TAKEHIRO HIRAO

Last Updated :2021/05/06

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Assistant Professor
Web Site
E-mail
thiraohiroshima-u.ac.jp
Other Contact Details
1–3–1 Kagamiyama, Higashi-Hiroshima, Hiroshima, Japan, Japan
TEL : (+81)82-424-7403 FAX : (+81)82-424-0724
Self-introduction
Researcher number: 20825343

Basic Information

Major Professional Backgrounds

  • 2013/04, Japan Society for the Promotion of Science, JSPS research fellow (DC1)
  • 2016/04, University of Texas at Austin, postdoctoral fellow
  • 2018/04, 2020/03/31, Hiroshima University, Graduate School of Science, Assistant Professor
  • 2020/04, Hiroshima University, Graduate School of Advanced Science and Engineering, Assistant Professor

Educational Backgrounds

  • Hiroshima University, Graduate School of Science , Chemistry Ph.D., Japan, 2013/04, 2016/03
  • Hiroshima University, Graduate School of Science , Japan, 2011/04, 2013/03

Academic Degrees

  • Hiroshima University
  • Hiroshima University

Research Fields

  • Chemistry;Basic chemistry;Organic chemistry

Research Keywords

  • Supramolecular chemistry
  • Noncovalent polymer
  • Organic Chemistry

Affiliated Academic Societies

  • The chemical society of Japan
  • The society of polymer science, Japan
  • The society of synthetic organic chemistry, Japan

Educational Activity

Course in Charge

  1. 2021, Undergraduate Education, Second Semester, Exercises in Organic Chemistry
  2. 2021, Undergraduate Education, First Semester, Chemical Experiments I
  3. 2021, Undergraduate Education, Second Semester, Chemical Experiments II
  4. 2021, Undergraduate Education, 2Term, Introduction to Advanced and Integrated Science
  5. 2021, Graduate Education (Master's Program) , First Semester, Organic Stereochemistry (Seminar)
  6. 2021, Graduate Education (Master's Program) , Second Semester, Organic Stereochemistry (Seminar)
  7. 2021, Graduate Education (Master's Program) , First Semester, Joint Seminar of Organic Chemistry (Seminar)
  8. 2021, Graduate Education (Doctoral Program) , First Semester, Organic Stereochemistry (Seminar)
  9. 2021, Graduate Education (Doctoral Program) , Second Semester, Organic Stereochemistry (Seminar)
  10. 2021, Graduate Education (Master's Program) , 3Term, Exercises in Chemistry B
  11. 2021, Graduate Education (Master's Program) , 1Term, Exercises in Chemistry A

Research Activities

Academic Papers

  1. Self-assembly of neutral platinum complexes possessing chiral hydrophilic TEG chains, Org. Bio. Chem., DOI: 10.1039/D1OB00492A, in Press
  2. Self-Assembling Behavior and Chiroptical Properties of Carbazole-Cored Phenyl Isoxazolyl Benzenes, J. Org. Chem., 86(8), 5499-5505, 2021
  3. ★, Helically Organized Fullerene Array in a Supramolecular Polymer Main Chain, J. Am. Chem. Soc., 143, 4339-4345, 2021
  4. Stereoselectivity in Dehydrative Cyclic Trimerization of Substituted 4-Alkylaminobenzoic Acids, New J. Chem., 45, 1187-1193, 2021
  5. A Light Harvesting/Charge Separation Model with Energy Gradient Made of Assemblies of meta-pyridyl Zinc Porphyrins, Chem. Eur. J., 27, 4053-4063, 2021
  6. Supramolecular fluorescent sensors: An historical overview and update, Coord. Chem. Rev., 15(427), Article number 213560, 2021
  7. Self-Healing Supramolecular Materials Constructed by Copolymerization via Molecular Recognition of Cavitand-based Coordination Capsules, Angew. Chem. Int. Ed., 59, 16690-16697, 2020
  8. A dual redox-responsive supramolecular polymer driven by molecular recognition between bisporphyrin and trinitrofluorenone, Chemical Communications, 56, 7553-7556, 2020
  9. Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene, Chemical Communications, 56, 6672-6675, 2020
  10. Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation, Organic Letter, 22, 5294-5298, 2020
  11. ★, Supramolecular Approach to Polymer-Shape Transformation via Calixarene–Fullerene Complexation, Macromolecules, 53(9), 3563-3570, 2020
  12. Supramolecular Polymerization and Functions of Isoxazole Ring Monomers, Chem. Lett., 49, 574-584, 2020
  13. AIE-active micelles formed by self-assembly of an amphiphilic platinum complex possessing isoxazole moieties, Chem. Commun., 56, 1137-1140, 2020
  14. Helical assembly of a dithienogermole exhibiting switchable circularly polarized luminescence, Chemical Communications, 55, 10607-10610, 2019
  15. Ring–Chain Competition in Supramolecular Polymerization Directed by Molecular Recognition of the Bisporphyrin Cleft, Macromolecules, 52(16), 6160-6168, 2019
  16. Supramolecular Properties of a Monocarboxylic Acid-Functionalized Texas-Sized Molecular Box, J. Am. Chem. Soc., 6823-6831, 2018
  17. ★, Control over multiple molecular states with directional changes driven by molecular recognition, Nat. Commun., 823, 2018
  18. ★, Sequence-controlled supramolecular terpolymerization directed by specific molecular recognitions, Nat. Commun., 634, 2017
  19. Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes, ChemistrySelect, 11322-11327, 2017
  20. Synthesis and Properties of Novel Optically Active Platinum-containing Poly(phenyleneethynylene)s, Chem. Lett., 937-939, 2016
  21. Synthesis of Optically Active Conjugated Polymers Containing Platinum in the Main Chain: Control of the Higher-Order Structures by Substituents and Solvents, J. Polym. Sci., Part A: Polym. Chem., 2452-2461, 2015
  22. Supramoelcular Porphyrin Copolymer Assembled through Host-Guest Interactions and Metal-Ligand Coordination, Angew. Chem. Int. Ed., 14830-14834, 2015
  23. Liposome collapse resulting from an allosteric interaction between 2,6-dimethyl-β-cyclodextrins and lipids, RSC Adv., 77746-77754, 2015
  24. ★, Supramolecular Fullerene Polymers and Networks Directed by Molecular Recognition between Calix[5]arene and C60, Chem. –Eur. J., 16136-16146, 2014
  25. Self-Assembly of Oligo(phenylisoxazolyl)benzenes Induced by Multiple Dipole-Dipole Interactions, Chem. Lett., 414-416, 2013
  26. Synthesis of Optically Active Poly(m-phenyleneethynylene-aryleneethynylene)s Bearing Hydroxy Groups and Examination of the Higher Order Structures, Macromolecules, 8161-8170, 2013
  27. Circular Dichroism and Circularly Polarized Luminescence Triggered by Self-Assembly of Tris(phenylisoxazolyl)benzene Possessing Perylenebisimide, Chem. Commun., 6025-6027, 2012
  28. Supramolecular Polymerization Triggered by Molecular Recognitioin between Bisporphyrin and Trinitrofluorenone, Angew. Chem. Int. Ed., 1473-1476, 2012

External Funds

Acceptance Results of Competitive Funds

  1. 2021, 2022
  2. KAKENHI (Grant-in-Aid for Young Scientists), 2020, 2022
  3. KAKENHI (Grant-in-Aid for Research Activity Start-up), 2018, 2020
  4. KAKENHI (Grant-in-Aid for JSPS Fellows), 2013, 2016