TAKEHIRO HIRAO

Last Updated :2021/05/06

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Assistant Professor
Web Site
https://orgchem.hiroshima-u.ac.jp/
E-mail
thiraohiroshima-u.ac.jp
Other Contact Details
1–3–1 Kagamiyama, Higashi-Hiroshima, Hiroshima, Japan, Japan
TEL : (+81)82-424-7403 FAX : (+81)82-424-0724
Self-introduction
Researcher number: 20825343

Basic Information

Major Professional Backgrounds

  • 2013/04, Japan Society for the Promotion of Science, JSPS research fellow (DC1)
  • 2016/04, University of Texas at Austin, postdoctoral fellow
  • 2018/04, 2020/03/31, Hiroshima University, Graduate School of Science, Assistant Professor
  • 2020/04, Hiroshima University, Graduate School of Advanced Science and Engineering, Assistant Professor

Educational Backgrounds

  • Hiroshima University, Graduate School of Science , Chemistry Ph.D., Japan, 2013/04, 2016/03
  • Hiroshima University, Graduate School of Science , Japan, 2011/04, 2013/03

Academic Degrees

  • Hiroshima University
  • Hiroshima University

Research Fields

  • Chemistry;Basic chemistry;Organic chemistry

Research Keywords

  • Supramolecular chemistry
  • Noncovalent polymer
  • Organic Chemistry

Affiliated Academic Societies

  • The chemical society of Japan
  • The society of polymer science, Japan
  • The society of synthetic organic chemistry, Japan

Educational Activity

Course in Charge

  1. 2021, Undergraduate Education, Second Semester, Exercises in Organic Chemistry
  2. 2021, Undergraduate Education, First Semester, Chemical Experiments I
  3. 2021, Undergraduate Education, Second Semester, Chemical Experiments II
  4. 2021, Undergraduate Education, 2Term, Introduction to Advanced and Integrated Science
  5. 2021, Graduate Education (Master's Program) , First Semester, Organic Stereochemistry (Seminar)
  6. 2021, Graduate Education (Master's Program) , Second Semester, Organic Stereochemistry (Seminar)
  7. 2021, Graduate Education (Master's Program) , First Semester, Joint Seminar of Organic Chemistry (Seminar)
  8. 2021, Graduate Education (Doctoral Program) , First Semester, Organic Stereochemistry (Seminar)
  9. 2021, Graduate Education (Doctoral Program) , Second Semester, Organic Stereochemistry (Seminar)
  10. 2021, Graduate Education (Master's Program) , 3Term, Exercises in Chemistry B
  11. 2021, Graduate Education (Master's Program) , 1Term, Exercises in Chemistry A

Research Activities

Academic Papers

  1. Self-assembly of neutral platinum complexes possessing chiral hydrophilic TEG chains, Org. Bio. Chem., DOI: 10.1039/D1OB00492A, in Press
    Link to Paper Search Results by DOI
  2. Self-Assembling Behavior and Chiroptical Properties of Carbazole-Cored Phenyl Isoxazolyl Benzenes, J. Org. Chem., 86(8), 5499-5505, 2021
    Link to Paper Search Results by DOI
  3. ★, Helically Organized Fullerene Array in a Supramolecular Polymer Main Chain, J. Am. Chem. Soc., 143, 4339-4345, 2021
    Link to Paper Search Results by DOI
  4. Stereoselectivity in Dehydrative Cyclic Trimerization of Substituted 4-Alkylaminobenzoic Acids, New J. Chem., 45, 1187-1193, 2021
    Link to Paper Search Results by DOI
  5. A Light Harvesting/Charge Separation Model with Energy Gradient Made of Assemblies of meta-pyridyl Zinc Porphyrins, Chem. Eur. J., 27, 4053-4063, 2021
    Link to Paper Search Results by DOI
  6. Supramolecular fluorescent sensors: An historical overview and update, Coord. Chem. Rev., 15(427), Article number 213560, 2021
    Link to Paper Search Results by DOI
  7. Self-Healing Supramolecular Materials Constructed by Copolymerization via Molecular Recognition of Cavitand-based Coordination Capsules, Angew. Chem. Int. Ed., 59, 16690-16697, 2020
    Link to Paper Search Results by DOI
  8. A dual redox-responsive supramolecular polymer driven by molecular recognition between bisporphyrin and trinitrofluorenone, Chemical Communications, 56, 7553-7556, 2020
    Link to Paper Search Results by DOI
  9. Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene, Chemical Communications, 56, 6672-6675, 2020
    Link to Paper Search Results by DOI
  10. Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation, Organic Letter, 22, 5294-5298, 2020
    Link to Paper Search Results by DOI
  11. ★, Supramolecular Approach to Polymer-Shape Transformation via Calixarene–Fullerene Complexation, Macromolecules, 53(9), 3563-3570, 2020
    Link to Paper Search Results by DOI
  12. Supramolecular Polymerization and Functions of Isoxazole Ring Monomers, Chem. Lett., 49, 574-584, 2020
    Link to Paper Search Results by DOI
  13. AIE-active micelles formed by self-assembly of an amphiphilic platinum complex possessing isoxazole moieties, Chem. Commun., 56, 1137-1140, 2020
    Link to Paper Search Results by DOI
  14. Helical assembly of a dithienogermole exhibiting switchable circularly polarized luminescence, Chemical Communications, 55, 10607-10610, 2019
  15. Ring–Chain Competition in Supramolecular Polymerization Directed by Molecular Recognition of the Bisporphyrin Cleft, Macromolecules, 52(16), 6160-6168, 2019
    Link to Paper Search Results by DOI
  16. Supramolecular Properties of a Monocarboxylic Acid-Functionalized Texas-Sized Molecular Box, J. Am. Chem. Soc., 6823-6831, 2018
  17. ★, Control over multiple molecular states with directional changes driven by molecular recognition, Nat. Commun., 823, 2018
    Link to Paper Search Results by DOI
  18. ★, Sequence-controlled supramolecular terpolymerization directed by specific molecular recognitions, Nat. Commun., 634, 2017
    Link to Paper Search Results by DOI
  19. Slow Intermolecular Complexation–Decomplexation Exchanges of Cyclodextrins in Fullerene and Its Derivative Complexes, ChemistrySelect, 11322-11327, 2017
  20. Synthesis and Properties of Novel Optically Active Platinum-containing Poly(phenyleneethynylene)s, Chem. Lett., 937-939, 2016
  21. Synthesis of Optically Active Conjugated Polymers Containing Platinum in the Main Chain: Control of the Higher-Order Structures by Substituents and Solvents, J. Polym. Sci., Part A: Polym. Chem., 2452-2461, 2015
  22. Supramoelcular Porphyrin Copolymer Assembled through Host-Guest Interactions and Metal-Ligand Coordination, Angew. Chem. Int. Ed., 14830-14834, 2015
  23. Liposome collapse resulting from an allosteric interaction between 2,6-dimethyl-β-cyclodextrins and lipids, RSC Adv., 77746-77754, 2015
  24. ★, Supramolecular Fullerene Polymers and Networks Directed by Molecular Recognition between Calix[5]arene and C60, Chem. –Eur. J., 16136-16146, 2014
    Link to Paper Search Results by DOI
  25. Self-Assembly of Oligo(phenylisoxazolyl)benzenes Induced by Multiple Dipole-Dipole Interactions, Chem. Lett., 414-416, 2013
  26. Synthesis of Optically Active Poly(m-phenyleneethynylene-aryleneethynylene)s Bearing Hydroxy Groups and Examination of the Higher Order Structures, Macromolecules, 8161-8170, 2013
  27. Circular Dichroism and Circularly Polarized Luminescence Triggered by Self-Assembly of Tris(phenylisoxazolyl)benzene Possessing Perylenebisimide, Chem. Commun., 6025-6027, 2012
  28. Supramolecular Polymerization Triggered by Molecular Recognitioin between Bisporphyrin and Trinitrofluorenone, Angew. Chem. Int. Ed., 1473-1476, 2012

External Funds

Acceptance Results of Competitive Funds

  1. 2021, 2022
  2. KAKENHI (Grant-in-Aid for Young Scientists), 2020, 2022
  3. KAKENHI (Grant-in-Aid for Research Activity Start-up), 2018, 2020
  4. KAKENHI (Grant-in-Aid for JSPS Fellows), 2013, 2016