西原 禎文SADAFUMI NISHIHARA

Last Updated :2021/01/05

所属・職名
大学院先進理工系科学研究科 教授
ホームページ
メールアドレス
snishihiroshima-u.ac.jp
その他連絡先
東広島市鏡山一丁目3番1号 理学部C棟C410
TEL:082-424-7418 FAX:082-424-7418
自己紹介
生体機能を化学的に模倣することで,新しいタイプの分子エレクトロニクスデバイス創出を目指して研究を行っています

基本情報

主な職歴

  • 2003年04月01日, 北海道大学, 電子科学研究所, 日本学術振興会特別研究員(DC)
  • 2004年04月01日, 名古屋大学, 大学院理学研究科, 日本学術振興会特別研究員(PD)
  • 2005年04月01日, 大阪府立大学, 大学院理学系研究科 物理科学専攻, 助教
  • 2005年08月01日, フランス国立科学研究センター, 在外研究員(兼任)
  • 2010年04月01日, 広島大学, 大学院理学研究科 化学専攻, 准教授
  • 2012年10月01日, グラスゴー大学, 客員上席研究員(兼任)
  • 2019年10月01日, 戦略的創造研究推進事業(さきがけ), JSTさきがけ研究員(兼任)
  • 2020年04月01日, 広島大学, 大学院先進理工系科学研究科, 教授

学位

  • 博士(学術) (北海道大学)

研究分野

  • 化学 / 複合化学 / 機能物性化学
  • 数物系科学 / 物理学 / 物性Ⅱ
  • 化学 / 材料化学 / デバイス関連化学

研究キーワード

  • 固体物性化学
  • 分子エレクトロニクス
  • 分子機械
  • 超分子化学

教育活動

授業担当

  1. 2020年, 修士課程・博士課程前期, 1ターム, サステナブル物質科学
  2. 2020年, 学部専門, セメスター(前期), 卒業研究
  3. 2020年, 学部専門, セメスター(後期), 卒業研究
  4. 2020年, 学部専門, セメスター(後期), 無機化学演習
  5. 2020年, 学部専門, 1ターム, 無機化学I
  6. 2020年, 修士課程・博士課程前期, セメスター(前期), 化学特別研究
  7. 2020年, 修士課程・博士課程前期, セメスター(後期), 化学特別研究
  8. 2020年, 修士課程・博士課程前期, セメスター(前期), 固体物性化学セミナー
  9. 2020年, 修士課程・博士課程前期, セメスター(後期), 固体物性化学セミナー
  10. 2020年, 博士課程・博士課程後期, セメスター(前期), 固体物性化学セミナー
  11. 2020年, 博士課程・博士課程後期, セメスター(後期), 固体物性化学セミナー
  12. 2020年, 修士課程・博士課程前期, 1ターム, 無機化学概論
  13. 2020年, 修士課程・博士課程前期, 2ターム, 固体物性化学
  14. 2020年, 修士課程・博士課程前期, 1ターム, 基礎化学特別演習A
  15. 2020年, 修士課程・博士課程前期, 3ターム, 基礎化学特別演習B
  16. 2020年, 修士課程・博士課程前期, 年度, 基礎化学特別研究
  17. 2020年, 博士課程・博士課程後期, 年度, 基礎化学特別研究
  18. 2020年, 修士課程・博士課程前期, 1ターム, サステナブル物質科学

研究活動

学術論文(★は代表的な論文)

  1. Co2+(15-crown-5) magnetic supramolecular cation in [Ni(dmit)2] π-spin system, J. Phys. Chem. B, 104巻, 25号, pp. 5871-5873, 2000
  2. Structure, optical and magnetic behaviour of meso-tetraphenylporphyrinatoiron (III) tetracyanoethenide, [FeIII(TPP)][TCNE], J. Chem. Soc., Dalton Trans., 4号, pp. 448-455, 2001
  3. [Ni(dmit)2] salt of a supramolecular cation, Sc3+(12-crown-4)2, Synth. Met., 121巻, 1-3号, pp. 1806-1807, 2001
  4. Formation of a molecular spin ladder induced by a supramolecular cation structure, Chem. Commun., 5号, pp. 408-409, 2002
  5. Two Polymorphs of (anilinium)(18-crown-6)[Ni(dmit)2]; Structure and Magnetic Properties, J. Solid State Chem., 168巻, 2号, pp. 661-667, 2002
  6. Structures of Flexible Supramolecular Cations (1,4-Cyclohexanediammonium2+)(Crown Ethers)2 in [Ni(dmit)2]- Salts, J. Supramol. Chem., 2巻, 1-3号, pp. 175-186, 2002
  7. Magnetic Properties of [Ni(dmit)2]- Anions Induced by Flexible Hydrogen-Bonded Supramolecular Cations [(p-Xylylenediammonium)0.5(Crown Ethers)]+, J. Phys. Chem. B, 107巻, 1号, pp. 66-74, 2003
  8. Magnetic and 1H-NMR spectroscopic studies of [Ph(NH3)](18-crown-6)[Ni(dmit)2] having molecular spin ladder structure, Synth. Met., 137巻, 1-3号, pp. 1279-1280, 2003
  9. Crystal Structure and Magnetic Properties of Gd2([18]crown-6)2(OH)2(CH3CN)[Ni(dmit)2]4 Complex Having f- and π-spins, Inorg. Chem., 42巻, 8号, pp. 2480-2482, 2003
  10. Molecular Rotor of Cs2([18]crown-6)3 in the Solid State Coupled with the Magnetism of [Ni(dmit)2], J. Am. Chem. Soc., 127巻, 12号, pp. 4397-4402, 2005
  11. Strong antiferromagnetic exchange interactions in quasi-one-dimensional (quasi-1D) compounds based on [Pd(dmit)2]- anions: Crystal structures, magnetic properties, and spin dimer analyses, Synth. Met., 150巻, 1号, pp. 57-61, 2005
  12. Crystal Structures and Magnetic Properties of [Ni(dmit)2]- Salts Including (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) Supramolecular Cations, Polyhedron, 24巻, 16-17号, pp. 2844-2848, 2005
  13. Two-dimensional molecular magnets based on [Pt(mnt)2]- ions: Structures and magnetic properties, Polyhedron, 24巻, 16-17号, pp. 2160-2164, 2005
  14. Cooperativity of dynamics of 18-crown-6 molecule forming one-dimensional chain in Cs2(18-crown-6)3[Ni(dmit)2]2, J. Chem. Phys., 123巻, 4号, pp. 044514, 2005
  15. Structural phase transition driven by spin-lattice interaction in a quasi-one-dimensional spin system of [1-(4-iodobenzyl)pyridinium][Ni(dmit)2], J. Phys. Chem. B, 109巻, 35号, pp. 16610-16615, 2005
  16. Supramolecular cations of (S)-, (R)-, and (SR)-Indan-1-aminium(dibenzo[18]crown-6) in magnetic [Ni(dmit)2]- salts, Eur. J. Inorg. Chem., 16号, pp. 3271-3276, 2005
  17. Novel spin transition observed in two quasi-one-dimensional spin system based on [M(mnt)2]- monoanion compounds (M=Ni or Pt; mnt2- = maleonitriledithiolate), Chem. Phys. Lett., 418巻, 4-6号, pp. 423-427, 2006
  18. Design of a Magnetic Bistability Molecular System Constructed by H-Bonding and π...π-Stacking Interactions, Inorg. Chem., 45巻, 5号, pp. 2229-2234, 2006
  19. Structural Phase Transition of Magnetic [Ni(dmit)2]- Salts Induced by Supramolecular Cation Structures of (M+)([12]crown-4)2, J. Phys. Chem. B, 110巻, 12号, pp. 5897-5904, 2006
  20. Structural and Magnetic Investigations for the Doping Effect of Nonmagnetic Impurity on the Spin-Peierls-like Transition in a Quasi-One-Dimensional Magnet: 1-(4'-Nitrobenzyl)pyridinium Bis(maleonitriledithiolato)nickelate, J. Phys. Chem. B, 110巻, 15号, pp. 7671-7677, 2006
  21. Quasi-one-dimensional molecular magnets based on derivatives of (fluorobenzyl)pyridinium with the [M(mnt)2] monoanion (M = Ni, Pd or Pt; mnt2- = maleonitriledithiolate): Syntheses, crystal structures and magnetic properties, Dalton Trans., 16号, pp. 1998-1994, 2006
  22. Diversities of coordination geometry at Cu2+ center in the bis(maleonitriledithiolato)cuprate complexes: Syntheses, magnetic properties, X-ray crystal structural analyses, and DFT calculations, Cryst. Growth Des., 6巻, 11号, pp. 2530-2537, 2006
  23. EPR Measurements of a Two-dimensional Spin Frustrated System, BIPNNBNO with S = 1 and S = 1/2, J. Phys: Condens. Matter., 51巻, pp. 91-94, 2006
  24. Magnetic Properties of a Spin-1 Ladder under Pressure, J. Magn. Mag. Mater., 310巻, 2号, pp. 420-422, 2007
  25. Spin density distribution in a partially magnetized organic quantum magnet, Phys. Rev. B, 75巻, 10号, pp. 104427-1-4, 2007
  26. Pressure effect on spin-Peierls-like transition in quasi-1D spin systems [RBzPy][Ni(mnt)2], Chem. Phys. Lett., 439巻, 4-6号, pp. 318-322, 2007
  27. Self-assembled molecular magnets from discrete dimer to one-dimensional helical chain: Syntheses, crystal structures and magnetic properties, Polyhedron, 26巻, pp. 4463-4469, 2007
  28. Multirotations of (anilinium)([18]crown-6) supramolecular cation structure in magnetic salt of [Ni(dmit)2]-, Chem. Asian J., 2巻, pp. 1083-1090, 2007 [Inside Cover Picture]
  29. 2D H-bonding molecular magnets based on [Ni(mnt)2]- monoanion: Syntheses, crystal structures and magnetic properties, Polyhedron, 33巻, 1号, pp. 1787-1792, 2007
  30. Microstructures related to the ferroelectric properties in BiFeO3-BaTiO3, Trans. MRS-J., 33巻, 1号, pp. 27-30, 2008
  31. Impurity effect of an S = 1/2 two leg spin ladder antiferromagnet [Ph(NH3)]([18]crown-6)[Ni(dmit)2] studied by ESR, J. Phys.: Conf. Ser., 150巻, pp. 042034-1-4, 2009
  32. Two d10 coordination polymers based on 4,4'-(hexafluoroisopropylidene)diphthalic acid: Syntheses, structures and physical properties, Inorg. Chem. Commun., 12巻, 6号, pp. 498-201, 2009
  33. Nano-sized domain structures in the psudocubic phase of (1-x)BiFeO3-xBaTiO3 (0.33<x<0.60), Trans. MRS-J., 34巻, 1号, pp. 47-50, 2009
  34. Ferroelectric Properties and Nano-Scaled Domain Structures in (1-x)BiFeO3-xBaTiO3 (0.33<x<0.50), Ferroelectrics, 385巻, pp. 155-161, 2009
  35. Cobalt(II) coordination polymers assembled from polycarboxylate and benzotriazole: Syntheses, structures and physical properties, Inorg. Chim. Acta, 362巻, 13号, pp. 4780-4784, 2009
  36. A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid: Synthesis, crystal structure and magnetic properties, Inorg. Chem. Commun., 12巻, 9号, pp. 895-897, 2009
  37. Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene, Inorg. Chim. Acta, 362巻, 14号, pp. 5103-5108, 2009
  38. Construction of hybrid d10 metal-organic frameworks by flexible aromatic dicarboxylate and N-donor ligands : syntheses, structures and physical properties, CrystEngComm., 11巻, 12号, pp. 2784-2796, 2009
  39. Synthesis, Structure and Magnetic Properties of a Novel Anion-Radical Salt Based on TCNQ, J. Inorg. Organometa. Polym. Mater., 20巻, 1号, pp. 177-181, 2010
  40. Syntheses and Characterizations of Three Cu(II) Complexes with 2,2 '-Bipyridine-3,3'-dicarboxylate and N-Donor Ancillary Ligands, J. Inorg. Organometa. Polym. Mater., 20巻, 1号, pp. 110-117, 2010
  41. Five 3D metal-organic frameworks constructed from V-shaped polycarboxylate acids and flexible imidazole-based ligands, CrystEngComm., 12巻, 4号, pp. 1175-1185, 2010
  42. Appearance of Magnetization Jumps in Magnetic Hysteresis Curves in Spinel Oxide FeV2O4, J. Appl. Phys., 107巻, pp. 09A504-1-3, 2010
  43. Synthesis, characterization, and crystal structures of two novel ion-pair complexes based on benzene-1,2-dithiolate ligand, Russ. J. Coord. Chem., 36巻, 3号, pp. 226-231, 2010
  44. Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid (Mellitic Acid), J. Inorg. Organomet. Polymer Matar., 20巻, 3号, pp. 564-569, 2010
  45. A Trinuclear Cu(II) Complex from the Use of Phenyl 2-Pyridyl Ketoxime: Structure and Magnetic Behavior, Synth. React. Inprg. Met. -Org. Chem., 40巻, 6号, pp. 421-424, 2010
  46. Synthesis, Crystal Structure, and Magnetic Property of a New Nickel(III) Complex Constructed from 1,2-Benezedithiolate, Synth. React. Inprg. Met. -Org. Chem., 40巻, 6号, pp. 416-420, 2010
  47. Stationary Behavior in Effective Magnetic Moment and Magnetization of 2,3,6-Trifluorophenyl Nitronyl Nitroxide Radical Crystals, Bull. Chem. Soc. Jpn., 83巻, 12号, pp. 1447-1454, 2010 [Selected Papers]
  48. Three zinc(II) complexes constructed from aromatic dicarboxylate and 1,4-bis((2-(pyridin-2-yl)-1H-imidazol-1-yl)methyl)benzene: Syntheses, crystal structures and luminescent properties, Inorg. Chem. Acta, 363巻, 14号, pp. 3932-3938, 2010
  49. Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Syntheses, crystal structures and luminescence, Inorg. Chem. Acta, 363巻, 14号, pp. 3727-3732, 2010
  50. New Photoluminescent Coordination Polymers Constructed from Dicarboxylate and 1,2-Bis(imidazol-1-ylmethyl)benzene, Russ. J. Coord. Chem., 36巻, 10号, pp. 739-745, 2010
  51. Three new nickel(III) compounds based on 2-thioxo-1,3-dithiole-4,5-dithiolate: Syntheses, structures, magnetic properties and theoretical analyses, Polyhedron, 29巻, 15号, pp. 2916-2923, 2010
  52. A chiral copper(II) inverse-9-metallacrown-3 complex: Synthesis, crystal structure, ferroelectric and magnetic properties, Inorg. Chim. Acta, 368巻, 1号, pp. 165-169, 2011
  53. A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline, J. Inorg. Organomet. Polymer Mater., 21巻, 1号, pp. 201-206, 2011
  54. Construction of two metal coordination polymers based on 1,4-terephthalate and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene, Russ. J. Coord. Chem., 37巻, 3号, pp. 202-210, 2011
  55. An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties, Inorg. Chem. Commun., 14巻, 6号, pp. 867-872, 2011
  56. Synthesis, Crystal Structure, Electronic Absorption and Magnetic Properties of a Novel Anion-Radical Salt Based on 7,7,8,8-Tetracyanoquinodimethane, J. Chem. Crystallogr., 41巻, 9号, pp. 1462-1267, 2011
  57. Synthesis, structure and magnetic properties of a pentanuclear Cu(II) coordination polymer with 4-(imidazol-1-yl)-benzoic acid, Inorg. Chem. Commun., 14巻, 9号, pp. 1444-1447, 2011
  58. Temperature-induced assembly of MOF polymorphs: Syntheses, structures and physical properties, CrysEngComm., 14巻, 5号, pp. 1856-1864, 2012
  59. Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands, J. Inorg. Org. Polym. Mat., 22巻, 1号, pp. 258-263, 2012
  60. Synthesis, Crystal Structure, and Magnetic Properties of a 3d-3d Mixed Heterometallic Coordination Polymer, Russ. J. Coord. Chem., 38巻, 2号, pp. 134-139, 2012
  61. A Coordination Polymer With a (3,4)-Connected (62.8)2(62.84) 3D Network: Synthesis, Crystal Structure and Luminescent Properties, Synth. React. Inorg. Metal-Org. nano-Met. Chem., 42巻, 9号, pp. 1222-1226, 2012
  62. Syntheses, Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Complexes With the Ditopic Ligand 1,3-Bis(imidazol-1-ylmethyl)benzene, J. Chem. Crystallogr., 42巻, 4号, pp. 416-422, 2012
  63. Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers, Inorg. Chim. Acta, 387巻, pp. 308-313, 2012
  64. THz ESR study of multiferroic material CuO under pulsed magnetic field, IRMMW-THz, pp. 1-3, 2012
  65. Molecular Photoconductor with Simultaneously Photocontrollable Localized Spins, J. Am. Chem. Soc., 134巻, 45号, pp. 18656-18666, 2012 [Front Cover Picture], [JACS Spotlight]
  66. Chiral Magnetic Soliton Lattice on a Chiral Helimagnet, Phys. Rev. Lett., 108巻, 10号, pp. 107202-1-5, 2012 [APS's very best papers], [APS Spotlighting Exceptional Research]
  67. Quick and selective synthesis of Li6[α-P2W18O62].28H2O soluble in various organic solvents, Dalton Trans., 42巻, 32号, pp. 11363-11366, 2013
  68. Anomalous magnetization behaviour in a single crystal of vanadium spinel FeV2O4, J. Phys.: Condens. Matter., 25巻, 41号, pp. 416008-1-8, 2013
  69. The effect of doping a molecular spin ladder with non-magnetic impurities, Dalton Trans., 42巻, 43号, pp. 15263-15266, 2013
  70. Interlayer Magnetoresistance due to Chiral Soliton Lattice Formation in Hexagonal Chiral Magnet CrNb6S6, Phys. Rev. Lett., 111巻, 19号, pp. 197204-1-5, 2013
  71. Crystal structure and magnetic properties of honeycomb-like lattice antiferromagnet p-BIP-V2, Phys. Rev. B, 87巻, 12号, pp. 125120-1-8, 2013
  72. On the Nature of the Structural and Magnetic Phase Transitions in the Layered Perovskite-Like (CH3NH3)2[(FeIICl4)Cl], Inorg. Chem., 53巻, 4号, pp. 2068-2075, 2014
  73. Synthesis and Physical Properties of Tetrathiafulvalene Derivatives with Ferrocene-terminated Substituents, Chem. Lett., 43巻, 7号, pp. 1131-1133, 2014
  74. Chiral Magnetic Soliton Lattice in MnSi, J. Phys. Soc. Conf. Proc., 2巻, pp. 010205-1-6, 2014
  75. Giant Photoconductivity in NMQ[Ni(dmit)2], Eur. J. Inorg. Chem., 24巻, pp. 4000-4009, 2014
  76. A magnetically isolated cuprate spin-ladder system: synthesis, structures, and magnetic properties, Dalton Trans., 43巻, 34号, pp. 12974-12981, 2014
  77. Electrical Network of Single-Crystalline Metal Oxide Nanoclusters Wired by π-Molecules, Angew. Chem. Int. Ed., 53巻, 42号, pp. 11228-11231, 2014 [Inside Back Cover Picture]
  78. Chiral Soliton Lattice in Chiral Magnetic Crystal CrNb3S6, J. Jpn. Soc. Powder Powder Metallurgy, 61巻, S1号, pp. S34-36, 2014
  79. A Cuprate Spin Ladder Linked by a Pyridyl Ligand, Chem. Lett., 43巻, 11号, pp. 1713-1715, 2014 [Editors’ Choice]
  80. Weak Ferromagnetism in Chiral Inorganic Compound CrSi, J. Phys. Soc. Conf. Proc., 3巻, pp. 014037-1-4, 2014
  81. High Magnetic Hardness for the Canted Antiferromagnetic, Ferroelectric, and Ferroelastic Layered Perovskite-like (C2H5NH3)2[(FeIICl4)Cl], Inorg. Chem., 54巻, 6号, pp. 2866-2874, 2015
  82. A heterospin pressure sensor, J. Mater. Chem. C, 3巻, 30号, pp. 7788-7791, 2015
  83. Multiple structural transformations coupled with switchable magnetic and dielectric responses in an amphidynamic crystal of 4'-tert-butylbenzyl-pyridinium bis(maleonitriledithiolate)nickelate, J. Mater. Chem. C, 3巻, 30号, pp. 7906-7915, 2015
  84. Magnetic soliton confinement and discretization effects arising from macroscopic coherence in a chiral spin soliton lattice, Phys. Rev. B, 92巻, 220412(R)号, pp. 1-6, 2015 [Editors’ Suggestion]
  85. Characteristic responses of a phospholipid molecular layer to polyols, Coll. Surf. B, 136巻, pp. 594-599, 2015
  86. Synthesis, Crystal Structure, and Magnetic Properties of a Chiral Cyanide-Bridged Bimetallic Framework K3[MnII(L-asp)]6[CrIII(CN)6]center dot 2H2O, Inorg. Chem., 55巻, 1号, pp. 300-306, 2016
  87. Orthorhombic distortion and orbital order in the vanadium spinel FeV2O4, Phys. Rev. B, 93巻, 2号, 2016
  88. Progressive Transformation between Two Magnetic Ground States for One Crystal Structure of a Chiral Molecular Magnet, Inorg. Chem., 55巻, 6号, pp. 3047-3057, 2016 [Front Cover Picture]
  89. Phase transitions and off-stoichiometric effects of vanadium spinel oxide CoV2O4, Mater. Res. Express, 3巻, 6号, pp. 066101-1-10, 2016
  90. Lanthanoid Template Isolation of the alpha-1,5 Isomer of Dicobalt(II)-Substituted Keggin Type Phosphotungstates: Syntheses, Characterization, and Magnetic Properties, Inorg. Chem., 55巻, 17号, pp. 8292-8300, 2016
  91. NMR study on the quasi one-dimensional quantum spin magnet with ladder structure, Hyper. Inter., 237巻, pp. 116-1-7, 2016
  92. Synthesis of ypsilon-Keggin-type Cobaltomolybdate-based 3D Framework Material and Characterization Using Atomic-scale HAADF-STEM and XANES, Inorg. Chem., 56巻, 4号, pp. 2042-2049, 2017
  93. Synthesis, Characterisation, and Structure of a Reduced Preyssler-Type Polyoxometalate, Chem. Lett., 46巻, 4号, pp. 602-604, 2017
  94. Collective resonant dynamics of the chiral spin soliton lattice in a monoaxial chiral magnetic crystal, Phys. Rev. B, 95巻, 10号, pp. 104415-1-5, 2017
  95. A Dielectric Anomaly Observed for Doubly Reduced Mixed-valence Polyoxometalate, Chem. Commun., 53巻, pp. 6824-6827, 2017 [Back Cover Picture]
  96. Two new sandwich-type manganese {Mn5} substituted polyoxotungstates: syntheses, crystal structures, electrochemistry and magnetic properties, Inorg. Chem., 56巻, 15号, pp. 8759-8767, 2017
  97. Coupling of Magnetic and Elastic Domains in the Organic Inorganic Layered Perovskite-like (C6H5C2H4NH3)2FeIICl4, Angew. Chem. Int. Ed., 56巻, 32号, pp. 9367-9370, 2017
  98. (Azulene-1,3-diyl)-bis(nitronyl nitroxide) and (Azulene-1,3-diyl)-bis(iminonitroxide) and Their Copper Complexes, Chem. Asian J., 12巻, 22号, pp. 2929-2941, 2017
  99. Magnetic solitons and magnetic phase diagram of the hexagonal chiral crystal CrNb3S6 in oblique magnetic fields, Phys. Rev. B, 96巻, 18号, 2017
  100. Co-Crystallization of Achiral Components into Chiral Network by Supramolecular Interactions: Coordination Complexes Organic Radical, Cryst. Growth Des., 17巻, 9号, pp. 4893-4899, 2017
  101. Preparation of Preyssler-type Phosphotungstate with One Central Potassium Cation and Potassium Cation Migration into the Preyssler Molecule to form Di-Potassium-Encapsulated Derivative, ACS Omega, 3巻, 2号, pp. 2363-2373, 2018
  102. Synthesis, crystal structures and magnetic properties of six coordination compounds constructed with pyridine iminomethyl-TEMPO radicals and [M(hfac)2] (M = CuII and MnCuII), CrystEngComm., 20巻, 21号, pp. 2961-2967, 2018
  103. ★, Giant Hysteretic Single-Molecule Electric Polarisation Switching above Room Temperature, Angew. Chem. Int. Ed., 57巻, 41号, pp. 13429-13432, 2018 [Inside Back Cover Picture], [Hot Paper]
  104. Chemo-chromism in an orthogonal dabco-based Co(II) network assembled by methanol-coordination and hydrogen bond formation, Dalton. Trans., 47巻, 23号, pp. 7656-7662, 2018
  105. Structural, Optical, Magnetic, and Dielectric Properties in Hybrid Solid Solutions of ZnαNi1-α(en)3Ag2I4 (0 < α < 1) by Varying the Relative Zn/Ni Content, ACS Omega, 3巻, 9号, pp. 10725-10732, 2018
  106. Optimizing Lithium Ion Conduction through Crown Ether-Based Cylindrical Channels in [Ni(dmit)2] Salts, Chem. Mater., 30巻, 20号, pp. 7130-7137, 2018
  107. A Sandwich Complex of Bismuth Cation and Mono-lacunary α-Keggin-type Phosphotungstate: Preparation and Structural Characterisation, Eur. J. Inorg. Chem., 3-4号, pp. 357-362, 2019
  108. A Self-Assembled Heterometallic {Co7-Ho1} Nanocluster: 3d-4f Trimeric Keggin-Type Silicotungstate [HoCo7Si3W29O108(OH)5(H2O)4]18- and its Catalytic and Magnetic Applications, Eur. J. Inorg. Chem., 3-4号, pp. 430-436, 2019
  109. Structural Phase Transition Behavior Observed for a Single Crystal of the Tetrabutylammonium Salt of a Mo18 Polyoxometalate, Eur. J. Inorg. Chem., 3-4号, pp. 492-495, 2019
  110. Magnetic Switching by Desorption/Adsorption of an Organic Solvent Molecule from/on [Ni(dmit)2]- Salt, Chem. Lett., 48巻, 4号, pp. 329-332, 2019
  111. ★, Selective Ion Exchange in Supramolecular Channels in the Crystalline State, Angew. Chem. Int. Ed., 58巻, 13号, pp. 4169-4172, 2019 [Front Cover Picture]
  112. Pressure-Controlled Migration of Paramagnetic Centers in a Heterospin Crystal, Inorg. Chem., 58巻, 14号, pp. 9187-9194, 2019
  113. Ferroelectric Behavior of a Hexamethylenetetramine-Based Molecular Perovskite Structure, Angew. Chem. Int. Ed., 58巻, 27号, pp. 9184-9187, 2019
  114. Ligand Structure Effects on Molecular Assembly and Magnetic Properties of Copper(II) Complexes with 3-Pyridyl-Substituted Nitronyl Nitroxide Derivatives, ACS Omega, 4巻, 17号, pp. 17160-17170, 2019
  115. One-Dimensional Molecular Nano-branched Structures of Tetrathiafulvalene Derivative with Crown Ether, Jpn. J. Appl, Phys., 59巻, SD号, pp. SDDA10-1-4, 2020
  116. Synthesis of Preyssler-Type Phosphotungstate with Sodium Cation in the Central Cavity through Migration of the Ion, Bull. Chem. Soc. Jpn., 93巻, 3号, pp. 461-466, 2020
  117. Doping of Metal-free Molecular Perovskite with Hexamethylenetetramine to Create Non-centrosymmetric Defects, CrystEngComm, 22巻, pp. 2279-2282, 2020
  118. Intermolecular Spin-Crossover-Like Phenomenon Sensitive to Applied External Pressure in Heterospin Crystals, Cryst. Growth Des., 20巻, 4号, pp. 2796-2802, 2020
  119. Effect of increasing pressure on the structure and temperature-induced changes in magnetic properties of heterospin complexes, Russ. Chem. Bull., 69巻, pp. 1530-1536, 2020
  120. Gas-Dependent Reversible Structural and Magnetic Transformation between Two Ladder Compounds, Crystals, 10巻, 9号, pp. 841(1-9), 2020
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  122. Structural Phase Transitions of a Molecular Metal Oxide, Angew. Chem. Int. Ed., 59巻, pp. 22446-22450, 2020
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著書等出版物

  1. 2013年, ゲルの安定化と機能性付与・次世代への応用開発, 技術情報協会, 2013年, 単行本(学術書), 共著
  2. 2014年, CSJカレントレビュー16“スピン化学が拓く分子磁性の新展開, 化学同人, 2014年, 単行本(学術書), 共著

受賞

  1. 2003年, 日本学術振興会特別研究員(DC)平成15年度採用, 日本学術振興会
  2. 2005年, 日本学術振興会特別研究員(PD)平成17年度採用, 日本学術振興会
  3. 2005年, 日本学術振興会特別研究員(海外)平成17年度採用, 日本学術振興会
  4. 2011年, 文部科学大臣表彰・科学技術賞, 文部科学省
  5. 2012年, 松浦賞, 広島化学同窓会
  6. 2017年, Award for Outstanding Research Achievement, アジア太平洋材料学会 (APSMR)
  7. 2019年, 物質・デバイス共同研究賞, 物質・デバイス領域共同研究拠点
  8. 2019年, JST さきがけ研究員 令和元年度採用, 科学技術振興機構
  9. 2019年, ひろしまベンチャー育成賞(金賞), 公益財団法人ひろしまベンチャー育成基金

取得

  1. 特許権, 6650138, 2020年01月22日, 分子性金属酸化物クラスター、分子性金属酸化物クラスター結晶、分子性金属酸化物クラスター結晶凝集体、分子メモリ、結晶メモリ及び分子性金属酸化物クラスターへの分子分極形成方法
  2. 特許権, 6469515, 2019年01月25日, イオンチャネルを利用したイオン交換法およびイオン交換体
  3. 特許権, 6469516, 2019年01月25日, キャリアドーピング法および導電体
  4. 特許権, 5669098, 2014年12月26日, イオン伝導性結晶およびそれを用いた固体電解質,電池用セパレータ,電池
  5. 特許権, 6189083, 2017年08月10日, α-ドーソン型ポリ酸の製造方法およびその方法により製造されたα-ドーソン型ポリ酸、α-ドーソン型ポリ酸化合物

外部資金

競争的資金等の採択状況

  1. 科学研究費助成事業(特別研究員奨励費), [日本学術振興会],単独, 超分子カチオン構造を利用した分子性スピンラダー構造の構築と物性評価, 2003年, 2004年
  2. 科学研究費助成事業(若手研究(B)),[日本学術振興会],単独, 多次元磁性金属錯体の化学構築と物性評価, 2006年, 2007年
  3. シーズ発掘試験,[科学技術振興機構],単独, 微小結晶用磁場中誘電率測定装置の開発, 2008年
  4. 科学研究費助成事業(基盤研究(C)),[日本学術振興会],単独, プログラム分子を用いたスピン空間制御, 2008年, 2010年
  5. シーズ発掘試験, [科学技術振興機構],単独, 単結晶中でのナノクラスター成長を利用した新規磁気記録材料の開発, 2009年
  6. 科学研究費助成事業(挑戦的萌芽研究),[日本学術振興会],単独, リボルバー型分子を利用した新規機能創出, 2011年, 2012年
  7. A-STEP(探索タイプ), [科学技術振興機構],単独, イオンチャンネル型固体電解質の開発, 2011年
  8. 科学研究費助成事業(基盤研究(B)),[日本学術振興会],代表, イオン移動型ポリオキソメタレートを用いた新規機能創出, 2012年, 2014年
  9. 二国間交流事業(共同研究),[日本学術振興会],代表, 次世代分子性強誘電材料の探査, 2015年, 2017年
  10. 科学研究費助成事業(基盤研究(B)),[日本学術振興会],代表, 単分子誘電体の機能開拓と応用, 2016年, 2018年
  11. 科学研究費助成事業(挑戦的萌芽研究),[日本学術振興会],代表, イオンスイッチ分子トランジスタの創出, 2016年, 2017年
  12. A-STEP(実証タイプ), [科学技術振興機構],単独, 超高密度記録に資する分子誘電メモリデバイスの改良と実証研究, 2018年, 2019年
  13. 科学研究費助成事業(基盤研究(B)),[日本学術振興会],代表, 単分子誘電物性の構造学的解明と新規物質群開拓, 2019年, 2021年
  14. 戦略的創造研究推進事業(さきがけ), [科学技術振興機構],単独, ペタビット時代を支える革新的分子ストレージング技術の確立, 2019年, 2022年
  15. 科学研究費助成事業(挑戦的研究(開拓)),[日本学術振興会],単独, 電場による分子キラリティの制御, 2020年, 2022年
  16. 研究成果展開事業(START), [科学技術振興機構],単独, 籠型分子を用いた超高密度不揮発性メモリおよび超低消費電力AIチップの開発, 2020年, 2022年