIC & BIOMOLECULAR CHEMISTRY, 18(26), 4962-4970, 20200714
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  72. Reactivity and Product Analysis of a Pair of Cumyloxyl and tert-Butoxyl Radicals Generated in Photolysis of tert-Butyl Cumyl Peroxide, JOURNAL OF ORGANIC CHEMISTRY, 85(13), 8627-8638, 20200702
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  73. Photoinduced Reactivity in a Dispiro-1,2,4-trioxolane: Adamantane Ring Expansion and First Direct Observation of the Long-Lived Triplet Diradical Intermediates, JOURNAL OF PHYSICAL CHEMISTRY A, 124(21), 4202-4210, 20200528
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  74. Duality of Reactivity of a Biradicaloid Compound with an o-Quinodimethane Scaffold, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 142(11), 5408-5418, 20200318
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  75. Efficient Generation and Synthetic Applications of Alkyl-Substituted Siloxycarbenes: Suppression of Norrish-Type Fragmentations of Alkanoylsilanes by Triplet Energy Transfer, CHEMISTRY-A EUROPEAN JOURNAL, 26(6), 1249-1253, 20200127
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  76. Direct Suzuki-Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons, ACS CATALYSIS, 10(1), 346-351, 20200103
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  77. Insights into the photochemistry of 5-aminotetrazole derivatives with applications in coordination chemistry. Effect of the saccharyl moiety on the photostability, PURE AND APPLIED CHEMISTRY, 92(1), 49-62, 202001
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  78. Bulky Substituent Effect on Reactivity of Localized Singlet Cyclopentane-1,3-diyls with pi-Single Bonding (C-pi-C) Character, CHEMISTRY-AN ASIAN JOURNAL, 14(23), 4223-4228, 20191202
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  79. Photodecomposition of Thienylsulfonyl Azides: Generation and Spectroscopic Characterization of Triplet Thienylsulfonyl Nitrenes and 3-Thienylnitrene, JOURNAL OF PHYSICAL CHEMISTRY A, 123(43), 9311-9320, 20191031
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  80. Transforming Triplet Vinylnitrene into Triplet Alkylnitrene at Cryogenic Temperatures, ORGANIC LETTERS, 21(18), 7194-7198, 20190920
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  81. The Effect of Viscosity on the Diffusion and Termination Reaction of Organic Radical Pairs, CHEMISTRY-A EUROPEAN JOURNAL, 25(42), 9846-9850, 20190725
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  82. Formation and Reactivity of Triplet Vinylnitrenes as a Function of Ring Size, JOURNAL OF ORGANIC CHEMISTRY, 84(14), 9215-9225, 20190719
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  83. Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of alpha-CF2H-Substituted Ketones in Flow, ACS CATALYSIS, 9(7), 6555-6563, 201907
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  84. Separation of Spectroscopically Uniform Nanographenes, CHEMISTRY-AN ASIAN JOURNAL, 14(10), 1786-1791, 20190515
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  85. Generation of "Sumanenylidene": A Ground-State Triplet Carbene on a Curved -Conjugated Periphery, CHEMISTRY-AN ASIAN JOURNAL, 14(10), 1844-1848, 20190515
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  86. Generation of Extremely Long-lived Localized Singlet Diradicals: New Insights into Bond-homolysis Process and Discovery of Novel Bonding System (C-pi-C), JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 77(5), 503-511, 201905
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  87. Photochemical generation of the 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) radical from caged nitroxides by near-infrared two-photon irradiation and its cytocidal effect on lung cancer cells, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 15, 863-873, 20190410
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  88. 1,2-Diazacyclopentane-3,5-diyl Diradicals: Electronic Structure and Reactivity, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 141(9), 3920-3933, 20190306
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  89. Curve Effect on Singlet Diradical Contribution in Kekule-type Diradicals: A Sensitive Probe for Quinoidal Structure in Curved -Conjugated Molecules, MOLECULES, 24(1), 20190101
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  90. Chloro- and Dichloro-methylsulfonyl Nitrenes: Spectroscopic Characterization, Photoisomerization, and Thermal Decomposition, MOLECULES, 23(12), 201812
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  91. Methoxyphosphinidene and Isomeric Methylphosphinidene Oxide, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140(42), 13604-13608, 20181024
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  92. Extremely Long Lived Localized Singlet Diradicals in a Macrocyclic Structure: A Case Study on the Stretch Effect, CHEMISTRY-A EUROPEAN JOURNAL, 24(55), 14808-14815, 20181001
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  93. Triplet States of Tetrazoles, Nitrenes, and Carbenes from Matrix Photolysis of Tetrazoles, and Phenylcyanamide as a Source of Phenylnitrene, JOURNAL OF PHYSICAL CHEMISTRY A, 122(37), 7276-7283, 20180920
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  94. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer, CHEMICAL COMMUNICATIONS, 54(67), 9290-9293, 20180828
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  95. Sulfamoyl nitrenes: singlet or triplet ground state?, CHEMICAL COMMUNICATIONS, 54(48), 6136-6139, 20180618
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  96. Selective Probing of Potassium Ion in Solution by Intramolecular Excimer Fluorescence of Dibenzo-Crown Ethers, CHEMPHYSCHEM, 19(11), 1331-1335, 20180605
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  97. Unusually Long-Wavelength Emissions of Cyclopropanes: New Insight into C-C Bond Homolysis, CHEMISTRY-A EUROPEAN JOURNAL, 24(30), 7595-7600, 20180528
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  98. Direct Observation of an Imidoylnitrene: Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 57(12), 3212-3216, 20180312
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  99. Experimental Observation of Thermally Excited Triplet States of Heavier Group 15 Element Centered Diradical Dianions, CHEMISTRY-A EUROPEAN JOURNAL, 24(13), 3156-3160, 20180302
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  100. Photochemically Induced Intramolecular Radical Cyclization Reactions with Imines, JOURNAL OF ORGANIC CHEMISTRY, 83(4), 1867-1875, 20180216
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  101. Magnetically Bistable Nitrenes: Matrix Isolation of Furoylnitrenes in Both Singlet and Triplet States and Triplet 3-Furylnitrene, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140(1), 10-13, 20180110
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  102. Photochemical [2+2] cycloaddition reaction of enone derivatives with 2-siloxy-1H-pyrrole derivatives, ARKIVOC, 192-204, 2018
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  103. Fast Heavy-Atom Tunneling in Trifluoroacetyl Nitrene, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56(49), 15672-15676, 20171204
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  214. New development of localized 1,3-biradicals. Oxygen atom effects on most stable spin multiplicity and reactivity., Kagaku to Kogyo, 54(2), 164-167, 20010201
  215. Stereochemical Deuterium Labeling as Mechanistic Probe for Differentiating the Singlet- and Triplet-Diradical Spin States in the Rearrangement of the 2-Spiroepoxy-1,3-cyclopentanediyl to Oxetanes., Journal of the American Chemical Society, 122(27), 6508-6509, 20000701
  216. Paterno-Buechi Photocyclization of 2-Siloxyfurans and Carbonyl Compounds. Notable Substituent and Carbonyl (Aldehyde vs Ketone and Singlet- vs Triplet-Excited State) Effects on the Regioselectivity (Double-Bond Selection) in the Formation of Bicyclic exo-Oxetanes., Journal of Organic Chemistry, 65(11), 3426-3431, 20000401
  217. Notable Sulfur Atom Effects on the Regio- and Stereoselective Formation of Oxetanes in Paterno-Buechi Photocycloaddition of Aromatic Aldehydes with Silyl O,S-Ketene Acetals., Journal of the American Chemical Society, 122(17), 4005-4010, 20000401
  218. Lewis acid promoted ring-opening reactions of 2-methoxy-2-siloxyoxetane in the presence of allylsilane: notable lewis acid effect on the ring-opening regioselectivity of the oxetane., Main Group Metal Chemistry, 23(11), 651-654, 20000301
  219. Intramolecular and Intermolecular Reactivity of Localized Singlet Diradicals: The Exceedingly Long-Lived 2,2-Diethoxy-1,3-diphenylcyclopentane-1,3-diyl., Journal of the American Chemical Society, 122(9), 2019-2026, 20000301
  220. Memory of chirality in photochemical reactions., Kokagaku, 31(1), 28-29, 20000101
  221. 18O-Tracer Studies of Fe(II)-Induced Decomposition of 1,2,4-Trioxolanes (Ozonides) Derived from Cyclopentenes and Indenes. Inner-Sphere Electron Transfer Reduction of the Peroxide Linkage., Journal of the American Chemical Society, 121(28), 6556-6562, 19991001
  222. Photooxygenation (Electron transfer) of silyl enol ethers derived from 1-indanone: silyl group and medium effects on the competitive formation of 3-siloxy-1,2-dioxetane and ? -peroxy ketone., Main Group Metal Chemistry, 22(9), 539-543, 19990901
  223. Photooxygenation (1O2) of silyl enol ethers derived from indan-1-ones: competitive formation of tricyclic 3-siloxy-1,2-dioxetane and ? -silylperoxy ketone., Journal of the Chemical Society, Perkin Transactions 1, 2507-2512, 19990801
  224. Donor-Acceptor Binary Photocatalysis System Illustrated by the Intramolecular Cyclization of a Cyclopropanone Acetal Tethered to Cyclohexen-2-one., Bulletin of the Chemical Society of Japan, 72(3), 511-517, 19990301
  225. Photochemical Generation and Methanol Trapping of Localized 1,3 and 1,4 Singlet Diradicals Derived from a Spiroepoxy-Substituted Cyclopentane-1,3-diyl., Journal of the American Chemical Society, 120(44), 11304-11310, 19981201
  226. A stereoselective, tandem [2+2] photocycloaddition-hydrolysis route to aldol-type adducts., Journal of the Chemical Society, Perkin Transactions 1, 3261-3266, 19980901
  227. Regioselective formation of 2-alkoxyoxetanes in the photoreaction of aromatic carbonyl compounds with ? ,? -dimethyl ketene silyl acetals: notable solvent and silyl group effects., Journal of the Chemical Society, Perkin Transactions 1, 3253-3260, 19980901
  228. Regioselective formation of 2-alkoxyoxetanes in the photoreaction of aromatic carbonyl compounds with ? ,? -dimethyl ketene silyl acetals: notable solvent and silyl group effects., Journal of the Chemical Society, Perkin Transactions 1, 3253-3260, 19980901
  229. Electronic substituent effects on the EPR-spectral D parameter of trimethylenemethane (TMM) triplet diradicals compared with localized cyclopentane-1,3-diyls., Journal of the Chemical Society, Perkin Transactions 2, 1063-1068, 19980501
  230. Notable Substituent Electronic Effects on the Regioselectivity of an Oxygen-Atom Abstraction in the Reaction of Unsymmetrically Substituted Monocyclic 1,2-Dioxolanes with Triphenylphosphine., Journal of Organic Chemistry, 62(3), 752-754, 19970201
  231. Photoinduced electron transfer reactions of cyclopropanone acetal with conjugated enones in the presence of a redox-type photosensitizer., Tetrahedron Letters, 37(11), 1833-1836, 19961101
  232. Selectivity in the ring-expansion and ring-switching reactions of bicyclooxonium ions., Journal of the Chemical Society, Perkin Transactions 1, 413-416, 19960501
  233. Oxidative Ring-Opening Reaction of Cyclopropanone Acetals with Carbonyl Compounds via Photoinduced Electron Transfer. Generation of a ? -Carbonyl Radical Species and Its Application to the Synthesis of ? -Hydroxy Ester Derivatives., Journal of Organic Chemistry, 60(10), 3065-3073, 19950301
  234. Electron Transfer Profile of Cyclopropanone Acetals in the Nonirradiated Reaction with Tetracyanoethylene, Chloranil, and Dicyanodichlorobenzoquinone., Journal of Organic Chemistry, 59(24), 7445-7452, 19941201
  235. Formation of unsaturated esters in the single electron transfer reaction of cyclopropanone acetals with quinones under non-irradiation conditions., Tetrahedron Letters, 35(21), 3551-3554, 19941101
  236. Photoinduced electron transfer reaction of cyclpropanone acetals with arylmethyl methanesulfonate: generation of ? -keto radical species and application to C-C bond formation., Journal of the Chemical Society, Chemical Communications, 1673-1674, 19940701
  237. Ring-opening addition reaction of cyclopropanol derivatives with carbenes., Tetrahedron Letters, 33(47), 7169-7172, 19921201
  238. Bis(2-acetoxyacrylonitrile) and its phenylene and alkylene bis homologs. Preparation, isomerization, and intramolecular [2 + 2] photocycloaddition., Journal of Organic Chemistry, 57(8), 2263-2266, 19920401
  239. Studies on The Application of The Paterno-Buchi Reaction to The Synthesis of Novel Fluorinated Scaffolds, CHEMISTRY-A EUROPEAN JOURNAL, 27(63), 15722-15729, 20211111
    Link to Paper Search Results by DOI
  240. Singly Occupied Molecular Orbital-Highest Occupied Molecular Orbital (SOMO-HOMO) Conversion, AUSTRALIAN JOURNAL OF CHEMISTRY, 74(12), 827-837, 2021
    Link to Paper Search Results by DOI
  241. 2-Arylquinolines as novel anticancer agents with dual EGFR/FAK kinase inhibitory activity: synthesis, biological evaluation, and molecular modelling insights, JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 37(1), 349-372, 20220101
    Link to Paper Search Results by DOI

Publications such as books

  1. 2015, Chemical Science of π-Electron Systems, Localized Singlet 1,3-Diradicals, springer, 2015
  2. 2014, Methods and Applications of Cycloaddition Reactions in Organic Syntheses, [3+2] Cycloaddition of α,β-Unsaturated Metal-Carbene Complexes, wiley, 2014
  3. 2010, Handbook of Synthetic Photochemistry, (97) Formation of a 4-membered ring: Oxetanes, wiley, 2010

Invited Lecture, Oral Presentation, Poster Presentation

  1. Photochemical Release of 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) Radical from Caged Nitroxides by Near Infrared Two-photon Irradiation and Its Cytocidal effect on Lung Cancer Cells, Manabu Abe, Asian Photochemistry Conference 2018, 2018/12/17, With Invitation, English, Asian Photochemistry Association, Taipei
  2. Design and synthesis of NIR two-photon responsive chromophores, Manabu Abe, 14th Korea-Japan Symposium on Frontier Photoscience: Photochemistry, Solar Cells, and Photocatalysts, 2018/10/26, With Invitation, Japanese
  3. Is π SIngle Bonding Possible?, Manabu Abe, 24th IUPAC International Conference on Physical Organic Chemistry, 2018/06/06, With Invitation, Japanese
  4. Design and synthesis of NIR two-photon responsive chromophores, Manabu Abe, International Symposium on Caged Compounds, 2018/03/09, With Invitation, Japanese
  5. Unusually Long-wavelength Emissions of Bicyclo[2.1.0]pentanes: New Insight unto C–C Bond Homolysis, Manabu Abe, Molecular Biradicals: Structure, Properties, and Reactivity, 2018/03/01, With Invitation, Japanese
  6. Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light, Manabu Abe, International Conference on Chemical Science and Technology, 2018/02/24, With Invitation, English
  7. Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light, Manabu Abe, Korea-Japan Frontier PhotoSceince (KJFP-2017), 2017/10/26, With Invitation, English
  8. Is π SIngle Bonding Possible?, Manabu Abe, Japan-Taiwan Bilateral Conference on Molecular Architecture, 2017/10/15, With Invitation, Japanese
  9. Nitrogen Atom Effect on Reactivity of 1,3-Diradicals, Manabu Abe, European Symposium on Organic Reactivity, 2017/09/05, With Invitation, English
  10. Is π SIngle Bonding Possible?, Manabu Abe, Herbert Mayr’s 70th Birthday, 2017/08/03, With Invitation, English
  11. Localized Diradicals on Macrocyclic Ring Systems, Manabu Abe, 8th Pacific Symposium on Radical Chemistry, 2017/07/18, With Invitation, English, Prof. Steven Bottle, QUT, Queensland University of Technology, Localized Diradicals on Macrocyclic Ring Systems
  12. Localized Diradicals in Macrocyclic Ring Systems, Manabu Abe, International Symposium on Reactive Intermediates and Unusual Molecules (ISRIUM), 2017/06/18, With Invitation, English, Das Thamattoor Department of Chemistry Colby College, Sorrento, Localized Diradicals in Macrocyclic Ring Systems
  13. A Challenge in Organic Chemistry: Is -Single Bonding Possible?, Manabu Abe, International Symposium of SFB 749 on "Dynamics and Intermediates of Molecular Transformations", 2017/04/02, With Invitation, English, Ludwig-Maximilians-Universität München Fakultät für Chemie und Pharmazie, München, A Challenge in Organic Chemistry: Is -Single Bonding Possible?
  14. Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light, Manabu Abe, WPI IIIS, 2016/11/26, With Invitation, English, WPI IIIS, Tsukuba, WPI IIIS, Tsukuba, Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light
  15. Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light, Manabu Abe, IBSC 2016, 2016/09/26, With Invitation, English, Design and Synthesis of New Chromophores for Two-Photon Uncaging Reaction using Near IR Light
  16. Chameleonic Character of 1,2-Diazacyclopentane-3,5-diyl Diradical, Manabu Abe, TSRC Radicals in the Rockies, 2016/08/01, With Invitation, English, Wolfram Sander, Telluride, USA, Chameleonic Character of 1,2-Diazacyclopentane-3,5-diyl Diradical
  17. Is pai-Single-bonding Possible?, Manabu Abe, The 23rd IUPAC Conference on Physical Organic Chemistry (ICPOC-23), 2016/07/03, With Invitation, English, Jason Harper, Sydney, Australia, Is pai-Single-bonding Possible?

Awards

  1. 2024/12/02, Asian Core Program Lectureship Award, Coordinator of Singapore, Is π-Single Bonding (C–π–C) Possible? A Challenge in Organic Chemistry
  2. 2010, Australian Journal of Chemistry, Lectureship Award, Australian Journal of Chemistry
  3. 2007, The Zimmer Award, Cincinnati University
  4. 2007, Nozoe Memorial Award for Young Organic Chemist (2007), 基礎有機化学会, Generation of Long-lived Singlet Biradicals: Studies on the Structure and Reactivity
  5. 2007, Chemistry Research Promotion Center, Taiwan Lectureship Award, Chemistry Research Promotion Center, Taiwan
  6. 2005, Incentive Award in Synthetic Organic Chemistry, Japan (2005)., 有機合成化学協会, 反応性中間体の反応挙動精査に基づく合成反応の開発
  7. 2004, The Award for the Best Presentation on the 1st International Symposium in Chemistry at Gumma (2004), 群馬国際化学会議実行委員長・西村淳, Heteroatom Effects on the Reactivity of Cyclopentane-1,3-Diyls

Patented

  1. Patent, 6366269, 2018/07/13
  2. Patent, 6797410, 2020/11/20

External Funds

Acceptance Results of Competitive Funds

  1. KAKENHI(Grant-in-Aid for Scientific Research (B)), 2021, 2023
  2. Strategic Basic Research Programs(CREST), 2018/10/01, 2024/03/31
  3. KAKENHI(Grant-in-Aid for Challenging Research (Exploratory)), 2020, 2021
  4. Strategic Basic Research Programs(CREST), 2018/10/01, 2020/03/31
  5. Strategic Basic Research Programs(CREST), 2018/10/01, 2021/03/31
  6. Strategic Basic Research Programs(CREST), 2018/10/01, 2023/03/31
  7. KAKENHI(Grant-in-Aid for Scientific Research (B)), 2017, 2019
  8. KAKENHI(Grant-in-Aid for JSPS Research Fellow), 2017, 2019
  9. KAKENHI, 2016, 2017
  10. KAKENHI, 2012, 2016
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  11. KAKENHI, 2011, 2012
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  12. Strategic Basic Research Programs(CREST), 2010/10/01, 2016/03/31
  13. KAKENHI, 2009, 2010
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  14. KAKENHI, 2008, 2009
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  15. KAKENHI, 2007, 2008
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  16. KAKENHI, 2007, 2007
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  17. KAKENHI, Development of Novel Molecular Transformation Reaction and Functionalization, Based on the Stabilization of Open-Shell Molecules, 2007, 2010
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  18. 2006
  19. 2005
  20. KAKENHI, New Development of Biradical Chemistry : Construction of a Novel Structure, 2005, 2006
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  21. 2003
  22. KAKENHI, 2000, 2001
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  23. KAKENHI, 2000, 2000
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  24. KAKENHI, 2000, 2001
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  25. KAKENHI, 1999, 1999
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  26. KAKENHI, 1999, 1999
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  27. KAKENHI, 1999, 1999
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  28. KAKENHI, 1998, 1999
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  29. KAKENHI, 1998, 1998
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  30. KAKENHI, 1998, 1998
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Social Activities

History as Committee Members

  1. Editorial Board, 2016/09/10, Advanced of Physical Organic Chemistry
  2. Organizing Committee Member, 2016/05/01, IUPAC S/C on Structual and Mechanistic Chemistry
  3. Associate Editor, 2012/09/01, Australian Jouranal of Chemistry

Organizing Academic Conferences, etc.

  1. 24th International conference on Photochemical Conversion and Storage of Solar Energy
  2. 2007/08
  3. International Symposium on Reactive Intermediates and Unusual Molecules, 2014/04, 2014/04
  4. 27th Symposium on Physical Organic Chemistry, 2016/09, 2016/09
  5. International Symposium on Reactive Intermediates and Unusual Molecules, 2015/12, 2015/12
  6. Pre-symposium on IUPAC Photochemistry, 2016/04, 2016/04
  7. 2015/07, 2015/07
  8. Pre-Symposium of Fujihara Seminar, 2016/04, 2016/04
  9. International Symposium on Stimuli-responsive Chemical Species for the Creation of Functional Molecules, organizing committee member, 2017/03, 2017/03
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  10. International Symposium on Stimuli-responsive Chemical Species for Young Chemists, organizing committee, 2016/12, 2016/12
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  11. International Symposium on Stimuli-responsive Chemical Species for Young Chemists, organizing committee, 2016/03, 2016/03
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  12. International Symposium on Stimuli-responsive Chemical Species for Young Chemists, organizing committee, 2014/12, 2014/12
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