定金 正洋MASAHIRO SADAKANE

Last Updated :2024/07/05

所属・職名
大学院先進理工系科学研究科 教授
ホームページ
メールアドレス
sadakane09hiroshima-u.ac.jp
その他連絡先
東広島市鏡山一丁目4番1号 工学部A4棟A4-631
TEL:082-424-4456 FAX:082-424-5494

基本情報

主な職歴

  • 2009年01月01日, 2019年03月31日, 広島大学, 大学院工学研究科, 准教授
  • 2001年12月01日, 2008年12月31日, 北海道大学, 触媒化学研究センター, 助教
  • 1993年04月01日, 1994年03月15日, 株式会社クラレ, 総合職社員
  • 1998年07月01日, 2001年03月31日, ジョージタウン大学, 化学科, 博士研究員
  • 2001年04月01日, 2001年11月30日, 理化学研究所, 有機金属化学研究室, 基礎化学特別研究員
  • 2010年10月01日, 2014年03月31日, JST, さきがけ研究員

学歴

  • ボン大学, 化学科, ケクレ有機生物化学研究所, ドイツ, 1996年04月, 1998年05月
  • 岡山大学, 工学研究科, 日本, 1991年04月, 1993年03月
  • 岡山大学, 工学部, 日本, 1987年04月, 1991年03月

学位

  • Dr.rer.nat. (ボン大学)
  • 修士(工学) (岡山大学)

教育担当

  • 【学士課程】 工学部 : 第三類(応用化学・生物工学・化学工学系) : 応用化学プログラム
  • 【博士課程前期】 先進理工系科学研究科 : 先進理工系科学専攻 : 応用化学プログラム
  • 【博士課程前期】 先進理工系科学研究科 : 先進理工系科学専攻 : スマートイノベーションプログラム
  • 【博士課程後期】 先進理工系科学研究科 : 先進理工系科学専攻 : 応用化学プログラム
  • 【博士課程後期】 先進理工系科学研究科 : 先進理工系科学専攻 : スマートイノベーションプログラム

担当主専攻プログラム

  • 応用化学プログラム

研究分野

  • 工学 / プロセス・化学工学 / 触媒・資源化学プロセス

研究キーワード

  • 触媒
  • ポリオキソメタレート
  • 多孔性材料

所属学会

  • 日本化学会
  • 触媒学会
  • 石油学会
  • ゼオライト学会

教育活動

授業担当

  1. 2024年, 学部専門, セメスター(後期), 化学実験II
  2. 2024年, 学部専門, 4ターム, 量子化学I
  3. 2024年, 学部専門, 3ターム, 触媒化学
  4. 2024年, 学部専門, 通年, 卒業論文
  5. 2024年, 修士課程・博士課程前期, 1ターム, 応用化学特別演習A
  6. 2024年, 修士課程・博士課程前期, 2ターム, 応用化学特別演習A
  7. 2024年, 修士課程・博士課程前期, 3ターム, 応用化学特別演習B
  8. 2024年, 修士課程・博士課程前期, 4ターム, 応用化学特別演習B
  9. 2024年, 修士課程・博士課程前期, 1ターム, 応用化学特別演習B
  10. 2024年, 修士課程・博士課程前期, 2ターム, 応用化学特別演習B
  11. 2024年, 修士課程・博士課程前期, 年度, 応用化学特別研究
  12. 2024年, 修士課程・博士課程前期, 1ターム, 多孔材料化学論
  13. 2024年, 修士課程・博士課程前期, 3ターム, Advanced Porous Material
  14. 2024年, 博士課程・博士課程後期, 年度, 応用化学特別研究

研究活動

学術論文(★は代表的な論文)

  1. Reactivity of Organoiridium Tungsten Oxide Clusters with Transition Metal Aquo Cations, INORGANIC CHEMISTRY, 63巻, 12号, pp. 5672-5680, 20240312
  2. Preparation and isolation of mono-Nb substituted Keggin-type phosphomolybdic acid and its application as an oxidation catalyst for isobutylaldehyde and Wacker-type oxidation, DALTON TRANSACTIONS, 52巻, 48号, 20231212
  3. A Cationic Metal Glue Strategy for Expanding Paramagnetic Hetero-Multinuclear Metal-Oxo Clusters within Polyoxometalate Ligands, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 62巻, 41号, 20231009
  4. Hexalacunary [α-H2P2W12O48]12- Wells-Dawson Anion: X-ray Crystal Structural Evidence and Oligomerization to WO(OH2)4+-Bridged Dimer and Trimers, CHEMISTRY-A EUROPEAN JOURNAL, 29巻, 45号, 20230810
  5. Additive manufacturing using highly concentrated nanocolloids of metal hydroxide salts towards structured metals and metal oxides, JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 131巻, 10号, pp. 830-836, 202310
  6. Synthesis and Structure Characterization of Multi-Molybdenum-Substituted Preyssler-type Phosphotungstates, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022巻, 36号, pp. 83-100, 20221113
  7. Chapter 3. Polyoxometalate Unit Assembling for Crystal Catallysts, CRYSTALLINE METAL OXIDE CALTALYSTS, pp. 83-100, 20221027
  8. Stable and Efficient Cu-Based Zeolitic Octahedral Metal Oxides for Ethylene and Ethane Separation at High Temperature and Humidity, ADVANCED MATERIALS TECHNOLOGIES, 20230829
  9. Higher acidity promoted photodegradation of fluoroquinolone antibiotics under visible light by strong interaction with a niobium oxide based zeolitic octahedral metal oxide, APPLIED CATALYSIS A-GENERAL, 662巻, 20230725
  10. Molar-Ratio-Dependent Coordination Assembly of Organoiridium(III)-Octatungstate Complexes in Aqueous Solution, INORGANIC CHEMISTRY, 62巻, 17号, pp. 6759-6767, 20230501
  11. Solid-state Thermal Transformation of Methylammonium Monomolybdate to Polyoxomolybdates and their Applications as Staining Reagents for Transmission Electron Microscopy Observations of Viruses, CHEMISTRY LETTERS, 52巻, 3号, pp. 167-171, 202303
  12. Synthesis and Structural Characterization of Multi- Molybdenum-Substituted Preyssler-type Phosphotungstates, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022巻, 36号, 2022
  13. Deoxydehydration of glycerol to allyl alcohol catalysed by ceria-supported rhenium oxide, MOLECULAR CATALYSIS, 535巻, 20230115
  14. Anion-Directed Conformation Switching and Trigonal Distortion in Hexakis(methylamine)nickel(II) Cations, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022巻, 30号, 20221026
  15. Redox-induced control of microporosity of zeolitic transition metal oxides based on epsilon-Keggin iron molybdate at an ultra-fine level, INORGANIC CHEMISTRY FRONTIERS, 9巻, 20号, pp. 5305-5316, 20221012
  16. Thermal Structure Transformation of Methylammonium Vanadate and it's Application as a Negative Staining Reagent for Observing SARS-CoV-2, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022巻, 26号, 20220919
  17. Assembly of epsilon-Keggin Polyoxometalate from Molecular Crystal to Zeolitic Octahedral Metal Oxide, CHEMISTRY-A EUROPEAN JOURNAL, 28巻, 41号, 20220720
  18. Synthesis, characterization, and multielectron redox property of pyridine-coordinated tetra-Ru-oxo core sandwich-type silicotungstate, [(gamma-SiW10O36)(2)({Ru(IV)(pyridine)}(4)O-4(OH)(2)](10-), ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 648巻, 13号, 20220714
  19. Preyssler-type phosphotungstate is a new family of negative-staining reagents for the TEM observation of viruses, SCIENTIFIC REPORTS, 12巻, 1号, 20220512
  20. Oxidation Catalysis over Solid-State Keggin-Type PhosphomolybdicAcid with Oxygen Defects br, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144巻, 17号, pp. 7693-7708, 20220504
  21. Dual Templating for AFX/LEV Intergrowth Zeolite, CHEMISTRY LETTERS, 51巻, 2号, pp. 121-123, 202202
  22. Conversion of ethanol to propylene over HZSM-5(Ga) co-modified with lanthanum and phosphorous, APPLIED CATALYSIS A-GENERAL, 417巻, pp. 137-144, 20120229
  23. Effective and selective bisphenol A synthesis on a layered silicate with spatially arranged sulfonic acid., Effective and selective bisphenol A synthesis on a layered silicate with spatially arranged sulfonic acid., 4巻, 4号, pp. 2186-2191, 2012
  24. Sunlight-induced effective heterogeneous photocatalytic decomposition of aqueous organic pollutants to CO2 assisted by a CO2 sorbent, amine-containing mesoporous silica., Sunlight-induced effective heterogeneous photocatalytic decomposition of aqueous organic pollutants to CO2 assisted by a CO2 sorbent, amine-containing mesoporous silica., 48巻, 44号, pp. 5521-5523, 2012
  25. Stabilization of high-valence ruthenium with silicotungstate ligands: preparation, structural characterization, and redox studies of ruthenium(III)-substituted α-Keggin-type silicotungstates with pyridine ligands, [SiW11O39Ru(III)(Py)]5-., Stabilization of high-valence ruthenium with silicotungstate ligands: preparation, structural characterization, and redox studies of ruthenium(III)-substituted α-Keggin-type silicotungstates with pyridine ligands, [SiW11O39Ru(III)(Py)]5-., 7巻, 6号, pp. 1331-1339, 2012
  26. Molecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent., Molecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent., 48巻, 56号, pp. 7073-7075, 2012
  27. Synthesis and characteristics of novel layered silicates HUS-2 and HUS-3 derived from a SiO2-choline hydroxide-NaOH-H2O system, JOURNAL OF MATERIALS CHEMISTRY, 22巻, 27号, pp. 13682-13690, 2012
  28. Transformation of LEV-type zeolite into less dense CHA-type zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 158巻, pp. 117-122, 20120801
  29. Acid stability evaluation of CHA-type zeolites synthesized by interzeolite conversion of FAU-type zeolite and their membrane application for dehydration of acetic acid aqueous solution, MICROPOROUS AND MESOPOROUS MATERIALS, 158巻, pp. 141-147, 20120801
  30. Hydrothermal and solid-state transformation of ruthenium-supported Keggin-type heteropolytungstates [XW11O39{Ru(II)(benzene)(H2O)}]n- (X = P (n = 5), Si (n = 6), Ge (n = 6)) to ruthenium-substituted Keggin-type heteropolytungstates., Hydrothermal and solid-state transformation of ruthenium-supported Keggin-type heteropolytungstates [XW11O39{Ru(II)(benzene)(H2O)}]n- (X = P (n = 5), Si (n = 6), Ge (n = 6)) to ruthenium-substituted Keggin-type heteropolytungstates., 41巻, 33号, pp. 9901-9907, 2012
  31. Morphology-controlled preparation of iron-based oxides using a paper template, MATERIALS LETTERS, 81巻, pp. 80-83, 20120815
  32. Building Block Synthesis of Crystalline Mo-V-based Oxides: Selective Oxidation Catalysts, JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 55巻, 4号, pp. 229-235, 201207
  33. Efficient and Selective Photocatalytic Cyclohexane Oxidation on a Layered Titanate Modified with Iron Oxide under Sunlight and CO2 Atmosphere, ACS CATALYSIS, 2巻, 9号, pp. 1910-1915, 201209
  34. Molecular Recognitive Adsorption of Aqueous Propionic Acid on Hiroshima University Silicate-2 (HUS-2), CHEMISTRY LETTERS, 42巻, 3号, pp. 244-246, 20130305
  35. Assembly of a Pentagonal Polyoxomolybdate Building Block, [Mo6O21](6-), into Crystalline MoV Oxides, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 10-11号, pp. 1731-1736, 201304
  36. Ternary modified TiO2 as a simple and efficient photocatalyst for green organic synthesis, CHEMICAL COMMUNICATIONS, 49巻, 35号, pp. 3652-3654, 2013
  37. Role of Structural Similarity Between Starting Zeolite and Product Zeolite in the Interzeolite Conversion Process, JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 13巻, 4号, pp. 3020-3026, 201304
  38. Conversion of Ethanol into Propylene over TON Type Zeolite, JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 56巻, 1号, pp. 22-31, 201301
  39. Effect of Structure-Directing Agents on FAU-CHA Interzeolite Conversion and Preparation of High Pervaporation Performance CHA Zeolite Membranes for the Dehydration of Acetic Acid Solution, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 86巻, 11号, pp. 1333-1340, 20131115
  40. Ordered Porous Crystalline Transition Metal Oxide, Inorganic Materials Series, 4巻, pp. 147-216, 20110101
  41. Synthesis and applications of mixed metal oxide nanotubes, Topics Appl. Phys, 117巻, pp. 147-158, 20100101
  42. Structural Organization of Catalytic Functions in Mo-Based Selective Oxidation Catalysts, Turning Points in Solid-State, Materials and Surface Science, pp. 507-518, 20080101
  43. Electrochemical Properties of Polyoxometalates as Electrocatalysts, Chem. Rev, 98巻, pp. 219-237, 19980101
  44. Preparation and structural characterization of tetrabutylammonium salt of mono-ruthenium(III)-substituted alpha-Keggin-type silicotungstates with 4,4'-bipyridine ligande and its electrochemical behaviour in organic solvents, Dalton Trans, 42巻, pp. 7190-7195, 20130101
  45. Organoruthenium-containing heteropoly-23-Tungstate Family [Ru2L2(alpha-XW11O39)2WO2]m- (L = p-cumen; X = GeIV, SiIV, m = 10; BIII, m = 12), Eur. J. Inorg. Chem, pp. 1742-1747, 20130101
  46. Determination of alpha-Keggin structure of [GeW11O39Ru(III)(H2O)]5-. Reaction of mono-substituted Keggin-type germanotungstate [GeW11O39Ru(III)(H2O)]5- with dimethyl sulfoxide to from [GeW11O39Ru(III)(dmso)]5- and their structural characterization, Dalton Trans, 42巻, pp. 2540-2545, 20130101
  47. Orthorhombic Mo3VOx catalyst most active for dehydrogenation of ethane among related complex metal oxides, Catal. Sci. & Tech, 3巻, pp. 380-387, 20130101
  48. An important property of polymer sphere templates for preparation of three-dimensionally ordered macroporous (3DOM) metal oxides by ethylene glycol method: glass transition temperature, Langmuir, 28巻, pp. 17766-17770, 20120101
  49. Highly efficient and selective sunlight-induced photocatalytic oxidation of cyclohexane to cyclohexanone on an eco-catalyst under a CO2 atmosphere, Green Chem, 14巻, pp. 1264-1267, 20120101
  50. Sunlight-induced efficent and selective photocatalytic benzene oxidation on TiO2-supported gold nanoparticles under CO2 atmosphere, Chem. Commun, 47巻, pp. 11531-11533, 20110101
  51. Thermal stability and acid strength of Preyssler-type phosphotungstic acid, H14[P5W30O110Na], and it's catalytic activity for hydroxylation of alkyl acetate, Z. Anorg. Allgem. Chem, 637巻, pp. 2120-2124, 20110101
  52. Redox Tunable Reversible Molecular Sieves: Orthorhombic Molybdenum Vanadium Oxide, Chem. Commun, 47巻, pp. 10812-10814, 20110101
  53. Preparation and structural characterization of Ru(II)-DMSO and Ru(III)-DMSO-substituted alpha-Keggin-type phosphotungstates, [PW11O39Ru(II)DMSO]5- and [PW11O39Ru(III)DMSO]4-, and catalytic activity for water oxidation, Z. Anorg. Allgem. Chem, 637巻, pp. 1467-1474, 20110101
  54. Preparation and Formation Mechanism of Three-Dimensionally Ordered Macroporous (3DOM) MgO, MgSO4, CaCO3, and SrCO3, and Photonic Stop Band Properties of 3DOM CaCO3, J. Solid State Chem, 184巻, pp. 2299-2305, 20110101
  55. Hydrothermal conversion of FAU zeolite into LEV zeolite in the presence of non-calcined seed crystals, J. Crystal Growth, 325巻, pp. 96-100, 20110101
  56. Preparation of Crystalline Tungsten Oxide Nanorods with Enhanced Photocatalytic Activity under Visible Light Irradiation, Chem. Lett, 40巻, pp. 443-445, 20110101
  57. Influence of seeding on FAU-*BEA interzeolite conversions, Microporous Mesoporous Mater, 142巻, pp. 161-167, 20110101
  58. Alpha and beta isomer of tetrahafnium (IV) containing decatungstosilicate [Hf4(OH)6(CH3COO)2(x-SiW10O37)2]12- (x = alpha, beta), Dalton Trans, 40巻, pp. 2920-2925, 20110101
  59. Influence of starting zeolite on synthesis of RUT type zeolite by interzeolite conversion method, J. Cryst. Growth, 314巻, pp. 274-278, 20110101
  60. FAU-LEV interzeolite conversion in fluoride media, Microporous Mesoporous Mater, 138巻, pp. 32-39, 20110101
  61. Influence of structural differences and acidic properties of phosphotungstic acids on their catalytic performance for acylayion of pyruvate ester alpha-acyloxyacrylate ester, Catal. Today, 164巻, pp. 107-111, 20110101
  62. Incorporation of highly dispersed aluminum into inner surfaces of supermicroporous silica using anionic surfactant, J. Pourous Mater, 18巻, pp. 493-500, 20110101
  63. Conversion of ethanol to propylene over HZSM-5 type zeolite containing alkaline earth metals, Appl. Catal. A:Gen, 383巻, pp. 89-95, 20100101
  64. Immobilization of nanofibrous A- and B-site substituted LaMnO3 perovskite-type oxides on macroscopic fiber with carbon nanofibers templates, Mater. Res. Bull, 45巻, pp. 1330-1333, 20100101
  65. Nano-Scale Hydroxyapatite Formation on Silica Fiber by Using Carbon Nanofibers as Templates, J. Nanosci. Nanotechnol, 10巻, pp. 5431-5436, 20100101
  66. Preparation of Three-dimensionally Ordered Macroporous LaFeO3 with Tunable Pore Diameters: High Porosity and Photonic Property, J. Solid State Chem, 183巻, pp. 1365-1371, 20100101
  67. Atomic-Level Imaging of Mo-V-O Complex Oxide Phase intergrowth, Grain Boundaries, and Defects using HAADF-STEM, Proc. Natl. Acad. Sci. USA, 107巻, pp. 6152-6157, 20100101
  68. Synthesis of 3-D Ordered Macroporous MxH3-xPW12O40 (M = Cs+ and NH4+): Trimodal Micro-, Meso-, and Macropores in CsxH3-xPW12O40 Material, Chem. Lett, 39巻, pp. 426-427, 20100101
  69. Atomic-Scale Investigation of Two-Component MoVO Complex Oxide Catalysts Using Aberration-Corrected High Annular Dark-Field Imaging, Chem. Mater, 22巻, pp. 2033-2040, 20100101
  70. Synthesis of high-silica OFF type zeolite by the interzeolite conversion method, Mater. Res. Bull, 45巻, pp. 646-650, 20100101
  71. Preparation of 3-D Ordered Macroporous Tungsten Oxides and Nano Particulate Tungsten Oxides using a Colloidal Crystal Template Method, and their Structural Characterization and Application as Photocatalysts under Visible Light Irradiation, J. Mater. Chem, 20巻, pp. 1811-1818, 20100101
  72. Synthesis of single phase Ca-alpha-SiAlON using Y-type Zeolite, J. Euro. Ceramic Soc, 30巻, pp. 1537-1541, 20100101
  73. Synthesis and Characterization of Three-Dimensionally Ordered Macroporous (3DOM) Tungsten Carbide: Application to Direct Methanol Fuel Cells, Chem. Mater, 22巻, pp. 966-973, 20100101
  74. Mesoporous silicas containing carboxylic acid: Preparation, thermal degradation, and catalytic performance, Appl. Catal. A: Gen, 372巻, pp. 82-89, 20100101
  75. Preparation of Well-Alloyed PtRu/C Catalyst by Sequential Mixing of the Precursors in a Polyol Method, J. Electrochem. Soc, 156巻, pp. B1348-B1353, 20090101
  76. An efficient synthesis of alpha-acyloxyacrylate esters as candidate monomers for bio-based polymers by heteropolyacid catalyzed acylation of pyruvate esters, Green Chem, 11巻, pp. 1666-1674, 20090101
  77. Facile preparation of SBA-15-supported niobic acid (Nb2O5-H2O) catalyst and its catalytic activity, Appl. Catal. A: Gen, 365巻, pp. 261-267, 20090101
  78. Effect of SnO2 Deposition Sequence in SnO2-Modified PtRu/C Catalyst Preparation on Catalytic Acitivity for Methanol Electro-Oxidation, J. Electrochem. Soc, 156巻, pp. B862-B869, 20090101
  79. Synthesis, Characterization and Formation Process of Transition Metal Oxide Nanotubes Using Carbon Nanofibers as Templates, J. Solid State Chem, 182巻, pp. 1587-1592, 20090101
  80. Synthesis of orthorhombic Mo-V-Sb-O by assembly of pentagonal Mo6O21 polyoxometalate building blocks, Angew. Chem. Int. Ed, 48巻, pp. 3782-3786, 20090101
  81. Preparation of Nano-Structured Crystalline WO3 and Improved Photochemical Activity for Decomposition of Organic Compounds under Visible Light Irradiation, Chem. Commun, pp. 6552-6554, 20080101
  82. Carbonyl-Ruthenium Substituted alpha-Keggin-Tunstosilicate, [alpha-SiW11O39RuII(CO)]6-: Synthesis, Structure, Redox Studies and Reactivity, Dalton Trans, pp. 6692-6698, 20080101
  83. An Efficient Heteropolyacid Catalyzed Acylation of Pyruvate Esters to alpha-Acyloxyacrylate Esters as Potential Candidate Monomers for Bio-based Polymers, Chem. Commun, pp. 5239-5241, 20080101
  84. Molybdenum-Vanadium based Molecular Sieves with a Microchannel of Corner-Sharing 7-Membered Metal-Oxide-Octahedron Ring, Angew. Chem. Int. Ed, 47巻, pp. 2493, 20080101
  85. Nano-scale Hydroxyapatite Coating on Macroscopic Silica Fiber using Carbon Nanofibers as Templates, Bull. Chem. Soc. Jpn, 81巻, pp. 380, 20080101
  86. Nano-structuring of complex metal oxides for catalytic oxidation, Catal. Today, 132巻, pp. 2, 20080101
  87. Facile Preparation of Three-Dimensionally Ordered Macroporous (3DOM) Alumina, Iron Oxide, Chromium Oxide, Manganese Oxide, and their Mixed Metal Oxides with High Porosity, Chem. Mater, 19巻, pp. 5779-5785, 20070101
  88. Immobilization of Nanofibrous Metal Oxides on Microfibers: Macrostructured Catalyst System Functionalized with Nanoscale Fibrous Metal Oxides, Chem. Commun, pp. 4047-4049, 20070101
  89. Crystalline Mo3VOx. Its Unique Structural Property and High Catalytic Performance in Alkane Selective Oxidation, Stud. Surf. Sci. Catal, 172巻, pp. 91-96, 20070101
  90. Dimerization of mono-ruthenium substituted alpha-Keggin-type tungstosilicate [alpha-SiW11O39Ru(III)(H2O)]5- to mu-oxo-bridged dimer in aqueous solution: synthesis, structure, and redox studies, Dalton Trans, pp. 2833-2838, 20070101
  91. Preparation of Mixed Oxide Nanotubes by Precursor-Accumulation on Carbon Nanofiber Templates, Chem. Lett, 36巻, pp. 258-259, 20070101
  92. Three-Dimensionally Ordered Macroporous (3DOM) Materials of Spinel-type Mixed Iron Oxides; Synthesis, Structural Characterization, and Formation Mechanism of Inverse Opals with Skeleton Structure, Bull. Chem. Soc. Jpn, 80巻, pp. 677-685, 20070101
  93. Novel Crystalline Mo3VOx Mixed Metal Oxide Catalyst with Trigonal Symmetry, Angew. Chem. Int. Ed, 46巻, pp. 1493, 20070101
  94. Vapour phase hydrogenation of phenol over Pd/C catalysts: a relationship between dispersion, metal area and hydrogenation activity, Catal. Comm, 8巻, pp. 471, 20070101
  95. Shape-Controlled Synthesis of ZrO2, Al2O3 and SiO2 Nanotubes Using Carbon Nanofibers as Templates, Chem. Mater, 18巻, pp. 4981-4983, 20060101
  96. Structural characterization of mono-ruthenium substituted Keggin-type silicotungstates, Dalton Trans, pp. 4271-4276, 20060101
  97. Three-dimensionally Ordered Macroporous Mixed Iron Oxide; Preparation and Structural Characterization of Inverse Opals with Skeleton Structure, Chem. Lett, 35巻, pp. 480-481, 20060101
  98. Facile Procedure to prepare Three-dimensionally ordered Macroporous (3DOM) Perovskite-type Mixed Metal Oxides by Colloidal Crystal Templating Method, Chem. Mater, 17巻, pp. 3546-3551, 20050101
  99. A novel Isopolytungstate functionalized by Ruthenium: [HW9O33Ru(II)(dmso)6]7-, Chem. Comm, 12巻, pp. 1420-1421, 20040101
  100. Cluster and Polynuclear Compounds. Polyoxomolybdate Clusters: Giant Wheels and Balls, Inorg. Synth, 34巻, pp. 191-200, 20040101
  101. Synthesis and Electrochemical Behavior of [SiW11O39Ru(III)(H2O)]5- and its oxo-bridged dimeric complex [SiW11O39Ru(IV)ORu(III)SiW11O39]11-, Dalton Trans, pp. 659-664, 20030101
  102. Formation of 1:1 and 2:2 Complexes of Ce(III) with the Heteropolytungstate Anion a2-[P2W17O61]10-, and their Interaction with Proline. The Structure of [Ce2(P2W17O61)2(H2O)8]14-, J. Chem. Soc., Dalton Trans, pp. 63-67, 20020101
  103. Prospects for rational assembly of composite polyoxometalates, Polyoxometalate chemistry for nano-composite design, pp. 17-26, 20020101
  104. Synthesis and Characterization of Copper-, Zinc-, Manganese-, and Cobalt-Substituted Dimeric Heteropolyanions, [(a-XW9O33)2M3(H2O)3]n- (n = 12, X = AsIII, SbIII, M = Cu2+, Zn2+; n = 10, X = SeIV, TeIV, M = Cu2+) and [(a-AsW9O33)2WO(H2O)M2(H2O)2]10- (M = Z, Inorg. Chem, 40巻, pp. 4742-4749, 20010101
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  222. Synthesis and characterization of carbonate-encapsulated ytterbium- and yttrium-containing polyoxotungstates, ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 74巻, pp. 1355-+, 201811
  223. Facile synthesis of highly crystalline EMT zeolite by hydrothermal conversion of FAU zeolite in the presence of 1,1'-(1,4-butanediyl)bis(1-azonia-4-azabicyclo [2,2,2]octane) dihydroxide, MICROPOROUS AND MESOPOROUS MATERIALS, 274巻, pp. 299-303, 20190115
  224. A Sandwich Complex of Bismuth Cation and Mono-Lacunary alpha-Keggin-Type Phosphotungstate: Preparation and Structural Characterisation, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 3-4号, pp. 357-362, 20190131
  225. A Self-Assembled Heterometallic {Co-7-Ho-1} Nanocluster: 3d-4f Trimeric Keggin-Type Silicotungstate [HoCo7Si3W29O108(OH)(5) (H2O)(4)](18-) and its Catalytic and Magnetic Applications, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 3-4号, pp. 430-436, 20190131
  226. Zeolite hydrothermal conversion in the presence of various cyclic alkylammonium cations and synthesis of nanosized BEA and MFI zeolites, MICROPOROUS AND MESOPOROUS MATERIALS, 277巻, pp. 115-123, 20190315
  227. Syntheses, and Crystal Structures of Y-III Containing Di-Metal Substituted 1,5 Isomers of Heterometallic Tungstophosphate Nanoclusters: [Y{PM2W10O38(H2O)(2)}(2)](11-)(M = Co-II and Zn-II), CHEMISTRYSELECT, 4巻, 9号, pp. 2538-2544, 20190307
  228. Phosphorus modified small-pore zeolites and their catalytic performances in ethanol conversion and NH3-SCR reactions, APPLIED CATALYSIS A-GENERAL, 575巻, pp. 204-213, 20190405
  229. Redox-Active Zeolitic Transition Metal Oxides Based on epsilon-Keggin Units for Selective Oxidation, INORGANIC CHEMISTRY, 58巻, 9号, pp. 6283-6293, 20190506
  230. Hydrothermal Conversion of Titanated FAU to AEI Zeolite and Its Enhanced Catalytic Performance for NOx Reduction, ADVANCED POROUS MATERIALS, 4巻, 1号, pp. 62-72, 201606
  231. Photocatalytic Activation of C-H Bonds by Spatially Controlled Chlorine and Titanium on the Silicate Layer, ACS CATALYSIS, 9巻, 6号, pp. 5742-5751, 201906
  232. Thermal Behavior, Crystal Structure, and Solid-State Transformation of Orthorhombic Mo-V Oxide under Nitrogen Flow or in Air, ACS OMEGA, 4巻, 8号, pp. 13165-13171, 201908
  233. Intramolecular Electron Transfer and Oxygen Transfer of Phosphomolybdate Molecular Wires, INORGANIC CHEMISTRY, 58巻, 18号, pp. 12272-12279, 20190916
  234. Synthesis of GME zeolite with high porosity by hydrothermal conversion of FAU zeolite using a dual-template method with tetraethylphosphonium and N,N-dimethyl-3,5-dimethylpiepridinium hydroxides, JOURNAL OF POROUS MATERIALS, 26巻, 5号, pp. 1345-1352, 201910
  235. Immobilizaion of Preyssler type heteropoly acids on siliceous mesporous supports and their catalytic activities in the dehydration of ethanol, REACTION KINETICS MECHANISMS AND CATALYSIS, 128巻, 1号, pp. 139-147, 201910
  236. Self-Assembled Tetrameric Lanthanide-Containing Germanotungstates [(Ln(2)GeW(10)O(38))(4)(W3O8)(OH)(4)(H2O)(2)](26-): Syntheses, Crystal Structure, Photoluminescence and Electrochemical Properties., CHEMISTRYSELECT, 4巻, 43号, pp. 12668-12675, 20191122
  237. Multi-dimensional Crystal Structuring of Complex Metal Oxide Catalysts of Group V and VI Elements by Unit-Assembling, TOPICS IN CATALYSIS, 62巻, 17-20号, pp. 1157-1168, 201911
  238. Formation Pathway of AEI Zeolites as a Basis for a Streamlined Synthesis, CHEMISTRY OF MATERIALS, 32巻, 1号, pp. 60-74, 20200114
  239. Synthesis of Preyssler-Type Phosphotungstate with Sodium Cation in the Central Cavity through Migration of the Ion, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 93巻, 3号, pp. 461-466, 202003
  240. New Path for Polyoxometalates: Controlled Synthesis and Characterization of Metal-Substituted Tungstosulfates, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020巻, 8号, pp. 682-689, 20200228
  241. Metal-substituted tungstosulfates with Keggin structure: synthesis and characterization, DALTON TRANSACTIONS, 49巻, 9号, pp. 2766-2770, 20200307
  242. High-quality synthesis of a nanosized CHA zeolite by a combination of a starting FAU zeolite and aluminum sources, DALTON TRANSACTIONS, 49巻, 29号, pp. 9972-9982, 20200807
  243. Solid-State Ion Migration in the Preyssler-Type Phosphotungstate for the Preparation of the Dipotassium Cation-Encapsulated Derivative, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 646巻, 15号, pp. 1297-1302, 20200814
  244. Effective Factor on Catalysis of Niobium Oxide for Magnesium, ACS OMEGA, 5巻, 34号, pp. 21906-21912, 20200901
  245. Triple-template system for phosphorus-modified AFX/CHA intergrowth zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 309巻, 20201215
  246. Synthesis of Phosphorus-Modified AFX Zeolite by the Hydrothermal Conversion of Tetraalkylphosphonium Hydroxide-Impregnated FAU Zeolite, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 94巻, 1号, pp. 1-7, 202101
  247. Vanadium-Enhanced Intramolecular Redox Property of a Transition-Metal Oxide Molecular Wire, INORGANIC CHEMISTRY, 59巻, 22号, pp. 16557-16566, 20201116
  248. Ultrahigh Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-Type Polyoxometalate-Based Framework Functionalized with a Lanthanide Ion, ACS APPLIED MATERIALS & INTERFACES, 13巻, 16号, pp. 19138-19147, 20210428
  249. Multiple templating strategy for the control of aluminum and phosphorus distributions in AFX zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 321巻, 202107
  250. Structural Characterization of Cerium-encapsulated Preyssler-type Phosphotungstate: Additional Evidence of Ce(III) in the Cavity, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 647巻, 11号, pp. 1239-1244, 20210611
  251. Poly(triethylene glycol methyl ether methacrylate) hydrogel as a carrier of phosphotungstic acid for acid catalytic reaction in water, MATERIALS ADVANCES, 2巻, 11号, pp. 3556-3559, 20210607
  252. Isolation and characterization of hirame aquareovirus (HAqRV): A new Aquareovirus isolated from diseased hirame Paralichthys olivaceus, VIROLOGY, 559巻, pp. 120-130, 202107
  253. Zeolitic Octahedral Metal Oxides with Ultra-Small Micropores for C-2 Hydrocarbon Separation, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 60巻, 33号, pp. 18328-18334, 20210809
  254. Catalytic Activities of Various Niobium Oxides for Hydrogen Absorption/Desorption Reactions of Magnesium, ACS OMEGA, 6巻, 36号, pp. 23564-23569, 20210914
  255. Structure and Thermal Transformations of Methylammonium Tungstate, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 647巻, 19号, pp. 1930-1937, 20211012
  256. Single-Molecule Magnetic, Catalytic and Photoluminescence Properties of Heterometallic 3d-4f [Ln{PZn2W10O38(H2O)(2)}(2)](11-) Tungstophosphate Nanoclusters, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2021巻, 37号, pp. 3819-3831, 20211007

著書等出版物

  1. 2015年, 2015年, 単行本(一般書), 共著, English

招待講演、口頭・ポスター発表等

  1. 分子性金属酸化物(ポリオキソメタレート)ユニットを用いた超セラミックスの合成, 定金正洋, 日本セラミックス協会年会サテライトプログラム、第4回超セラミックス研究講演会, 2024年03月13日, 招待, 日本語
  2. Solid State Heat-promoted Synthesis and Acid-promoted Synthesis of Polyoxomolybdate from Methylammonium Monomolybate, Masahiro Sadakane, Ndaru C. Sukmana, Sugiarto, Frontiers in Metal Oxide Cluster Science (FMOCS)-VII, 2023年04月14日, 通常, 英語, FMOCS organizing committee, Taragona, Spain
  3. New Mo-V-O Crystalline Molecular Sieves -Structure, Formation Mechanism, Pore Properties and Catalytic Acitivities, 定金 正洋, 2014年07月, 通常, 日本語
  4. 定金正洋, 2013年03月04日, 招待, 英語, 大阪
  5. ポリオキソメタレート(金属酸化物錯体)を用いた 触媒、吸着、染色材料設計 ポリオキソメタレート(金属酸化物錯体)を用いた 触媒、吸着、染色材料設計 , 定金 正洋, 2014年04月, 招待
  6. ポリオキソメタレート(金属酸化物錯体)を用いた 触媒、吸着、染色材料設計 ポリオキソメタレート(金属酸化物錯体)を用いた 触媒、吸着、染色材料設計 , 定金 正洋, 2014年04月, 招待
  7. 3次元規則的マクロ多孔性遷移金属複合酸化物の合成, 定金正洋, 第9回触媒道場, 2015年09月02日, 招待, 日本語, 触媒学会西日本支部, 箕面、大阪府
  8. 規則的ミクロ細孔をもつモリブデン系酸化物のユニット合成, 定金正洋, 日本化学会中国四国支部 高知地区化学講演会, 2015年12月14日, 招待, 日本語, 日本化学会西日本支部, 高知大学朝倉キャンパス
  9. 定金正洋, 2018年08月05日, 招待, 英語, 日本大学, 東京
  10. 定金正洋, ICCC2018, 2018年08月01日, 招待, 英語, ICCC2018, 仙台
  11. 分子性の酸化物クラスターを積層させた機能性酸化物の構築, 定金正洋, 日本結晶学会年会 シンポジウム「有機化合物-錯体-無機物質の結晶が織りなす多彩な構造と機能」, 2017年11月24日, 招待, 日本語, 日本結晶学会
  12. ルテニウム含有ヘテロポリタングステートの合成と酸化触媒としての応用, 定金正洋, 平成29年度触媒学会西日本支部およびナノ構造触媒研究会合同セミナー, 2017年11月10日, 招待, 日本語, 平成29年度触媒学会西日本支部およびナノ構造触媒研究会, 関西大学
  13. 2017年08月25日, 招待, 英語
  14. 定金正洋, 2017年08月22日, 招待, 英語
  15. 規則的ミクロ細孔をもった結晶性モリブデン酸化物の合成と応用, 定金正洋, 第10回中国四国地区錯体化学研究会・若手の会中国四国支部 第2回勉強会, 2017年05月27日, 招待, 日本語, 中国四国地区錯体化学研究会・若手の会中国四国支部
  16. 2019年08月19日, 招待, 英語

受賞

  1. 2007年, 日本化学会北海道支部奨励賞
  2. 2007年04月15日, BCSJ Award, 日本化学会
  3. 2015年01月29日, ナノテクノロジープラットフォーム,秀でた6大利用成果, 文部科学省「ナノテクノロジープラットフォーム事業」

外部資金

競争的資金等の採択状況

  1. ビスメタル個体触媒によるホルメート経由型化学品製造の国際共同研究開発, ビスメタル固体触媒によるホルメート経由型化学品製造の国際共同研究開発, 2020年/1月2/日, 2023年/0月9/日
  2. 科学研究費助成事業(基盤研究(B)), 機能性材料を指向したPreyssler型タングステート自在合成法開発, 2021年, 2023年
  3. 研究成果展開事業 研究成果最適展開支援プログラム トライアウトタイプ, 高性能な電子顕微鏡用ウイルス染色剤を指向した新規金属酸化物クラスター製造法の開発, 2021年05月01日, 2022年03月31日
  4. 戦略的創造研究推進事業(さきがけ), 分子性酸化物を用いた高効率な水の完全酸化触媒の創生, 2010年10月01日, 2014年03月31日
  5. 科学研究費助成事業(基盤研究(C)), 無機酸化物キラル触媒を目指したポリオキソメタレートのエナンチオマー分離技術の開発, 2014年, 2016年
  6. 科学研究費助成事業(基盤研究(B)), 機能性材料ゼオライトの自在設計・合成法の確立, 2012年, 2014年
  7. 科学研究費助成事業(基盤研究(C)), 分子構造設計による新規ヘテロポリ酸触媒の開発, 2009年, 2011年
  8. 科学研究費助成事業(萌芽研究), ナノ構造物を表面に固定した新規機能性膜の開発, 2008年, 2009年
  9. 科学研究費助成事業(基盤研究(A)), 酸素八面体金属酸化物モレキュラーシーブの創成と新触媒機能, 2008年, 2010年
  10. 科学研究費助成事業(基盤研究(B)), 構造有機体アシストによるペロブスカイト複合酸化物のナノ構造化と新酸化触媒展開, 2006年, 2007年
  11. 科学研究費助成事業(基盤研究(B)), ユニット合成法によるクラスター格子構造複合酸化物触媒の構築と接触酸化反応, 2004年, 2005年
  12. 科学研究費助成事業(若手研究(B)), ケギン型ポリオキソモリブデートの物性・構造制御法の開発, 2004年, 2006年
  13. 科学研究費助成事業(基盤研究(C)), ジルコニア系超微粒子担持金属触媒上でのカーボンナノチューブ生成機構の解明, 2002年, 2004年
  14. 科学研究費助成事業(基盤研究(C)), 金属酸化物クラスター格子の形成とその酸化触媒機能, 2001年, 2002年
  15. 日立金属・材料科学財団助成金, 無機酸化物分子を用いた高効率な水の酸化触媒の創生
  16. 日本板硝子材料工学助成会研究助成, 新しい酸化モリブデン系規則的多孔体の創生と応用
  17. 平成21年度科学技術研究助成金, 排ガス中のスス燃焼除去触媒開発を目指した高結晶性金属酸化物ナノ粒子合成
  18. 科学研究費助成事業(基盤研究(A)), ユニットネットワーク固体の構築工学展開による新機能触媒物質群形成, 2011年, 2013年
  19. 科学研究費助成事業(基盤研究(A)), 新規MoPOM連結型細孔性無機結晶の創出と酸化還元ダイナミズム, 2015年
  20. 科学研究費助成事業(基盤研究(B)), 機能性材料としての応用を指向した新規Preyssler型タングステートの合成, 2018年, 2020年
  21. 科学研究費助成事業(新学術領域研究), 分子性金属酸化物を用いた高効率な水の酸化触媒の開発, 2018年, 2019年

社会活動

学術会議等の主催

  1. 第114回触媒学会, 実行委員, 2014年04月, 2014年09月
  2. 2011年09月, 2012年08月
  3. キックオフミーティング:JSPS研究拠点形成事業「先進エネルギー材料を指向した国際ポリオキソメタレート科学研究拠点」と NANOXCAT French-Japan 国際共同研究, 主催者, 2019年07月, 2019年06月