Tsutomu Mizuta

Last Updated :2026/06/11

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Professor
E-mail
tmizutahiroshima-u.ac.jpmizutasci.hiroshima-u.ac.jp
Other Contact Details
1-3-1, Kagamiyama, Higashi-Hiroshima, Japan
TEL : (+81)82-424-7420 FAX : (+81)82-424-0729

Basic Information

Major Professional Backgrounds

  • 1989/10/01, 1994/03/31, Hiroshima University, Research Assistant
  • 1994/04/01, 1996/03/31, Instiute for Molecular Science, Research Assistant
  • 1996/04/01, 2002/05/31, Hiroshima University, Research Assistant
  • 2002/06/01, 2011/08/31, Hiroshima University, Associate Professor

Educational Backgrounds

  • Hiroshima University, Graduate School, Division of Natural Science, Department of Chemistry, Japan, 1987/04, 1989/09
  • Hiroshima University, Graduate School, Division of Natural Science, Department of Chemistry, Japan, 1985/04, 1987/03
  • Hiroshima University, Faculty of Science, Japan, 1981/04, 1985/03

Academic Degrees

  • Doctor of Science, Hiroshima University
  • Master of Science, Hiroshima University

Educational Activity

  • [Bachelor Degree Program] School of Science : Chemistry : Chemistry
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program

In Charge of Primary Major Programs

  • Chemistry

Research Fields

  • Chemistry;Basic chemistry;Inorganic chemistry

Research Keywords

  • phosphine ligand
  • phcsphine|macrocycle
  • multinuclear metal complex
  • catalysis|multinuclear complex
  • Stereoselectivity
  • organometallic catalyst
  • metal complex
  • Phosphorus ligand
  • multidentate phosphorus ligand
  • electrontransfer

Educational Activity

Course in Charge

  1. 2026, Liberal Arts Education Program1, 2Term, Modern Chemistry
  2. 2026, Undergraduate Education, 4Term, Advanced Chemistry
  3. 2026, Undergraduate Education, First Semester, Special Study for Graduation
  4. 2026, Undergraduate Education, Second Semester, Special Study for Graduation
  5. 2026, Undergraduate Education, 3Term, Organometallic Chemistry
  6. 2026, Graduate Education (Master's Program) , First Semester, Exercises in Chemistry A
  7. 2026, Graduate Education (Master's Program) , Second Semester, Exercises in Chemistry B
  8. 2026, Graduate Education (Master's Program) , Year, Master's Thesis in Chemistry
  9. 2026, Graduate Education (Doctoral Program) , Year, Doctoral Thesis in Chemistry

Research Activities

Academic Papers

  1. Redox Activity of IrIII Complexes with Multidentate Ligands Based on Dipyrido-Annulated N-Heterocyclic Carbenes: Access to High Valent and High Spin State with Carbon Donors, Chemistry A European Journal, 29(63), 20231113
  2. Redox Activity of IrIII Complexes with Multidentate Ligands Based on Dipyrido-Annulated N-Heterocyclic Carbenes: Access to High Valent and High Spin State with Carbon Donors, Chemistry A European Journal, 29(63), 20231113
  3. Improved syntheses of doubly naphthalene-bridged diphosphine and its diiminodiphosphorane derivatives linking two Cu(I) centers, Polyhedron, 233, 20230315
  4. Improved syntheses of doubly naphthalene-bridged diphosphine and its diiminodiphosphorane derivatives linking two Cu(I) centers, Polyhedron, 233, 20230315
  5. An Alkynyl-Stabilized Pt5Ag22 Cluster Featuring a Two-Dimensional Alkynyl–Platinum “Crucifix Motif”, Chemistry A European Journal, 23(71), 17885-17888, 20171219
  6. An Alkynyl-Stabilized Pt5Ag22 Cluster Featuring a Two-Dimensional Alkynyl–Platinum “Crucifix Motif”, Chemistry A European Journal, 23(71), 17885-17888, 20171219
  7. An Atomically Precise Alkynyl-Protected PtAg42 Superatom Nanocluster and Its Structural Implications, Chemistry an Asian Journal, 12(22), 2904-2907, 20171116
  8. An Atomically Precise Alkynyl-Protected PtAg42 Superatom Nanocluster and Its Structural Implications, Chemistry an Asian Journal, 12(22), 2904-2907, 20171116
  9. Hydrolysis of Me3SiCH2 groups on a double-chelating bis(ferrocenediyl)diphosphine coordinating to a Pt(0) center, Polyhedron, 110, 114-118, 20160528
  10. Hydrolysis of Me3SiCH2 groups on a double-chelating bis(ferrocenediyl)diphosphine coordinating to a Pt(0) center, Polyhedron, 110, 114-118, 20160528
  11. Synthesis of bicyclic diphosphine having a P-P bond doubly clamped with two 1,8-naphthalenediyl groups, Polyhedron, 92, 37-40, 20150528
  12. Synthesis of bicyclic diphosphine having a P-P bond doubly clamped with two 1,8-naphthalenediyl groups, Polyhedron, 92, 37-40, 20150528
  13. Synthesis of a hetero-bimetallic complex with an inorganic cyclic framework using a bis(iminophosphorane)iron complex as a chelating ligand, CHEMISTRY LETTERS, 37(2), 166-167, 20080205
    Link to Paper Search Results by DOI
  14. PhP-PPh group bound to 1,8-positions of naphthalene: Preparation of cis isomer and synthesis of binuclear complex, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 696(21), 3402-3407, 20111015
    Link to Paper Search Results by DOI
  15. Synthesis and Crystal Structures of P-Iron-Substituted Phosphinoborane Monomers, ORGANOMETALLICS, 31(5), 2026-2034, 20120312
    Link to Paper Search Results by DOI
  16. Synthesis of [2]ferrocenophanes containing trivalent diphosphine units, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 713, 80-88, 20120815
    Link to Paper Search Results by DOI
  17. Formation of a Hexacarbonyl Diiron Complex Having a Naphthalene-1,8-bis(phenylphosphido) Bridge and the Electrochemical Behavior of Its Derivatives, ORGANOMETALLICS, 32(23), 7014-7024, 20131209
    Link to Paper Search Results by DOI
  18. Reduction of CO2 to Trimethoxyboroxine with BH3 in THF, ORGANOMETALLICS, 33(22), 6692-6695, 20141124
    Link to Paper Search Results by DOI
  19. Synthesis of bicyclic diphosphine having a P-P bond doubly clamped with two 1,8-naphthalenediyl groups, POLYHEDRON, 92, 30-36, 20150528
    Link to Paper Search Results by DOI
  20. Naphtho[1,8-b,c]phosphete and 1,2-diphosphaacenaphthene from the reaction of 1,8-dilithionaphthalene with RPCl2., Naphtho[1,8-b,c]phosphete and 1,2-diphosphaacenaphthene from the reaction of 1,8-dilithionaphthalene with RPCl2., 41(20), 2002
  21. Naphtho[1,8-b,c]phosphete and 1,2-diphosphaacenaphthene from the reaction of 1,8-dilithionaphthalene with RPCl2., Naphtho[1,8-b,c]phosphete and 1,2-diphosphaacenaphthene from the reaction of 1,8-dilithionaphthalene with RPCl2., 41(20), 2002
  22. Naphtho[1,8-b,c]phosphete and 1,2-diphosphaacenaphthene from the reaction of 1,8-dilithionaphthalene with RPCl2., Naphtho[1,8-b,c]phosphete and 1,2-diphosphaacenaphthene from the reaction of 1,8-dilithionaphthalene with RPCl2., 41(20), 2002
  23. Ring-opening reaction of phosphorus-bridged [1]ferrocenophane via ring slippage from eta(5)- to eta(1)-Cp., Ring-opening reaction of phosphorus-bridged [1]ferrocenophane via ring slippage from eta(5)- to eta(1)-Cp., 125(8), 2003
  24. Ring-opening reaction of phosphorus-bridged [1]ferrocenophane via ring slippage from eta(5)- to eta(1)-Cp., Ring-opening reaction of phosphorus-bridged [1]ferrocenophane via ring slippage from eta(5)- to eta(1)-Cp., 125(8), 2003
  25. Ring-opening reaction of phosphorus-bridged [1]ferrocenophane via ring slippage from eta(5)- to eta(1)-Cp., Ring-opening reaction of phosphorus-bridged [1]ferrocenophane via ring slippage from eta(5)- to eta(1)-Cp., 125(8), 2003
  26. Synthesis of binuclear complexes bound in an enlarged tetraphosphamacrocycle: two diphosphine metal units linked in front-to-front style., Synthesis of binuclear complexes bound in an enlarged tetraphosphamacrocycle: two diphosphine metal units linked in front-to-front style., 48(16), 2009
  27. Synthesis of binuclear complexes bound in an enlarged tetraphosphamacrocycle: two diphosphine metal units linked in front-to-front style., Synthesis of binuclear complexes bound in an enlarged tetraphosphamacrocycle: two diphosphine metal units linked in front-to-front style., 48(16), 2009
  28. Synthesis of binuclear complexes bound in an enlarged tetraphosphamacrocycle: two diphosphine metal units linked in front-to-front style., Synthesis of binuclear complexes bound in an enlarged tetraphosphamacrocycle: two diphosphine metal units linked in front-to-front style., 48(16), 2009
  29. Structure elucidation of secondary metabolites isolated from the leaves of Ixora undulate and their inhibitory activity toward advanced glycation end-products formation., Structure elucidation of secondary metabolites isolated from the leaves of Ixora undulate and their inhibitory activity toward advanced glycation end-products formation., 108, 2014