SADAFUMI NISHIHARA

Last Updated :2024/12/02

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Professor
Web Site
https://kotai.hiroshima-u.ac.jp/en/
E-mail
snishihiroshima-u.ac.jp
Other Contact Details
1-3-1, Kagamiyama, Higashi-Hiroshima, 739-8526, Japan, Japan
TEL : (+81)82-424-7418 FAX : (+81)82-424-7418
Self-introduction
Development of Molecular Electronics Device Based on Supramolecular Chemistry

Basic Information

Major Professional Backgrounds

  • 2003/04/01, Hokkaido University, Special Postdoctoral Researcher(DC)
  • 2004/04/01, Nagoya University, Special Postdoctoral Researcher(PD)
  • 2005/04/01, Osaka Prefecture University, Assistant Professor
  • 2005/08/01, CNRS, Visiting Researcher
  • 2010/04/01, Hiroshima University, Graduate School of Science, Associate Professor
  • 2012/10/01, University of Glasgow, Visiting Senior Researcher
  • 2019/10/01, JST PRESTO Project, PRESTO Researcher
  • 2020/04/01, Hiroshima University, Graduate School of Advanced Science and Engineering, Professor
  • 2022/10/01, JST, PRESTO, PRESTO Researcher

Academic Degrees

  • Ph.D., HOKKAIDO UNIVERSITY

Research Fields

  • Chemistry;Applied chemistry;Functional solid state chemistry
  • Mathematical and physical sciences;Physics;Condensed matter physics II
  • Chemistry;Materials chemistry;Device related chemistry

Research Keywords

  • Solid State Chemistry
  • Molecular Electronics
  • Molecular Machine
  • Supramolecular Chemistry

Educational Activity

Course in Charge

  1. 2024, Liberal Arts Education Program1, 2Term, Modern Chemistry
  2. 2024, Undergraduate Education, 4Term, Advanced Chemistry
  3. 2024, Undergraduate Education, First Semester, Special Study for Graduation
  4. 2024, Undergraduate Education, Second Semester, Special Study for Graduation
  5. 2024, Undergraduate Education, Second Semester, Exercises in Inorganic Chemistry
  6. 2024, Undergraduate Education, First Semester, Chemical Experiments I
  7. 2024, Undergraduate Education, Second Semester, Chemical Experiments II
  8. 2024, Undergraduate Education, 1Term, Inorganic Chemistry I
  9. 2024, Graduate Education (Master's Program) , 1Term, Introduction to Inorganic Chemistry
  10. 2024, Graduate Education (Master's Program) , 2Term, Solid State Chemistry
  11. 2024, Graduate Education (Master's Program) , First Semester, Exercises in Chemistry A
  12. 2024, Graduate Education (Master's Program) , Second Semester, Exercises in Chemistry B
  13. 2024, Graduate Education (Master's Program) , Academic Year, Master's Thesis in Chemistry
  14. 2024, Graduate Education (Doctoral Program) , Academic Year, Doctoral Thesis in Chemistry
  15. 2024, Graduate Education (Master's Program) , 1Term, Sustainability Materials Science

Research Activities

Academic Papers

  1. Co2+(15-crown-5) magnetic supramolecular cation in [Ni(dmit)2]− π-spin system, J. Phys. Chem. B, 104(25), 5871-5873, 2000
    Link to Paper Search Results by DOI
  2. Structure, optical and magnetic behaviour of meso-tetraphenylporphyrinatoiron (III) tetracyanoethenide, [FeIII(TPP)][TCNE], J. Chem. Soc., Dalton Trans., 448-455, 2001
    Link to Paper Search Results by DOI
  3. [Ni(dmit)2]- salt of a supramolecular cation, Sc3+(12-crown-4)2, Synth. Met., 121(1-3), 1806-1807, 2001
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  4. Formation of a molecular spin ladder induced by a supramolecular cation structure, Chem. Commun., 408-409, 2002
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  5. Two Polymorphs of (anilinium)(18-crown-6)[Ni(dmit)2]; Structure and Magnetic Properties, J. Solid State Chem., 168(2), 661-667, 2002
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  6. Structures of Flexible Supramolecular Cations (1,4-Cyclohexanediammonium2+)(Crown Ethers)2 in [Ni(dmit)2]- Salts, J. Supramol. Chem., 2(1-3), 175-186, 2002
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  7. Magnetic Properties of [Ni(dmit)2]- Anions Induced by Flexible Hydrogen-Bonded Supramolecular Cations [(p-Xylylenediammonium)0.5(Crown Ethers)]+, J. Phys. Chem. B, 107(1), 66-74, 2003
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  8. Magnetic and 1H-NMR spectroscopic studies of [Ph(NH3)](18-crown-6)[Ni(dmit)2] having molecular spin ladder structure, Synth. Met., 137(1-3), 1279-1280, 2003
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  9. Crystal Structure and Magnetic Properties of Gd2([18]crown-6)2(OH)2(CH3CN)[Ni(dmit)2]4 Complex Having f- and pai-spins, Inorg. Chem., 42(8), 2480-2482, 2003
    Link to Paper Search Results by DOI
  10. Molecular Rotor of Cs2([18]crown-6)3 in the Solid State Coupled with the Magnetism of [Ni(dmit)2], J. Am. Chem. Soc., 127(12), 4397-4402, 2005
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  11. Strong antiferromagnetic exchange interactions in quasi-one-dimensional (quasi-1D) compounds based on [Pd(dmit)2]- anions: Crystal structures, magnetic properties, and spin dimer analyses, Synth. Met., 150(1), 57-61, 2005
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  12. Crystal Structures and Magnetic Properties of [Ni(dmit)2]- Salts Including (4-fluoroanilinium)([18]crown-6) and (4-methylanilinium)([18]crown-6) Supramolecular Cations, Polyhedron, 24(16-17), 2844-2848, 2005
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  13. Two-dimensional molecular magnets based on [Pt(mnt)2]- ions: Structures and magnetic properties, Polyhedron, 24(16-17), 2160-2164, 2005
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  14. Cooperativity of dynamics of 18-crown-6 molecule forming one-dimensional chain in Cs2(18-crown-6)3[Ni(dmit)2]2, J. Chem. Phys., 123(4), 044514, 2005
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  15. Structural phase transition driven by spin-lattice interaction in a quasi-one-dimensional spin system of [1-(4-iodobenzyl)pyridinium][Ni(dmit)2], J. Phys. Chem. B, 109(35), 16610-16615, 2005
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  16. Supramolecular cations of (S)-, (R)-, and (SR)-Indan-1-aminium(dibenzo[18]crown-6) in magnetic [Ni(dmit)2]- salts, Eur. J. Inorg. Chem., 3271-3276, 2005
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  17. Novel spin transition observed in two quasi-one-dimensional spin system based on [M(mnt)2]- monoanion compounds (M=Ni or Pt; mnt2- = maleonitriledithiolate), Chem. Phys. Lett., 418(4-6), 423-427, 2006
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  18. Design of a Magnetic Bistability Molecular System Constructed by H-Bonding and π...π-Stacking Interactions, Inorg. Chem., 45(5), 2229-2234, 2006
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  19. Structural Phase Transition of Magnetic [Ni(dmit)2]- Salts Induced by Supramolecular Cation Structures of (M+)([12]crown-4)2, J. Phys. Chem. B, 110(12), 5897-5904, 2006
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  20. Structural and Magnetic Investigations for the Doping Effect of Nonmagnetic Impurity on the Spin-Peierls-like Transition in a Quasi-One-Dimensional Magnet: 1-(4'-Nitrobenzyl)pyridinium Bis(maleonitriledithiolato)nickelate, J. Phys. Chem. B, 110(15), 7671-7677, 2006
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  21. Quasi-one-dimensional molecular magnets based on derivatives of (fluorobenzyl)pyridinium with the [M(mnt)2] monoanion (M = Ni, Pd or Pt; mnt2- = maleonitriledithiolate): Syntheses, crystal structures and magnetic properties, Dalton Trans., 1998-1994, 2006
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  22. Diversities of coordination geometry at Cu2+ center in the bis(maleonitriledithiolato)cuprate complexes: Syntheses, magnetic properties, X-ray crystal structural analyses, and DFT calculations, Cryst. Growth Des., 6(11), 2530-2537, 2006
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  23. EPR Measurements of a Two-dimensional Spin Frustrated System, BIPNNBNO with S = 1 and S = 1/2, J. Phys: Condens. Matter., 51, 91-94, 2006
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  24. Magnetic Properties of a Spin-1 Ladder under Pressure, J. Magn. Mag. Mater., 310(2), 420-422, 2007
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  25. Spin density distribution in a partially magnetized organic quantum magnet, Phys. Rev. B, 75(10), 104427-1-4, 2007
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  26. Pressure effect on spin-Peierls-like transition in quasi-1D spin systems [RBzPy][Ni(mnt)2], Chem. Phys. Lett., 439(4-6), 318-322, 2007
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  27. Self-assembled molecular magnets from discrete dimer to one-dimensional helical chain: Syntheses, crystal structures and magnetic properties, Polyhedron, 26, 4463-4469, 2007
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  28. Multirotations of (anilinium)([18]crown-6) supramolecular cation structure in magnetic salt of [Ni(dmit)2]-, Chem. Asian J., 2, 1083-1090, 2007
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  29. 2D H-bonding molecular magnets based on [Ni(mnt)2]- monoanion: Syntheses, crystal structures and magnetic properties, Polyhedron, 33(1), 1787-1792, 2007
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  30. Microstructures related to the ferroelectric properties in BiFeO3-BaTiO3, Trans. MRS-J., 33(1), 27-30, 2008
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  31. Impurity effect of an S = 1/2 two leg spin ladder antiferromagnet [Ph(NH3)]([18]crown-6)[Ni(dmit)2] studied by ESR, J. Phys.: Conf. Ser., 150, 042034-1-4, 2009
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  32. Two d10 coordination polymers based on 4,4'-(hexafluoroisopropylidene)diphthalic acid: Syntheses, structures and physical properties, Inorg. Chem. Commun., 12(6), 498-201, 2009
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  33. Ferroelectric Properties and Nano-Scaled Domain Structures in (1-x)BiFeO3-xBaTiO3 (0.33<x<0.50), Ferroelectrics, 385, 155-161, 2009
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  34. Cobalt(II) coordination polymers assembled from polycarboxylate and benzotriazole: Syntheses, structures and physical properties, Inorg. Chim. Acta, 362(13), 4780-4784, 2009
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  35. A 3D Gd-Ag coordination polymer constructed from pyridine-3,5-dicarboxylic acid: Synthesis, crystal structure and magnetic properties, Inorg. Chem. Commun., 12(9), 895-897, 2009
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  36. Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene, Inorg. Chim. Acta, 362(14), 5103-5108, 2009
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  37. Construction of hybrid d10 metal-organic frameworks by flexible aromatic dicarboxylate and N-donor ligands : syntheses, structures and physical properties, CrystEngComm., 11(12), 2784-2796, 2009
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  38. Nano-sized domain structures in the psudocubic phase of (1-x)BiFeO3-xBaTiO3 (0.33<x<0.60), Trans. MRS-J., 34(1), 47-50, 2009
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  39. Synthesis, Structure and Magnetic Properties of a Novel Anion-Radical Salt Based on TCNQ, J. Inorg. Organometa. Polym. Mater., 20(1), 177-181, 2010
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  40. Syntheses and Characterizations of Three Cu(II) Complexes with 2,2 '-Bipyridine-3,3'-dicarboxylate and N-Donor Ancillary Ligands, J. Inorg. Organometa. Polym. Mater., 20(1), 110-117, 2010
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  41. Five 3D metal-organic frameworks constructed from V-shaped polycarboxylate acids and flexible imidazole-based ligands, CrystEngComm., 12(4), 1175-1185, 2010
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  42. Appearance of Magnetization Jumps in Magnetic Hysteresis Curves in Spinel Oxide FeV2O4, J. Appl. Phys., 107, 09A504-1-3, 2010
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  43. Synthesis, characterization, and crystal structures of two novel ion-pair complexes based on benzene-1,2-dithiolate ligand, Russ. J. Coord. Chem., 36(3), 226-231, 2010
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  44. Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid (Mellitic Acid), J. Inorg. Organomet. Polymer Matar., 20(3), 564-569, 2010
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  45. A Trinuclear Cu(II) Complex from the Use of Phenyl 2-Pyridyl Ketoxime: Structure and Magnetic Behavior, Synth. React. Inprg. Met. -Org. Chem., 40(6), 421-424, 2010
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  46. Synthesis, Crystal Structure, and Magnetic Property of a New Nickel(III) Complex Constructed from 1,2-Benezedithiolate, Synth. React. Inprg. Met. -Org. Chem., 40(6), 416-420, 2010
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  47. Stationary Behavior in Effective Magnetic Moment and Magnetization of 2,3,6-Trifluorophenyl Nitronyl Nitroxide Radical Crystals, Bull. Chem. Soc. Jpn., 83(12), 1447-1454, 2010
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  48. Three zinc(II) complexes constructed from aromatic dicarboxylate and 1,4-bis((2-(pyridin-2-yl)-1H-imidazol-1-yl)methyl)benzene: Syntheses, crystal structures and luminescent properties, Inorg. Chem. Acta, 363(14), 3932-3938, 2010
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  49. Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Syntheses, crystal structures and luminescence, Inorg. Chem. Acta, 363(14), 3727-3732, 2010
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  50. New Photoluminescent Coordination Polymers Constructed from Dicarboxylate and 1,2-Bis(imidazol-1-ylmethyl)benzene, Russ. J. Coord. Chem., 36(10), 739-745, 2010
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  51. Three new nickel(III) compounds based on 2-thioxo-1,3-dithiole-4,5-dithiolate: Syntheses, structures, magnetic properties and theoretical analyses, Polyhedron, 29(15), 2916-2923, 2010
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  52. A chiral copper(II) inverse-9-metallacrown-3 complex: Synthesis, crystal structure, ferroelectric and magnetic properties, Inorg. Chim. Acta, 368(1), 165-169, 2011
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  53. A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triacetate Acid with Phenanthroline, J. Inorg. Organomet. Polymer Mater., 21(1), 201-206, 2011
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  54. Construction of two metal coordination polymers based on 1,4-terephthalate and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene, Russ. J. Coord. Chem., 37(3), 202-210, 2011
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  55. An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties, Inorg. Chem. Commun., 14(6), 867-872, 2011
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  56. Synthesis, Crystal Structure, Electronic Absorption and Magnetic Properties of a Novel Anion-Radical Salt Based on 7,7,8,8-Tetracyanoquinodimethane, J. Chem. Crystallogr., 41(9), 1462-1267, 2011
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  57. Synthesis, structure and magnetic properties of a pentanuclear Cu(II) coordination polymer with 4-(imidazol-1-yl)-benzoic acid, Inorg. Chem. Commun., 14(9), 1444-1447, 2011
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  58. Chiral Magnetic Soliton Lattice on a Chiral Helimagnet, Phys. Rev. Lett., 108(10), 107202-1-5, 2012
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  59. Molecular Photoconductor with Simultaneously Photocontrollable Localized Spins, J. Am. Chem. Soc., 134(45), 18656-18666, 2012
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  60. Temperature-induced assembly of MOF polymorphs: Syntheses, structures and physical properties, CrysEngComm., 14(5), 1856-1864, 2012
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  61. Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands, J. Inorg. Org. Polym. Mat., 22(1), 258-263, 2012
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  62. Synthesis, Crystal Structure, and Magnetic Properties of a 3d-3d Mixed Heterometallic Coordination Polymer, Russ. J. Coord. Chem., 38(2), 134-139, 2012
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  63. A Coordination Polymer With a (3,4)-Connected (62.8)2(62.84) 3D Network: Synthesis, Crystal Structure and Luminescent Properties, Synth. React. Inorg. Metal-Org. nano-Met. Chem., 42(9), 1222-1226, 2012
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  64. Syntheses, Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Complexes With the Ditopic Ligand 1,3-Bis(imidazol-1-ylmethyl)benzene, J. Chem. Crystallogr., 42(4), 416-422, 2012
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  65. Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers, Inorg. Chim. Acta, 387, 308-313, 2012
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  66. THz ESR study of multiferroic material CuO under pulsed magnetic field, IRMMW-THz, 1-3, 2012
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  67. Quick and selective synthesis of Li6[alpha-P2W18O62].28H2O soluble in various organic solvents, Dalton Trans., 42(32), 11363-11366, 2013
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  68. Anomalous magnetization behaviour in a single crystal of vanadium spinel FeV2O4, J. Phys.: Condens. Matter., 25(41), 416008-1-8, 2013
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  69. The effect of doping a molecular spin ladder with non-magnetic impurities, Dalton Trans., 42(43), 15263-15266, 2013
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  70. Interlayer Magnetoresistance due to Chiral Soliton Lattice Formation in Hexagonal Chiral Magnet CrNb6S6, Phys. Rev. Lett., 111(19), 197204-1-5, 2013
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  71. Crystal structure and magnetic properties of honeycomb-like lattice antiferromagnet p-BIP-V2, Phys. Rev. B, 87(12), 125120-1-8, 2013
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  72. On the Nature of the Structural and Magnetic Phase Transitions in the Layered Perovskite-Like (CH3NH3)2[(FeIICl4)Cl], Inorg. Chem., 53(4), 2068-2075, 2014
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  73. Giant Photoconductivity in NMQ[Ni(dmit)2], Eur. J. Inorg. Chem., 24, 4000-4009, 2014
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  74. A magnetically isolated cuprate spin-ladder system: synthesis, structures, and magnetic properties, Dalton Trans., 43(34), 12974-12981, 2014
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  75. Electrical Network of Single-Crystalline Metal Oxide Nanoclusters Wired by pi-Molecules, Angew. Chem. Int. Ed., 53(42), 11228-11231, 2014
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  76. A Cuprate Spin Ladder Linked by a Pyridyl Ligand, Chem. Lett., 43(11), 1713-1715, 2014
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  77. Synthesis and Physical Properties of Tetrathiafulvalene Derivatives with Ferrocene-terminated Substituents, Chem. Lett., 43(7), 1131-1133, 2014
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  78. Chiral Magnetic Soliton Lattice in MnSi, J. Phys. Soc. Conf. Proc., 2, 010205-1-6, 2014
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  79. Weak Ferromagnetism in Chiral Inorganic Compound CrSi, J. Phys. Soc. Conf. Proc., 3, 014037-1-4, 2014
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  80. Chiral Soliton Lattice in Chiral Magnetic Crystal CrNb3S6, J. Jpn. Soc. Powder Powder Metallurgy, 61(S1), S34-36, 2014
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  81. High Magnetic Hardness for the Canted Antiferromagnetic, Ferroelectric, and Ferroelastic Layered Perovskite-like (C2H5NH3)2[(FeIICl4)Cl], Inorg. Chem., 54(6), 2866-2874, 2015
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  82. A heterospin pressure sensor, J. Mater. Chem. C, 3(30), 7788-7791, 2015
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  83. Multiple structural transformations coupled with switchable magnetic and dielectric responses in an amphidynamic crystal of 4'-tert-butylbenzyl-pyridinium bis(maleonitriledithiolate)nickelate, J. Mater. Chem. C, 3(30), 7906-7915, 2015
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  84. Magnetic soliton confinement and discretization effects arising from macroscopic coherence in a chiral spin soliton lattice, Phys. Rev. B, 92(220412(R)), 1-6, 2015
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  85. Characteristic responses of a phospholipid molecular layer to polyols, Coll. Surf. B, 136, 594-599, 2015
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  86. Synthesis, Crystal Structure, and Magnetic Properties of a Chiral Cyanide-Bridged Bimetallic Framework K3[MnII(L-asp)]6[CrIII(CN)6]center dot 2H2O, Inorg. Chem., 55(1), 300-306, 2016
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  87. Orthorhombic distortion and orbital order in the vanadium spinel FeV2O4, Phys. Rev. B, 93(2), 2016
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  88. Progressive Transformation between Two Magnetic Ground States for One Crystal Structure of a Chiral Molecular Magnet, Inorg. Chem., 55(6), 3047-3057, 2016
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  89. Phase transitions and off-stoichiometric effects of vanadium spinel oxide CoV2O4, Mater. Res. Express, 3(6), 066101-1-10, 2016
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  90. Lanthanoid Template Isolation of the alpha-1,5 Isomer of Dicobalt(II)-Substituted Keggin Type Phosphotungstates: Syntheses, Characterization, and Magnetic Properties, Inorg. Chem., 55(17), 8292-8300, 2016
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  91. NMR study on the quasi one-dimensional quantum spin magnet with ladder structure, Hyper. Inter., 237, 116-1-7, 2016
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  92. Synthesis of ypsilon-Keggin-type Cobaltomolybdate-based 3D Framework Material and Characterization Using Atomic-scale HAADF-STEM and XANES, Inorg. Chem., 56(4), 2042-2049, 2017
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  93. Synthesis, Characterisation, and Structure of a Reduced Preyssler-Type Polyoxometalate, Chem. Lett., 46(4), 602-604, 2017
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  94. Collective resonant dynamics of the chiral spin soliton lattice in a monoaxial chiral magnetic crystal, Phys. Rev. B, 95(10), 104415-1-5, 2017
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  95. A Dielectric Anomaly Observed for Doubly Reduced Mixed-valence Polyoxometalate, Chem. Commun., 53, 6824-6827, 2017
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  96. Two new sandwich-type manganese {Mn5} substituted polyoxotungstates: syntheses, crystal structures, electrochemistry and magnetic properties, Inorg. Chem., 56(15), 8759-8767, 2017
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  97. Coupling of Magnetic and Elastic Domains in the Organic Inorganic Layered Perovskite-like (C6H5C2H4NH3)2FeIICl4, Angew. Chem. Int. Ed., 56(32), 9367-9370, 2017
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  98. (Azulene-1,3-diyl)-bis(nitronyl nitroxide) and (Azulene-1,3-diyl)-bis(iminonitroxide) and Their Copper Complexes, Chem. Asian J., 12(22), 2929-2941, 2017
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  99. Magnetic solitons and magnetic phase diagram of the hexagonal chiral crystal CrNb3S6 in oblique magnetic fields, Phys. Rev. B, 96(18), 2017
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  100. Co-Crystallization of Achiral Components into Chiral Network by Supramolecular Interactions: Coordination Complexes Organic Radical, Cryst. Growth Des., 17(9), 4893-4899, 2017
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  101. Preparation of Preyssler-type Phosphotungstate with One Central Potassium Cation and Potassium Cation Migration into the Preyssler Molecule to form Di-Potassium-Encapsulated Derivative, ACS Omega, 3(2), 2363-2373, 2018
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  102. Synthesis, crystal structures and magnetic properties of six coordination compounds constructed with pyridine iminomethyl-TEMPO radicals and [M(hfac)2] (M = CuII and MnCuII), CrystEngComm., 20(21), 2961-2967, 2018
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  103. Chemo-chromism in an orthogonal dabco-based Co(II) network assembled by methanol-coordination and hydrogen bond formation, Dalton. Trans., 47(23), 7656-7662, 2018
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  104. Structural, Optical, Magnetic, and Dielectric Properties in Hybrid Solid Solutions of Zn alpha Ni1-alpha(en)(3)Ag2I4 (0 < alpha < 1) by Varying the Relative Zn/Ni Content, ACS Omega, 3(9), 10725-10732, 2018
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  105. ★, Giant Hysteretic Single-Molecule Electric Polarisation Switching above Room Temperature, Angew. Chem. Int. Ed., 57(41), 13429-13432, 2018
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  106. Optimizing Lithium Ion Conduction through Crown Ether-Based Cylindrical Channels in [Ni(dmit)2]− Salts, Chem. Mater., 30(20), 7130-7137, 2018
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  107. A Sandwich Complex of Bismuth Cation and Mono-lacunary alpha-Keggin-type Phosphotungstate: Preparation and Structural Characterisation, Eur. J. Inorg. Chem., 357-362, 2019
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  108. A Self-Assembled Heterometallic {Co7-Ho1} Nanocluster: 3d-4f Trimeric Keggin-Type Silicotungstate [HoCo7Si3W29O108(OH)5(H2O)4]18- and its Catalytic and Magnetic Applications, Eur. J. Inorg. Chem., 430-436, 2019
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  109. Structural Phase Transition Behavior Observed for a Single Crystal of the Tetrabutylammonium Salt of a Mo18 Polyoxometalate, Eur. J. Inorg. Chem., 492-495, 2019
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  110. Magnetic Switching by Desorption/Adsorption of an Organic Solvent Molecule from/on [Ni(dmit)2]- Salt, Chem. Lett., 48(4), 329-332, 2019
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  111. ★, Selective Ion Exchange in Supramolecular Channels in the Crystalline State, Angew. Chem. Int. Ed., 58(13), 4169-4172, 2019
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  112. Pressure-Controlled Migration of Paramagnetic Centers in a Heterospin Crystal, Inorg. Chem., 58(14), 9187-9194, 2019
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  113. Ferroelectric Behavior of a Hexamethylenetetramine-Based Molecular Perovskite Structure, Angew. Chem. Int. Ed., 58(27), 9184-9187, 2019
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  114. Ligand Structure Effects on Molecular Assembly and Magnetic Properties of Copper(II) Complexes with 3-Pyridyl-Substituted Nitronyl Nitroxide Derivatives, ACS Omega, 4(17), 17160-17170, 2019
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  115. One-Dimensional Molecular Nano-branched Structures of Tetrathiafulvalene Derivative with Crown Ether, Jpn. J. Appl, Phys., 59(SD), SDDA10-1-4, 2020
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  116. Synthesis of Preyssler-Type Phosphotungstate with Sodium Cation in the Central Cavity through Migration of the Ion, Bull. Chem. Soc. Jpn., 93(3), 461-466, 2020
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  117. Doping of Metal-free Molecular Perovskite with Hexamethylenetetramine to Create Non-centrosymmetric Defects, CrystEngComm, 22, 2279-2282, 2020
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  118. Intermolecular Spin-Crossover-Like Phenomenon Sensitive to Applied External Pressure in Heterospin Crystals, Cryst. Growth Des., 20(4), 2796-2802, 2020
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  119. Spin Crossover between the High-spin and Low-spin States and Dielectric Switching in the Ionic Crystals of a Fe(II) [2 ☓ 2] Molecular Grid, Bull. Chem. Soc. Jpn., 93(12), 1583-1587, 2020
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  120. Structural Phase Transitions of a Molecular Metal Oxide, Angew. Chem. Int. Ed., 59, 22446-22450, 2020
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  121. Effect of increasing pressure on the structure and temperature-induced changes in magnetic properties of heterospin complexes, Russ. Chem. Bull., 69, 1530-1536, 2020
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  122. Gas-Dependent Reversible Structural and Magnetic Transformation between Two Ladder Compounds, Crystals, 10(9), 841(1-9), 2020
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  123. ★, Welcome to the single-molecule electret device, Nature Nanotechnol., 15, 966-967, 2020
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  124. Single-Molecule Magnetic, Catalytic and Photoluminescence Properties of Heterometallic 3d-4f [Ln{PZn2W10O38(H2O)2}2]11- Tungstophosphate Nanoclusters, Eur. J. Inorg. Chem., 37, 3819-3831, 2021
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  125. Fluorescent Properties of a Cage-Shaped Molecule Composed of Tetrakis[4-(4-pyridylphenyl)]ethylene Moieties, Jpn. J. Appl. Phys., 61, SE1004-1-5, 2022
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  126. A tertrameric Praseodymium Substituted Arsenotungstate (III) – Synthesis & Characterization, Electrochemistry, Catalytic and its Magnetic Applications, Polyhedron, 216, 115698-1-7, 2022
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  127. Structural phase transition in cobalt oxyfluoride Co3Sb4O6F6 observed by high-resolution synchrotron and neutron diffraction, J. Phys. Chem. Solids., 163, 110568-1-7, 2022
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  128. Ferroelasticity-like and solvent affect the magnetism of a copper-organic radical one-dimensional coordination polymer, Dalton Trans., 51, 6682-6686, 2022
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Awards

  1. 2017, Award for Outstanding Research Achievement, Asia Pacific Society for Materials Research (APSMR)
  2. 2019, JST PRESTO, JST
  3. 2021, Hiroshima University President's Award, Hiroshima University

Patented

  1. Patent, 6650138, 2020/01/22
  2. Patent, 6469515, 2019/01/25
  3. Patent, 6469516, 2019/01/25
  4. Patent, 5669098, 2014/12/26
  5. Patent, 6189083, 2017/08/10

External Funds

Acceptance Results of Competitive Funds

  1. KAKENHI, 2003, 2004
  2. KAKENHI, 2006, 2007
  3. 2008
  4. KAKENHI, Control of spin structures by using program molecules, 2008, 2010
  5. 2009
  6. KAKENHI, Development of Functional Materials Based on Revolver-shaped Molecules, 2011, 2012
  7. 2011
  8. KAKENHI, 2012, 2014
  9. KAKENHI, Exploring a frontier in molecular ferroelectric material, 2015, 2017
  10. KAKENHI, 2016, 2018
  11. KAKENHI, 2016, 2017
  12. Adaptable and Seamless Technology transfer Program through targetdriven R&D, 2018, 2019
  13. 2019, 2021
  14. JST PRESTO, 2019, 2022
  15. 2020, 2022
  16. 2020, 2022
  17. Moonshot (MILLENNIA Program), Survey on the Construction of "DIGITAL BIOSPHERE" for Human Expansion into Space, 2020, 2021
  18. JST, PRESTO, Development of Single Molecule Electret Based Strage Class Memory, 2022, 2026
  19. 2023, 2026