TAKEHIRO HIRAO

Last Updated :2021/01/14

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Assistant Professor
Web Site
E-mail
thiraohiroshima-u.ac.jp
Other Contact Details
1–3–1 Kagamiyama, Higashi-Hiroshima, Hiroshima, Japan, Japan
TEL : (+81)82-424-7403 FAX : (+81)82-424-0724
Self-introduction
Researcher number: 20825343

Basic Information

Educational Backgrounds

  • Hiroshima University, Graduate School of Science , Chemistry Ph.D., Japan, 2013/04, 2016/03
  • Hiroshima University, Graduate School of Science , Japan, 2011/04, 2013/03

Academic Degrees

  • Hiroshima University
  • Hiroshima University

Research Fields

  • Chemistry;Basic chemistry;Organic chemistry

Research Keywords

  • Supramolecular chemistry
  • Noncovalent polymer
  • Organic Chemistry

Affiliated Academic Societies

  • The chemical society of Japan
  • The society of polymer science, Japan
  • The society of synthetic organic chemistry, Japan

Educational Activity

Course in Charge

  1. 2020, Undergraduate Education, Second Semester, Exercises in Organic Chemistry
  2. 2020, Undergraduate Education, First Semester, Chemical Experiments I
  3. 2020, Undergraduate Education, Second Semester, Chemical Experiments II
  4. 2020, Undergraduate Education, 2Term, Introduction to Advanced and Integrated Science
  5. 2020, Graduate Education (Master's Program) , First Semester, Organic Stereochemistry (Seminar)
  6. 2020, Graduate Education (Master's Program) , Second Semester, Organic Stereochemistry (Seminar)
  7. 2020, Graduate Education (Master's Program) , First Semester, Joint Seminar of Organic Chemistry (Seminar)
  8. 2020, Graduate Education (Doctoral Program) , First Semester, Organic Stereochemistry (Seminar)
  9. 2020, Graduate Education (Doctoral Program) , Second Semester, Organic Stereochemistry (Seminar)
  10. 2020, Graduate Education (Master's Program) , 1Term, Exercises in Chemistry A
  11. 2020, Graduate Education (Master's Program) , 3Term, Exercises in Chemistry B

Research Activities

Academic Papers

  1. Stereoselectivity in Dehydrative Cyclic Trimerization of Substituted 4-Alkylaminobenzoic Acids, New J. Chem., in Press
  2. A Light Harvesting/Charge Separation Model with Energy Gradient Made of Assemblies of meta-pyridyl Zinc Porphyrins, Chem. Eur. J., in Press
  3. Supramolecular fluorescent sensors: An historical overview and update, Coord. Chem. Rev., 15(427), Article number 213560, 2021
  4. Self-Healing Supramolecular Materials Constructed by Copolymerization via Molecular Recognition of Cavitand-based Coordination Capsules, Angew. Chem. Int. Ed., 59, 16690-16697, 2020
  5. A dual redox-responsive supramolecular polymer driven by molecular recognition between bisporphyrin and trinitrofluorenone, Chemical Communications, 56, 7553-7556, 2020
  6. Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene, Chemical Communications, 56, 6672-6675, 2020
  7. Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation, Organic Letter, 22, 5294-5298, 2020
  8. ★, Supramolecular Approach to Polymer-Shape Transformation via Calixarene–Fullerene Complexation, Macromolecules, 53(9), 3563-3570, 2020
  9. Supramolecular Polymerization and Functions of Isoxazole Ring Monomers, Chem. Lett., 49, 574-584, 2020
  10. AIE-active micelles formed by self-assembly of an amphiphilic platinum complex possessing isoxazole moieties, Chem. Commun., 56, 1137-1140, 2020
  11. Helical assembly of a dithienogermole exhibiting switchable circularly polarized luminescence, Chemical Communications, 55, 10607-10610, 2019
  12. Ring–Chain Competition in Supramolecular Polymerization Directed by Molecular Recognition of the Bisporphyrin Cleft, Macromolecules, 52(16), 6160-6168, 2019
  13. Supramolecular Properties of a Monocarboxylic Acid-Functionalized Texas-Sized Molecular Box, J. Am. Chem. Soc., 6823-6831, 2018
  14. ★, Control over multiple molecular states with directional changes driven by molecular recognition, Nat. Commun., 823, 2018
  15. ★, Sequence-controlled supramolecular terpolymerization directed by specific molecular recognitions, Nat. Commun., 634, 2017
  16. Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes, ChemistrySelect, 11322-11327, 2017
  17. Synthesis of Optically Active Conjugated Polymers Containing Platinum in the Main Chain: Control of the Higher-Order Structures by Substituents and Solvents, J. Polym. Sci., Part A: Polym. Chem., 2452-2461, 2015
  18. Synthesis and Properties of Novel Optically Active Platinum-containing Poly(phenyleneethynylene)s, Chem. Lett., 937-939, 2016
  19. Supramoelcular Porphyrin Copolymer Assembled through Host-Guest Interactions and Metal-Ligand Coordination, Angew. Chem. Int. Ed., 14830-14834, 2015
  20. Liposome collapse resulting from an allosteric interaction between 2,6-dimethyl-β-cyclodextrins and lipids, RSC Adv., 77746-77754, 2015
  21. ★, Supramolecular Fullerene Polymers and Networks Directed by Molecular Recognition between Calix[5]arene and C60, Chem. –Eur. J., 16136-16146, 2014
  22. Self-Assembly of Oligo(phenylisoxazolyl)benzenes Induced by Multiple Dipole-Dipole Interactions, Chem. Lett., 414-416, 2013
  23. Synthesis of Optically Active Poly(m-phenyleneethynylene-aryleneethynylene)s Bearing Hydroxy Groups and Examination of the Higher Order Structures, Macromolecules, 8161-8170, 2013
  24. Circular Dichroism and Circularly Polarized Luminescence Triggered by Self-Assembly of Tris(phenylisoxazolyl)benzene Possessing Perylenebisimide, Chem. Commun., 6025-6027, 2012
  25. Supramolecular Polymerization Triggered by Molecular Recognitioin between Bisporphyrin and Trinitrofluorenone, Angew. Chem. Int. Ed., 1473-1476, 2012

External Funds

Acceptance Results of Competitive Funds

  1. KAKENHI (Grant-in-Aid for Young Scientists), 2020, 2021
  2. KAKENHI (Grant-in-Aid for Research Activity Start-up), 2018, 2019
  3. KAKENHI (Grant-in-Aid for JSPS Fellows), 2013, 2016