TAKEHIRO HIRAO
Last Updated :2023/09/11
- Affiliations, Positions
- Graduate School of Advanced Science and Engineering, Assistant Professor
- Web Site
- E-mail
- thirao
hiroshima-u.ac.jp
- Other Contact Details
- 1–3–1 Kagamiyama, Higashi-Hiroshima, Hiroshima, Japan, Japan
TEL : (+81)82-424-7138 FAX : (+81)
- Self-introduction
- My research currently focuses on the development of non-covalently linked supramolecular polymeric ensembles.
Basic Information
Major Professional Backgrounds
- 2013/04, Japan Society for the Promotion of Science, JSPS research fellow (DC1)
- 2016/04, University of Texas at Austin, postdoctoral fellow
- 2018/04, 2020/03/31, Hiroshima University, Graduate School of Science, Assistant Professor
- 2020/04, Hiroshima University, Graduate School of Advanced Science and Engineering, Assistant Professor
Educational Backgrounds
- Hiroshima University, Graduate School of Science , Chemistry Ph.D., Japan, 2013/04, 2016/03
- Hiroshima University, Graduate School of Science , Japan, 2011/04, 2013/03
Academic Degrees
- Hiroshima University
- Hiroshima University
Research Fields
- Chemistry;Basic chemistry;Organic chemistry
Research Keywords
- Supramolecular chemistry
- Noncovalent polymer
- Organic Chemistry
Affiliated Academic Societies
- The chemical society of Japan
- The society of polymer science, Japan
- The society of synthetic organic chemistry, Japan
Educational Activity
Course in Charge
- 2023, Liberal Arts Education Program1, Intensive, Introduction to Science
- 2023, Liberal Arts Education Program1, Intensive, Introduction to Science
- 2023, Undergraduate Education, 4Term, Advanced Chemistry
- 2023, Undergraduate Education, First Semester, Special Study for Graduation
- 2023, Undergraduate Education, Second Semester, Special Study for Graduation
- 2023, Undergraduate Education, Second Semester, Exercises in Organic Chemistry
- 2023, Undergraduate Education, First Semester, Chemical Experiments I
- 2023, Undergraduate Education, Second Semester, Chemical Experiments II
- 2023, Undergraduate Education, 2Term, Introduction to Advanced and Integrated Science
- 2023, Graduate Education (Master's Program) , 1Term, Exercises in Chemistry A
- 2023, Graduate Education (Master's Program) , 2Term, Exercises in Chemistry A
- 2023, Graduate Education (Master's Program) , 3Term, Exercises in Chemistry B
- 2023, Graduate Education (Master's Program) , 4Term, Exercises in Chemistry B
- 2023, Graduate Education (Master's Program) , Academic Year, Master's Thesis in Chemistry
- 2023, Graduate Education (Doctoral Program) , Academic Year, Doctoral Thesis in Chemistry
Research Activities
Academic Papers
- Nanoarchitectonics of supramolecular porphyrins based on a bis(porphyrin) cleft molecule, J. Porphyri. Phthalocyanines, in Press, 2023
- Supramolecular Chiral Sensing by Supramolecular Helical
Polymers, Chem. Commun., 2023
- Development of Supramolecular Polymers with Unique Chain Structures, Supramolecular Nanotechnology: Advanced Design of Self-Assembled Functional Materials, ISBN-10: 3527349480, 2023
- Lanthanide and Actinide Ion Complexes Containing Organic Ligands Investigated by Surface-Enhanced Infrared Absorption Spectroscopy, Inorg. Chem., in Press, 2022
- Macromolecular architectures constructed by biscalix[5]arene–[60]fullerene host–guest interactions, Polymer Journal, 2022
- Improved synthesis of tetrakis(porphyrin) molecular cleft via palladium-mediated cross-coupling between a bis(porphyrin) boronic ester and bis(iodophenyl)butadiyne, J. Porphyr. Phthalocyanines, 2022
- Nonporous Adaptive Crystals for Separations, Kagaku, 77(8), 64-65, 2022
- Self-assembly of neutral platinum complexes controlled by thermal inputs, Chem. Commun., 58, 8356-8359, 2022
- Supramolecular Ensembles Formed via Calix[5]arene-Fullerene Host-Guest Interactions, Chem. Asian J., 17, e202200344, 2022
- Chiral Supramolecular Polymer Formed via Host-Guest Complexation of an Octaphosphonate Biscavitand and a Chiral Diammonium Guest, Bull. Chem. Soc. Jpn., 95, 621-627, 2022
- Non-Racemically Twisted Supramolecular Fullerene Polymers, KOBUNSHI, 71(1), 6-6, 2022
- ★, Self-Sorting Behavior in Supramolecular Fullerene Polymerization
Directed by Host-Guest Complexation between Calix[5]arene and
C60, Chem. Commun., 57, 11831-11834, 2021
- Solvent-Directed Formation of Helically Twisted Stacking Constructs via Self-Assembly of Tris(phenylisoxazolyl)benzene Dimers, Org. Biomol. Chem., 19, 7165-7171, 2021
- Gas-Phase UV Spectroscopy of Chemical Intermediates Produced in Solution: Oxidation Reactions of Phenylhydrazines by DDQ, J. Phys. Chem. A, 125, 6697-6702, 2021
- Self-Complementary Structure of Bisporphyrin Dimer, Chem. Lett., 50, 1844-1847, 2021
- Negative Cooperativity in Guest Binding of a Ditopic Self-Folding
Biscavitand, Org. Lett., 23, 6217-6221, 2021
- SUPRAMOLECULAR CHEMISTRY OF FULLERENES, Handbook of Fullerene Science and Technology, in Press, 2021
- ★, Polymerization of a biscalix[5]arene derivative, RSC Adv., 11, 17587-17594, 2021
- Self-assembly of neutral platinum complexes possessing chiral hydrophilic TEG chains, Org. Bio. Chem., 19, 5303-5311, 2021
- Self-Assembling Behavior and Chiroptical Properties of Carbazole-Cored Phenyl Isoxazolyl Benzenes, J. Org. Chem., 86(8), 5499-5505, 2021
- ★, Helically Organized Fullerene Array in a Supramolecular Polymer Main Chain, J. Am. Chem. Soc., 143, 4339-4345, 2021
- Stereoselectivity in Dehydrative Cyclic Trimerization of Substituted 4-Alkylaminobenzoic Acids, New J. Chem., 45, 1187-1193, 2021
- A Light Harvesting/Charge Separation Model with Energy Gradient Made of Assemblies of meta-pyridyl Zinc Porphyrins, Chem. Eur. J., 27, 4053-4063, 2021
- Supramolecular fluorescent sensors: An historical overview and update, Coord. Chem. Rev., 15(427), Article number 213560, 2021
- Self-Healing Supramolecular Materials Constructed by Copolymerization via Molecular Recognition of Cavitand-based Coordination Capsules, Angew. Chem. Int. Ed., 59, 16690-16697, 2020
- A dual redox-responsive supramolecular polymer driven by molecular recognition between bisporphyrin and trinitrofluorenone, Chemical Communications, 56, 7553-7556, 2020
- Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene, Chemical Communications, 56, 6672-6675, 2020
- Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation, Organic Letter, 22, 5294-5298, 2020
- ★, Supramolecular Approach to Polymer-Shape Transformation via Calixarene–Fullerene Complexation, Macromolecules, 53(9), 3563-3570, 2020
- Supramolecular Polymerization and Functions of Isoxazole Ring Monomers, Chem. Lett., 49, 574-584, 2020
- AIE-active micelles formed by self-assembly of an amphiphilic platinum complex possessing isoxazole moieties, Chem. Commun., 56, 1137-1140, 2020
- Helical assembly of a dithienogermole exhibiting switchable circularly polarized luminescence, Chemical Communications, 55, 10607-10610, 2019
- Ring–Chain Competition in Supramolecular Polymerization Directed by Molecular Recognition of the Bisporphyrin Cleft, Macromolecules, 52(16), 6160-6168, 2019
- Supramolecular Properties of a Monocarboxylic Acid-Functionalized Texas-Sized Molecular Box, J. Am. Chem. Soc., 6823-6831, 2018
- ★, Control over multiple molecular states with directional changes driven by molecular recognition, Nat. Commun., 823, 2018
- ★, Sequence-controlled supramolecular terpolymerization directed by specific molecular recognitions, Nat. Commun., 634, 2017
- Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes, ChemistrySelect, 11322-11327, 2017
- Synthesis of Optically Active Conjugated Polymers Containing Platinum in the Main Chain: Control of the Higher-Order Structures by Substituents and Solvents, J. Polym. Sci., Part A: Polym. Chem., 2452-2461, 2015
- Synthesis and Properties of Novel Optically Active Platinum-containing Poly(phenyleneethynylene)s, Chem. Lett., 937-939, 2016
- Supramoelcular Porphyrin Copolymer Assembled through Host-Guest Interactions and Metal-Ligand Coordination, Angew. Chem. Int. Ed., 14830-14834, 2015
- Liposome collapse resulting from an allosteric interaction between 2,6-dimethyl-b-cyclodextrins and lipids, RSC Adv., 77746-77754, 2015
- ★, Supramolecular Fullerene Polymers and Networks Directed by Molecular Recognition between Calix[5]arene and C60, Chem. –Eur. J., 16136-16146, 2014
- Self-Assembly of Oligo(phenylisoxazolyl)benzenes Induced by Multiple Dipole-Dipole Interactions, Chem. Lett., 414-416, 2013
- Synthesis of Optically Active Poly(m-phenyleneethynylene-aryleneethynylene)s Bearing Hydroxy Groups and Examination of the Higher Order Structures, Macromolecules, 8161-8170, 2013
- Circular Dichroism and Circularly Polarized Luminescence Triggered by Self-Assembly of Tris(phenylisoxazolyl)benzene Possessing Perylenebisimide, Chem. Commun., 6025-6027, 2012
- Supramolecular Polymerization Triggered by Molecular Recognitioin between Bisporphyrin and Trinitrofluorenone, Angew. Chem. Int. Ed., 1473-1476, 2012
Invited Lecture, Oral Presentation, Poster Presentation
- Development of supramolecular fullerene assemblies via host-guest interactions, Takehiro Hirao, 2023/09/05, With Invitation, Japanese
- Pathway complexity in the self-assembly process of platinum
complexes possessing TEG chains, Takehiro Hirao, Masaya Yoshida, Takeharu Haino, The 103rd CSJ Annual Meeting, 2023/03/24, Without Invitation, English, Chiba
- Takehiro, Hirao, School of Chemistry and Chemical Engineering, Huazhong University of Science & Technology (HUST), Invited Lecture, 2022/12/22, With Invitation, English
- Takehiro, Hirao, Naoka Fujii, Yoshiki Iwabe, Takeharu Haino, 2022/12/16, Without Invitation, Japanese
- Takehiro, Hirao, 2022 International Conference on Modern Challenges in Polymer Science and Technology (2022 MCPST), 2022/01/18, With Invitation, English, Taiwan (online)
- Takehiro, Hirao, 2021/11/04, With Invitation, Japanese
Awards
- 2022/05/31, the Matsuura Award, 広島化学同窓会
External Funds
Acceptance Results of Competitive Funds
- KAKENHI (Grant-in-Aid for Young Scientists), 2022, 2025
- KAKENHI (Grant-in-Aid for Scientific Research (A)) (collaborator), 2021, 2025
- 2021, 2022
- KAKENHI (Grant-in-Aid for Young Scientists), 2020, 2022
- KAKENHI (Grant-in-Aid for Research Activity Start-up), 2018, 2020
- KAKENHI (Grant-in-Aid for JSPS Fellows), 2013, 2016