MASAHIRO SADAKANE

Last Updated :2025/02/04

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Professor
Web Site
http://home.hiroshima-u.ac.jp/catalche/index-e.html
E-mail
sadakane09hiroshima-u.ac.jp
Other Contact Details
1-4-1，Kagamiyama，Higashi-Hiroshima, Japan
TEL : (+81)82-424-4456 FAX : (+81)82-424-5494

Basic Information

Major Professional Backgrounds

  • 2009/01/01, 2019/03/31, Hiroshima University, Graduate School of Engineering, Associate Professor
  • 2001/12/01, 2008/12/31, Hokkaido University, Catalysis Research Center, Assistant Professor
  • 1993/04/01, 1994/03/15, Kuraray Co., Employee
  • 1998/07/01, 2001/03/31, Gerogetown University, NSF Postdoc Researcher
  • 2001/04/01, 2001/11/30, RIKEN, Organometalic Chemistry Laboratory, Postdoc Researcher
  • 2010/10/01, 2014/03/31, JST, PRESTO Researcher

Educational Backgrounds

  • Bonn University, Chemistry, Kekure Institute for Organic and Biochemistry, Germany, 1996/04, 1998/05
  • Okayama University, Graduate School, Division of Engineering, Japan, 1991/04, 1993/03
  • Okayama University, Faculty of Engineering, Japan, 1987/04, 1991/03

Academic Degrees

  • Dr.rer.nat., University of Bonn
  • Master of Engineering, Okayama University

Educational Activity

  • [Bachelor Degree Program] School of Engineering : Cluster 3(Applied Chemistry, Biotechnology and Chemical Engineering) : Program of Applied Chemistry
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Applied Chemistry Program
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Smart Innovation Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Applied Chemistry Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Smart Innovation Program

In Charge of Primary Major Programs

  • Applied Chemistry

Research Fields

  • Engineering;Process / Chemical engineering;Catalyst / Resource chemical process

Research Keywords

  • Catalyst
  • Polyoxometalate
  • Porous material

Affiliated Academic Societies

  • The Chemical Society of Japan
  • Catalysis Society of Japan
  • The Japan Petroleum Institute
  • Japan Association of Zeolite

Educational Activity

Course in Charge

  1. 2024, Undergraduate Education, Second Semester, Chemical Experiments II
  2. 2024, Undergraduate Education, 4Term, Quantum Chemistry I
  3. 2024, Undergraduate Education, 3Term, Catalysis Chemistry
  4. 2024, Undergraduate Education, Year, Graduation Thesis
  5. 2024, Graduate Education (Master's Program) , 1Term, Special Exercises on Applied Chemistry A
  6. 2024, Graduate Education (Master's Program) , 2Term, Special Exercises on Applied Chemistry A
  7. 2024, Graduate Education (Master's Program) , 3Term, Special Exercises on Applied Chemistry B
  8. 2024, Graduate Education (Master's Program) , 4Term, Special Exercises on Applied Chemistry B
  9. 2024, Graduate Education (Master's Program) , 1Term, Special Exercises on Applied Chemistry B
  10. 2024, Graduate Education (Master's Program) , 2Term, Special Exercises on Applied Chemistry B
  11. 2024, Graduate Education (Master's Program) , Academic Year, Special Study on Applied Chemistry
  12. 2024, Graduate Education (Master's Program) , 1Term, Advanced Porous Material
  13. 2024, Graduate Education (Master's Program) , 3Term, Advanced Porous Material
  14. 2024, Graduate Education (Doctoral Program) , Academic Year, Special Study on Applied Chemistry

Research Activities

Academic Papers

  1. Reactivity of Organoiridium Tungsten Oxide Clusters with Transition Metal Aquo Cations, INORGANIC CHEMISTRY, 63(12), 5672-5680, 20240312
    Link to Paper Search Results by DOI
  2. Preparation and isolation of mono-Nb substituted Keggin-type phosphomolybdic acid and its application as an oxidation catalyst for isobutylaldehyde and Wacker-type oxidation, DALTON TRANSACTIONS, 52(48), 20231212
    Link to Paper Search Results by DOI
  3. A Cationic Metal Glue Strategy for Expanding Paramagnetic Hetero-Multinuclear Metal-Oxo Clusters within Polyoxometalate Ligands, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 62(41), 20231009
    Link to Paper Search Results by DOI
  4. Hexalacunary [α-H2P2W12O48]12- Wells-Dawson Anion: X-ray Crystal Structural Evidence and Oligomerization to WO(OH2)4+-Bridged Dimer and Trimers, CHEMISTRY-A EUROPEAN JOURNAL, 29(45), 20230810
    Link to Paper Search Results by DOI
  5. Additive manufacturing using highly concentrated nanocolloids of metal hydroxide salts towards structured metals and metal oxides, JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 131(10), 830-836, 202310
    Link to Paper Search Results by DOI
  6. Synthesis and Structure Characterization of Multi-Molybdenum-Substituted Preyssler-type Phosphotungstates, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022(36), 83-100, 20221113
    Link to Paper Search Results by DOI
  7. Chapter 3. Polyoxometalate Unit Assembling for Crystal Catallysts, CRYSTALLINE METAL OXIDE CALTALYSTS, 83-100, 20221027
    Link to Paper Search Results by DOI
  8. Stable and Efficient Cu-Based Zeolitic Octahedral Metal Oxides for Ethylene and Ethane Separation at High Temperature and Humidity, ADVANCED MATERIALS TECHNOLOGIES, 20230829
    Link to Paper Search Results by DOI
  9. Higher acidity promoted photodegradation of fluoroquinolone antibiotics under visible light by strong interaction with a niobium oxide based zeolitic octahedral metal oxide, APPLIED CATALYSIS A-GENERAL, 662, 20230725
    Link to Paper Search Results by DOI
  10. Molar-Ratio-Dependent Coordination Assembly of Organoiridium(III)-Octatungstate Complexes in Aqueous Solution, INORGANIC CHEMISTRY, 62(17), 6759-6767, 20230501
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  11. Solid-state Thermal Transformation of Methylammonium Monomolybdate to Polyoxomolybdates and their Applications as Staining Reagents for Transmission Electron Microscopy Observations of Viruses, CHEMISTRY LETTERS, 52(3), 167-171, 202303
    Link to Paper Search Results by DOI
  12. Synthesis and Structural Characterization of Multi- Molybdenum-Substituted Preyssler-type Phosphotungstates, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022(36), 2022
    Link to Paper Search Results by DOI
  13. Deoxydehydration of glycerol to allyl alcohol catalysed by ceria-supported rhenium oxide, MOLECULAR CATALYSIS, 535, 20230115
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  14. Anion-Directed Conformation Switching and Trigonal Distortion in Hexakis(methylamine)nickel(II) Cations, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022(30), 20221026
    Link to Paper Search Results by DOI
  15. Redox-induced control of microporosity of zeolitic transition metal oxides based on epsilon-Keggin iron molybdate at an ultra-fine level, INORGANIC CHEMISTRY FRONTIERS, 9(20), 5305-5316, 20221012
    Link to Paper Search Results by DOI
  16. Thermal Structure Transformation of Methylammonium Vanadate and it's Application as a Negative Staining Reagent for Observing SARS-CoV-2, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022(26), 20220919
    Link to Paper Search Results by DOI
  17. Assembly of epsilon-Keggin Polyoxometalate from Molecular Crystal to Zeolitic Octahedral Metal Oxide, CHEMISTRY-A EUROPEAN JOURNAL, 28(41), 20220720
    Link to Paper Search Results by DOI
  18. Synthesis, characterization, and multielectron redox property of pyridine-coordinated tetra-Ru-oxo core sandwich-type silicotungstate, [(gamma-SiW10O36)(2)({Ru(IV)(pyridine)}(4)O-4(OH)(2)](10-), ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 648(13), 20220714
    Link to Paper Search Results by DOI
  19. Preyssler-type phosphotungstate is a new family of negative-staining reagents for the TEM observation of viruses, SCIENTIFIC REPORTS, 12(1), 20220512
    Link to Paper Search Results by DOI
  20. Oxidation Catalysis over Solid-State Keggin-Type PhosphomolybdicAcid with Oxygen Defects br, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144(17), 7693-7708, 20220504
    Link to Paper Search Results by DOI
  21. Dual Templating for AFX/LEV Intergrowth Zeolite, CHEMISTRY LETTERS, 51(2), 121-123, 202202
    Link to Paper Search Results by DOI
  22. Conversion of ethanol to propylene over HZSM-5(Ga) co-modified with lanthanum and phosphorous, APPLIED CATALYSIS A-GENERAL, 417, 137-144, 20120229
    Link to Paper Search Results by DOI
  23. Effective and selective bisphenol A synthesis on a layered silicate with spatially arranged sulfonic acid., Effective and selective bisphenol A synthesis on a layered silicate with spatially arranged sulfonic acid., 4(4), 2186-2191, 2012
    Link to Paper Search Results by DOI
  24. Sunlight-induced effective heterogeneous photocatalytic decomposition of aqueous organic pollutants to CO2 assisted by a CO2 sorbent, amine-containing mesoporous silica., Sunlight-induced effective heterogeneous photocatalytic decomposition of aqueous organic pollutants to CO2 assisted by a CO2 sorbent, amine-containing mesoporous silica., 48(44), 5521-5523, 2012
    Link to Paper Search Results by DOI
  25. Stabilization of high-valence ruthenium with silicotungstate ligands: preparation, structural characterization, and redox studies of ruthenium(III)-substituted α-Keggin-type silicotungstates with pyridine ligands, [SiW11O39Ru(III)(Py)]5-., Stabilization of high-valence ruthenium with silicotungstate ligands: preparation, structural characterization, and redox studies of ruthenium(III)-substituted α-Keggin-type silicotungstates with pyridine ligands, [SiW11O39Ru(III)(Py)]5-., 7(6), 1331-1339, 2012
    Link to Paper Search Results by DOI
  26. Molecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent., Molecular recognitive adsorption of aqueous tetramethylammonium on the organic derivative of Hiroshima University Silicate-1 with a silane coupling reagent., 48(56), 7073-7075, 2012
    Link to Paper Search Results by DOI
  27. Synthesis and characteristics of novel layered silicates HUS-2 and HUS-3 derived from a SiO2-choline hydroxide-NaOH-H2O system, JOURNAL OF MATERIALS CHEMISTRY, 22(27), 13682-13690, 2012
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  28. Transformation of LEV-type zeolite into less dense CHA-type zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 158, 117-122, 20120801
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  29. Acid stability evaluation of CHA-type zeolites synthesized by interzeolite conversion of FAU-type zeolite and their membrane application for dehydration of acetic acid aqueous solution, MICROPOROUS AND MESOPOROUS MATERIALS, 158, 141-147, 20120801
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  30. Hydrothermal and solid-state transformation of ruthenium-supported Keggin-type heteropolytungstates [XW11O39{Ru(II)(benzene)(H2O)}]n- (X = P (n = 5), Si (n = 6), Ge (n = 6)) to ruthenium-substituted Keggin-type heteropolytungstates., Hydrothermal and solid-state transformation of ruthenium-supported Keggin-type heteropolytungstates [XW11O39{Ru(II)(benzene)(H2O)}]n- (X = P (n = 5), Si (n = 6), Ge (n = 6)) to ruthenium-substituted Keggin-type heteropolytungstates., 41(33), 9901-9907, 2012
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  31. Morphology-controlled preparation of iron-based oxides using a paper template, MATERIALS LETTERS, 81, 80-83, 20120815
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  32. Building Block Synthesis of Crystalline Mo-V-based Oxides: Selective Oxidation Catalysts, JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 55(4), 229-235, 201207
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  33. Efficient and Selective Photocatalytic Cyclohexane Oxidation on a Layered Titanate Modified with Iron Oxide under Sunlight and CO2 Atmosphere, ACS CATALYSIS, 2(9), 1910-1915, 201209
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  34. Molecular Recognitive Adsorption of Aqueous Propionic Acid on Hiroshima University Silicate-2 (HUS-2), CHEMISTRY LETTERS, 42(3), 244-246, 20130305
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  35. Assembly of a Pentagonal Polyoxomolybdate Building Block, [Mo6O21](6-), into Crystalline MoV Oxides, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 1731-1736, 201304
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  36. Ternary modified TiO2 as a simple and efficient photocatalyst for green organic synthesis, CHEMICAL COMMUNICATIONS, 49(35), 3652-3654, 2013
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  37. Role of Structural Similarity Between Starting Zeolite and Product Zeolite in the Interzeolite Conversion Process, JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 13(4), 3020-3026, 201304
    Link to Paper Search Results by DOI
  38. Conversion of Ethanol into Propylene over TON Type Zeolite, JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 56(1), 22-31, 201301
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  39. Effect of Structure-Directing Agents on FAU-CHA Interzeolite Conversion and Preparation of High Pervaporation Performance CHA Zeolite Membranes for the Dehydration of Acetic Acid Solution, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 86(11), 1333-1340, 20131115
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  40. Ordered Porous Crystalline Transition Metal Oxide, Inorganic Materials Series, 4, 147-216, 20110101
  41. Synthesis and applications of mixed metal oxide nanotubes, Topics Appl. Phys, 117, 147-158, 20100101
  42. Structural Organization of Catalytic Functions in Mo-Based Selective Oxidation Catalysts, Turning Points in Solid-State, Materials and Surface Science, 507-518, 20080101
  43. Electrochemical Properties of Polyoxometalates as Electrocatalysts, Chem. Rev, 98, 219-237, 19980101
  44. Preparation and structural characterization of tetrabutylammonium salt of mono-ruthenium(III)-substituted alpha-Keggin-type silicotungstates with 4,4'-bipyridine ligande and its electrochemical behaviour in organic solvents, Dalton Trans, 42, 7190-7195, 20130101
  45. Organoruthenium-containing heteropoly-23-Tungstate Family [Ru2L2(alpha-XW11O39)2WO2]m- (L = p-cumen; X = GeIV, SiIV, m = 10; BIII, m = 12), Eur. J. Inorg. Chem, 1742-1747, 20130101
  46. Determination of alpha-Keggin structure of [GeW11O39Ru(III)(H2O)]5-. Reaction of mono-substituted Keggin-type germanotungstate [GeW11O39Ru(III)(H2O)]5- with dimethyl sulfoxide to from [GeW11O39Ru(III)(dmso)]5- and their structural characterization, Dalton Trans, 42, 2540-2545, 20130101
  47. Orthorhombic Mo3VOx catalyst most active for dehydrogenation of ethane among related complex metal oxides, Catal. Sci. & Tech, 3, 380-387, 20130101
  48. An important property of polymer sphere templates for preparation of three-dimensionally ordered macroporous (3DOM) metal oxides by ethylene glycol method: glass transition temperature, Langmuir, 28, 17766-17770, 20120101
  49. Highly efficient and selective sunlight-induced photocatalytic oxidation of cyclohexane to cyclohexanone on an eco-catalyst under a CO2 atmosphere, Green Chem, 14, 1264-1267, 20120101
  50. Sunlight-induced efficent and selective photocatalytic benzene oxidation on TiO2-supported gold nanoparticles under CO2 atmosphere, Chem. Commun, 47, 11531-11533, 20110101
  51. Thermal stability and acid strength of Preyssler-type phosphotungstic acid, H14[P5W30O110Na], and it's catalytic activity for hydroxylation of alkyl acetate, Z. Anorg. Allgem. Chem, 637, 2120-2124, 20110101
  52. Redox Tunable Reversible Molecular Sieves: Orthorhombic Molybdenum Vanadium Oxide, Chem. Commun, 47, 10812-10814, 20110101
  53. Preparation and structural characterization of Ru(II)-DMSO and Ru(III)-DMSO-substituted alpha-Keggin-type phosphotungstates, [PW11O39Ru(II)DMSO]5- and [PW11O39Ru(III)DMSO]4-, and catalytic activity for water oxidation, Z. Anorg. Allgem. Chem, 637, 1467-1474, 20110101
  54. Preparation and Formation Mechanism of Three-Dimensionally Ordered Macroporous (3DOM) MgO, MgSO4, CaCO3, and SrCO3, and Photonic Stop Band Properties of 3DOM CaCO3, J. Solid State Chem, 184, 2299-2305, 20110101
  55. Hydrothermal conversion of FAU zeolite into LEV zeolite in the presence of non-calcined seed crystals, J. Crystal Growth, 325, 96-100, 20110101
  56. Preparation of Crystalline Tungsten Oxide Nanorods with Enhanced Photocatalytic Activity under Visible Light Irradiation, Chem. Lett, 40, 443-445, 20110101
  57. Influence of seeding on FAU-*BEA interzeolite conversions, Microporous Mesoporous Mater, 142, 161-167, 20110101
  58. Alpha and beta isomer of tetrahafnium (IV) containing decatungstosilicate [Hf4(OH)6(CH3COO)2(x-SiW10O37)2]12- (x = alpha, beta), Dalton Trans, 40, 2920-2925, 20110101
  59. Influence of starting zeolite on synthesis of RUT type zeolite by interzeolite conversion method, J. Cryst. Growth, 314, 274-278, 20110101
  60. FAU-LEV interzeolite conversion in fluoride media, Microporous Mesoporous Mater, 138, 32-39, 20110101
  61. Influence of structural differences and acidic properties of phosphotungstic acids on their catalytic performance for acylayion of pyruvate ester alpha-acyloxyacrylate ester, Catal. Today, 164, 107-111, 20110101
  62. Incorporation of highly dispersed aluminum into inner surfaces of supermicroporous silica using anionic surfactant, J. Pourous Mater, 18, 493-500, 20110101
  63. Conversion of ethanol to propylene over HZSM-5 type zeolite containing alkaline earth metals, Appl. Catal. A:Gen, 383, 89-95, 20100101
  64. Immobilization of nanofibrous A- and B-site substituted LaMnO3 perovskite-type oxides on macroscopic fiber with carbon nanofibers templates, Mater. Res. Bull, 45, 1330-1333, 20100101
  65. Nano-Scale Hydroxyapatite Formation on Silica Fiber by Using Carbon Nanofibers as Templates, J. Nanosci. Nanotechnol, 10, 5431-5436, 20100101
  66. Preparation of Three-dimensionally Ordered Macroporous LaFeO3 with Tunable Pore Diameters: High Porosity and Photonic Property, J. Solid State Chem, 183, 1365-1371, 20100101
  67. Atomic-Level Imaging of Mo-V-O Complex Oxide Phase intergrowth, Grain Boundaries, and Defects using HAADF-STEM, Proc. Natl. Acad. Sci. USA, 107, 6152-6157, 20100101
  68. Synthesis of 3-D Ordered Macroporous MxH3-xPW12O40 (M = Cs+ and NH4+): Trimodal Micro-, Meso-, and Macropores in CsxH3-xPW12O40 Material, Chem. Lett, 39, 426-427, 20100101
  69. Atomic-Scale Investigation of Two-Component MoVO Complex Oxide Catalysts Using Aberration-Corrected High Annular Dark-Field Imaging, Chem. Mater, 22, 2033-2040, 20100101
  70. Synthesis of high-silica OFF type zeolite by the interzeolite conversion method, Mater. Res. Bull, 45, 646-650, 20100101
  71. Preparation of 3-D Ordered Macroporous Tungsten Oxides and Nano Particulate Tungsten Oxides using a Colloidal Crystal Template Method, and their Structural Characterization and Application as Photocatalysts under Visible Light Irradiation, J. Mater. Chem, 20, 1811-1818, 20100101
  72. Synthesis of single phase Ca-alpha-SiAlON using Y-type Zeolite, J. Euro. Ceramic Soc, 30, 1537-1541, 20100101
  73. Synthesis and Characterization of Three-Dimensionally Ordered Macroporous (3DOM) Tungsten Carbide: Application to Direct Methanol Fuel Cells, Chem. Mater, 22, 966-973, 20100101
  74. Mesoporous silicas containing carboxylic acid: Preparation, thermal degradation, and catalytic performance, Appl. Catal. A: Gen, 372, 82-89, 20100101
  75. Preparation of Well-Alloyed PtRu/C Catalyst by Sequential Mixing of the Precursors in a Polyol Method, J. Electrochem. Soc, 156, B1348-B1353, 20090101
  76. An efficient synthesis of alpha-acyloxyacrylate esters as candidate monomers for bio-based polymers by heteropolyacid catalyzed acylation of pyruvate esters, Green Chem, 11, 1666-1674, 20090101
  77. Facile preparation of SBA-15-supported niobic acid (Nb2O5-H2O) catalyst and its catalytic activity, Appl. Catal. A: Gen, 365, 261-267, 20090101
  78. Effect of SnO2 Deposition Sequence in SnO2-Modified PtRu/C Catalyst Preparation on Catalytic Acitivity for Methanol Electro-Oxidation, J. Electrochem. Soc, 156, B862-B869, 20090101
  79. Synthesis, Characterization and Formation Process of Transition Metal Oxide Nanotubes Using Carbon Nanofibers as Templates, J. Solid State Chem, 182, 1587-1592, 20090101
  80. Synthesis of orthorhombic Mo-V-Sb-O by assembly of pentagonal Mo6O21 polyoxometalate building blocks, Angew. Chem. Int. Ed, 48, 3782-3786, 20090101
  81. Preparation of Nano-Structured Crystalline WO3 and Improved Photochemical Activity for Decomposition of Organic Compounds under Visible Light Irradiation, Chem. Commun, 6552-6554, 20080101
  82. Carbonyl-Ruthenium Substituted alpha-Keggin-Tunstosilicate, [alpha-SiW11O39RuII(CO)]6-: Synthesis, Structure, Redox Studies and Reactivity, Dalton Trans, 6692-6698, 20080101
  83. An Efficient Heteropolyacid Catalyzed Acylation of Pyruvate Esters to alpha-Acyloxyacrylate Esters as Potential Candidate Monomers for Bio-based Polymers, Chem. Commun, 5239-5241, 20080101
  84. Molybdenum-Vanadium based Molecular Sieves with a Microchannel of Corner-Sharing 7-Membered Metal-Oxide-Octahedron Ring, Angew. Chem. Int. Ed, 47, 2493, 20080101
  85. Nano-scale Hydroxyapatite Coating on Macroscopic Silica Fiber using Carbon Nanofibers as Templates, Bull. Chem. Soc. Jpn, 81, 380, 20080101
  86. Nano-structuring of complex metal oxides for catalytic oxidation, Catal. Today, 132, 2, 20080101
  87. Facile Preparation of Three-Dimensionally Ordered Macroporous (3DOM) Alumina, Iron Oxide, Chromium Oxide, Manganese Oxide, and their Mixed Metal Oxides with High Porosity, Chem. Mater, 19, 5779-5785, 20070101
  88. Immobilization of Nanofibrous Metal Oxides on Microfibers: Macrostructured Catalyst System Functionalized with Nanoscale Fibrous Metal Oxides, Chem. Commun, 4047-4049, 20070101
  89. Crystalline Mo3VOx. Its Unique Structural Property and High Catalytic Performance in Alkane Selective Oxidation, Stud. Surf. Sci. Catal, 172, 91-96, 20070101
  90. Dimerization of mono-ruthenium substituted alpha-Keggin-type tungstosilicate [alpha-SiW11O39Ru(III)(H2O)]5- to mu-oxo-bridged dimer in aqueous solution: synthesis, structure, and redox studies, Dalton Trans, 2833-2838, 20070101
  91. Preparation of Mixed Oxide Nanotubes by Precursor-Accumulation on Carbon Nanofiber Templates, Chem. Lett, 36, 258-259, 20070101
  92. Three-Dimensionally Ordered Macroporous (3DOM) Materials of Spinel-type Mixed Iron Oxides; Synthesis, Structural Characterization, and Formation Mechanism of Inverse Opals with Skeleton Structure, Bull. Chem. Soc. Jpn, 80, 677-685, 20070101
  93. Novel Crystalline Mo3VOx Mixed Metal Oxide Catalyst with Trigonal Symmetry, Angew. Chem. Int. Ed, 46, 1493, 20070101
  94. Vapour phase hydrogenation of phenol over Pd/C catalysts: a relationship between dispersion, metal area and hydrogenation activity, Catal. Comm, 8, 471, 20070101
  95. Shape-Controlled Synthesis of ZrO2, Al2O3 and SiO2 Nanotubes Using Carbon Nanofibers as Templates, Chem. Mater, 18, 4981-4983, 20060101
  96. Structural characterization of mono-ruthenium substituted Keggin-type silicotungstates, Dalton Trans, 4271-4276, 20060101
  97. Three-dimensionally Ordered Macroporous Mixed Iron Oxide; Preparation and Structural Characterization of Inverse Opals with Skeleton Structure, Chem. Lett, 35, 480-481, 20060101
  98. Facile Procedure to prepare Three-dimensionally ordered Macroporous (3DOM) Perovskite-type Mixed Metal Oxides by Colloidal Crystal Templating Method, Chem. Mater, 17, 3546-3551, 20050101
  99. A novel Isopolytungstate functionalized by Ruthenium: [HW9O33Ru(II)(dmso)6]7-, Chem. Comm, 12, 1420-1421, 20040101
  100. Cluster and Polynuclear Compounds. Polyoxomolybdate Clusters: Giant Wheels and Balls, Inorg. Synth, 34, 191-200, 20040101
  101. Synthesis and Electrochemical Behavior of [SiW11O39Ru(III)(H2O)]5- and its oxo-bridged dimeric complex [SiW11O39Ru(IV)ORu(III)SiW11O39]11-, Dalton Trans, 659-664, 20030101
  102. Formation of 1:1 and 2:2 Complexes of Ce(III) with the Heteropolytungstate Anion a2-[P2W17O61]10-, and their Interaction with Proline. The Structure of [Ce2(P2W17O61)2(H2O)8]14-, J. Chem. Soc., Dalton Trans, 63-67, 20020101
  103. Prospects for rational assembly of composite polyoxometalates, Polyoxometalate chemistry for nano-composite design, 17-26, 20020101
  104. Synthesis and Characterization of Copper-, Zinc-, Manganese-, and Cobalt-Substituted Dimeric Heteropolyanions, [(a-XW9O33)2M3(H2O)3]n- (n = 12, X = AsIII, SbIII, M = Cu2+, Zn2+; n = 10, X = SeIV, TeIV, M = Cu2+) and [(a-AsW9O33)2WO(H2O)M2(H2O)2]10- (M = Z, Inorg. Chem, 40, 4742-4749, 20010101
  105. Chiral Polyoxotungstates. 1. Stereoselective interaction of amino acids with enantiomers of [CeIII(a1-P2W17O61)(H2O)x]7-. The structure of DL-[Ce2(H2O)8(P2W17O61)]14-, Inorg. Chem, 40, 2715-2719, 20010101
  106. Formation of unsymmetrical polyoxotungstates via transfer of polyoxometalate building blocks. NMR evidence supports the kinetic stability of the pentatungstate anion, [W5O18]6-, in aqueous solution, J. Am. Chem. Soc, 123, 2087-2088, 20010101
  107. Controlled Assembly of Polyoxometalate Chains from Lacunary Building Blocks and Lanthanide Cation Linkers, Angew. Chem. Int. Ed, 36, 2914-2916, 20000101
  108. Electrochemical Oxidation of (R)-4-Hydroxy-2-pyrrolidon: a Key Building Block for Stereoselective N-Acyliminium Ion Coupling Reactions, Tetrahedron, 55, 14407-14420, 19990101
  109. Co-solvent Effects on the Redox Potentials of Manganese-Substituted a-Keggin Type Silicon Polyoxotungstate K6SiW11O39Mn(H2O): First Electrochemical Generation of the Manganese(V) Redox System in Aqueous Environment, Acta Chem. Scand, 53, 837-841, 19990101
  110. Application of Transition Metal Substituted alpha-Keggin Silicon Polyoxotungstates as Oxidation Electrocatalyst, Novel Trends in Electroorganic Synthesis, Ed, 139-142, 19980101
  111. Electrogenerated N, O-Acetals in Cyclization and Cycloaddition Reactions, Novel Trends in Electroorganic Synthesis, Ed, 55-60, 19980101
  112. A [3+2] Annulation Procedure for the Synthesis of Bicyclic Methylenepyrrolidines, Synlett, 95-96, 19970101
  113. Development of Transition Metal Complexes as Redox Reagents and Redox Catalysts, Organic Synthesis via Organometallics (OMS 5), Ed, 253-278, 19960101
  114. Investigation of the manganese-substituted a-Keggin-heteropolyanion K6SiW11O39Mn(H2O) by cyclic voltammetry and its application as oxidation catalyst, J. Mol. Catal., A: Chemical, 114, 221-228, 19960101
  115. Palladium-Catalyzed Carbonylative [2+2] Cycloaddition for the Stereoselective Synthesis of Either cis- or trans-3-Alkenyl b-Lactams, J. Org. Chem, 59, 3040-3046, 19940101
  116. Carbonylative [2+2] Cycloaddition for the Contruction of b-Lactam Skelton with Palladium Catalyst, Tetra. Lett, 34, 6553-6556, 19930101
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  230. Intramolecular Electron Transfer and Oxygen Transfer of Phosphomolybdate Molecular Wires, INORGANIC CHEMISTRY, 58(18), 12272-12279, 20190916
    Link to Paper Search Results by DOI
  231. Synthesis of GME zeolite with high porosity by hydrothermal conversion of FAU zeolite using a dual-template method with tetraethylphosphonium and N,N-dimethyl-3,5-dimethylpiepridinium hydroxides, JOURNAL OF POROUS MATERIALS, 26(5), 1345-1352, 201910
    Link to Paper Search Results by DOI
  232. Immobilizaion of Preyssler type heteropoly acids on siliceous mesporous supports and their catalytic activities in the dehydration of ethanol, REACTION KINETICS MECHANISMS AND CATALYSIS, 128(1), 139-147, 201910
    Link to Paper Search Results by DOI
  233. Self-Assembled Tetrameric Lanthanide-Containing Germanotungstates [(Ln(2)GeW(10)O(38))(4)(W3O8)(OH)(4)(H2O)(2)](26-): Syntheses, Crystal Structure, Photoluminescence and Electrochemical Properties., CHEMISTRYSELECT, 4(43), 12668-12675, 20191122
    Link to Paper Search Results by DOI
  234. Multi-dimensional Crystal Structuring of Complex Metal Oxide Catalysts of Group V and VI Elements by Unit-Assembling, TOPICS IN CATALYSIS, 62(17-20), 1157-1168, 201911
    Link to Paper Search Results by DOI
  235. Formation Pathway of AEI Zeolites as a Basis for a Streamlined Synthesis, CHEMISTRY OF MATERIALS, 32(1), 60-74, 20200114
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  236. Synthesis of Preyssler-Type Phosphotungstate with Sodium Cation in the Central Cavity through Migration of the Ion, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 93(3), 461-466, 202003
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  237. New Path for Polyoxometalates: Controlled Synthesis and Characterization of Metal-Substituted Tungstosulfates, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020(8), 682-689, 20200228
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  238. Metal-substituted tungstosulfates with Keggin structure: synthesis and characterization, DALTON TRANSACTIONS, 49(9), 2766-2770, 20200307
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  239. High-quality synthesis of a nanosized CHA zeolite by a combination of a starting FAU zeolite and aluminum sources, DALTON TRANSACTIONS, 49(29), 9972-9982, 20200807
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  240. Solid-State Ion Migration in the Preyssler-Type Phosphotungstate for the Preparation of the Dipotassium Cation-Encapsulated Derivative, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 646(15), 1297-1302, 20200814
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  241. Effective Factor on Catalysis of Niobium Oxide for Magnesium, ACS OMEGA, 5(34), 21906-21912, 20200901
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  242. Triple-template system for phosphorus-modified AFX/CHA intergrowth zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 309, 20201215
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  243. Synthesis of Phosphorus-Modified AFX Zeolite by the Hydrothermal Conversion of Tetraalkylphosphonium Hydroxide-Impregnated FAU Zeolite, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 94(1), 1-7, 202101
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  244. Vanadium-Enhanced Intramolecular Redox Property of a Transition-Metal Oxide Molecular Wire, INORGANIC CHEMISTRY, 59(22), 16557-16566, 20201116
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  245. Ultrahigh Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-Type Polyoxometalate-Based Framework Functionalized with a Lanthanide Ion, ACS APPLIED MATERIALS & INTERFACES, 13(16), 19138-19147, 20210428
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  246. Multiple templating strategy for the control of aluminum and phosphorus distributions in AFX zeolite, MICROPOROUS AND MESOPOROUS MATERIALS, 321, 202107
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  247. Structural Characterization of Cerium-encapsulated Preyssler-type Phosphotungstate: Additional Evidence of Ce(III) in the Cavity, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 647(11), 1239-1244, 20210611
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  248. Poly(triethylene glycol methyl ether methacrylate) hydrogel as a carrier of phosphotungstic acid for acid catalytic reaction in water, MATERIALS ADVANCES, 2(11), 3556-3559, 20210607
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  249. Isolation and characterization of hirame aquareovirus (HAqRV): A new Aquareovirus isolated from diseased hirame Paralichthys olivaceus, VIROLOGY, 559, 120-130, 202107
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  250. Zeolitic Octahedral Metal Oxides with Ultra-Small Micropores for C-2 Hydrocarbon Separation, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 60(33), 18328-18334, 20210809
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  251. Catalytic Activities of Various Niobium Oxides for Hydrogen Absorption/Desorption Reactions of Magnesium, ACS OMEGA, 6(36), 23564-23569, 20210914
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  252. Structure and Thermal Transformations of Methylammonium Tungstate, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 647(19), 1930-1937, 20211012
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  253. Single-Molecule Magnetic, Catalytic and Photoluminescence Properties of Heterometallic 3d-4f [Ln{PZn2W10O38(H2O)(2)}(2)](11-) Tungstophosphate Nanoclusters, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2021(37), 3819-3831, 20211007
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Publications such as books

  1. 2015, Perovskite and Related Oxides, Three-Dimensionally Ordered Macroporous (3DOM) Perovskite Mixed Metal Oxide, 2015, Book(general), Joint work, English, Masahiro Sadakane, Wataru Ueda

Invited Lecture, Oral Presentation, Poster Presentation

  1. Synthesis of Supra-ceramics using polyoxometalates, Masahiro Sadakane, Annual meeting of Japan Ceramics Society, Satellite program, The 4th meeting of Supra-ceramics, 2024/03/13, With Invitation, Japanese
  2. Solid State Heat-promoted Synthesis and Acid-promoted Synthesis of Polyoxomolybdate from Methylammonium Monomolybate, Masahiro Sadakane, Ndaru C. Sukmana, Sugiarto, Frontiers in Metal Oxide Cluster Science (FMOCS)-VII, 2023/04/14, Without Invitation, English, FMOCS organizing committee, Taragona, Spain
  3. Catalytic activity of -oxo dimer of mono-ruthenium substituted -Keggin-type heteropolytungstates for water oxidation, Masahiro Sadakane, 2012 OCARINA Annual International Meeting, 2013/03/04, With Invitation, English, Oosaka
  4. Synthesis and characterization of Ru(CO) substituted heteropolytungstates, Masahiro Sadakane, International Symposium on Metal-Oxo Cluster Sciences: Exploring Novel Possibilities, 2018/08/05, With Invitation, English, Nippon University, Tokyo
  5. Reactivity of Ru sources with heteropolytungstates and reactivity of Ru containing heterpolytungstates, Masahiro Sadakane, ICCC2018, 2018/08/01, With Invitation, English, ICCC2018, Sendai, Japan
  6. Synthesis and redox of Ru-substituted heteropolytungstates, Masahiro Sadakane, International Forum in Metal Oxide Cluster Science, 2017/08/25, With Invitation, English, Kaifen ZhongZhou International Hotel, Kaifen, China
  7. Synthesis and application of Preyssler-type phosphotungstates with different encapsulated cations, Masahiro Sadakane, The Fifth International Symposium of Frontiers in Metal Oxide Cluster Science (FMOCS V), 2017/08/22, With Invitation, English
  8. Ultrathin Inorganic Nanowire based on Polyoxometalate, Masahiro Sadakane, Zhenxin Zhang, Nobuhiro Yasuda, Norihito Hiyoshi, Wataru Ueda, Frontiers in Metal Oxide Cluster Science-VI (FMOCS-VI), 2019/08/19, With Invitation, English

Awards

  1. 2007/04/15, BCSJ Award, The chemical society of Japan, Three-Dimensionally Ordered Macroporous (3DOM) Materials of Spinel-type Mixed Iron Oxides; Synthesis, Structural Characterization, and Formation Mechanism of Inverse Opals with Skeleton Structure

External Funds

Acceptance Results of Competitive Funds

  1. ‐, 2020//1/2/, 2023//0/9/
  2. KAKENHI(Grant-in-Aid for Scientific Research (B)), 2021, 2023
  3. Adaptable and Seamless Technology transfer Program through targetdriven R&D(A-STEP), 2021/05/01, 2022/03/31
  4. Strategic Basic Research Programs(PRESTO), 2010/10/01, 2014/03/31
  5. KAKENHI, 2014, 2016
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  6. KAKENHI, 2012, 2014
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  7. KAKENHI, Development of new heteropoly acid catalysts, 2009, 2011
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  8. KAKENHI, 2008, 2009
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  9. KAKENHI, Creation of octahedral metal oxide molecular sieves and their new catalytic functions, 2008, 2010
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  10. KAKENHI, Nano structurizing and new oxidation catalyst development of perovskite compound oxide by structuralo rganics assistance, 2006, 2007
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  11. KAKENHI, Construction of cluster lattice structured mixed metal oxides using unit synthesis and it's catalytic selective oxidation, 2004, 2005
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  12. KAKENHI, 2004, 2006
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  13. KAKENHI, Mechanism of carbon nanotube formation on metal supported on zirconia-based fine particles, 2002, 2004
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  14. KAKENHI, Formation of metal oxide cluster lattice and catalytic oxidation properties, 2001, 2002
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  15. KAKENHI, Structure engineering of functional solid catalysts by unit-network methodology, 2011, 2013
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  16. KAKENHI, 2015
  17. KAKENHI(Grant-in-Aid for Scientific Research (B)), 2018, 2020
  18. KAKENHI(Grant-in-Aid for Scientific Research on Innovative Areas), 2018, 2019

Social Activities

Organizing Academic Conferences, etc.

  1. 2014/04, 2014/09
  2. ZMPC2012, Local Organizing Committee, 2011/09, 2012/08
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  3. Kick-Off Meeting of EPSRC-JSPS Core-to-Core Collaboration in Advanced Materials International Network on Polyoxometalate Science for Advanced Energy Materials and NANOXCAT French-Japan International Associate Laboratory, Organizer, 2019/07, 2019/06