Hiroto Yoshida

Last Updated :2025/06/30

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Professor
Web Site
E-mail
yhirotohiroshima-u.ac.jp
Other Contact Details
1-3-1 Kagamiyama, Higashi-Hiroshima, Japan
TEL : (+81)82-424-7724 FAX : (+81)
Self-introduction
Development of new synthetic methodologies based on new reactions, reagents, and catalysts

Basic Information

Major Professional Backgrounds

  • 2001/04/01, 2006/11/30, Hiroshima University, Graduate School of Engineering, Research Assistant
  • 2006/12/01, 2007/03/31, Hiroshima University, Graduate School of Engineering, Assistant Professor
  • 2007/04/01, 2020/03/31, Hiroshima University, Graduate School of Engineering, Associate Professor
  • 2020/04/01, Hiroshima University, Graduate School of Advanced Science and Engineering, Professor
  • 2006/09/01, 2006/11/10, Iowa State University, Researcher
  • 2012/10, JST ACT-C, Principal Investigator
  • 2016, Okayama University, Lecturer (part-time)
  • 2020, Kyushu University, Lecturer (part-time)
  • 2023, Kwansei Gakuin University, Lecturer (part-time)
  • 2023, Gifu University, Lecturer (part-time)

Educational Backgrounds

  • Kyoto University, Graduate School, Division of Engineering, Department of Material Chemistry, Japan, 1998/04, 2001/03
  • Kyoto University, 1996/04, 1998/03
  • Kyoto University, Faculty of Engineering, Japan, 1992/04, 1996/03

Academic Degrees

  • Doctor of Engineering, Kyoto University
  • Master of Engineering, Kyoto University

Educational Activity

  • [Bachelor Degree Program] School of Science : Chemistry : Chemistry
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program

In Charge of Primary Major Programs

  • Chemistry

Research Fields

  • Chemistry;Basic chemistry;Organic chemistry
  • Chemistry;Applied chemistry;Synthetic chemistry

Research Keywords

  • Main Group Organometallics
  • transition metal catalyst
  • reactive intermediate

Affiliated Academic Societies

  • Catalysis Society of Japan
  • The Society of Physical Organic Chemistry, Japan

Educational Activity

Course in Charge

  1. 2025, Liberal Arts Education Program1, 2Term, Modern Chemistry
  2. 2025, Undergraduate Education, First Semester, Special Study for Graduation
  3. 2025, Undergraduate Education, Second Semester, Special Study for Graduation
  4. 2025, Undergraduate Education, 1Term, Organic Chemistry I
  5. 2025, Undergraduate Education, Year, Advanced Subject Research
  6. 2025, Undergraduate Education, 3Term, Synthetic organic chemistry
  7. 2025, Undergraduate Education, First Semester, Special Lectures in Chemistry (Mechanistic Analysis of Organic Reactions)
  8. 2025, Graduate Education (Master's Program) , First Semester, Exercises in Chemistry A
  9. 2025, Graduate Education (Master's Program) , Second Semester, Exercises in Chemistry B
  10. 2025, Graduate Education (Master's Program) , Year, Master's Thesis in Chemistry
  11. 2025, Graduate Education (Doctoral Program) , Year, Doctoral Thesis in Chemistry

Award of Education

  1. 2019/72
  2. 2015
  3. 2014
  4. 2012
  5. 2012/11
  6. 2010
  7. 2008

Research Activities

Academic Papers

  1. Stannylation of alkyl chlorides with stannylpotassium, CHEMISTRY LETTERS, 53(12), 20241231
  2. Modulating Lewis acidity with boronamides and boronates: effect on behavior in borylation and cross-coupling, CHEMISTRY LETTERS, 53(11), 20241126
  3. Weak Base-Promoted Direct Cross-Coupling of Naphthalene-1,8-diaminato-substituted Arylboron Compounds, JACS AU, 4(10), 3931-3941, 20241007
  4. Surefire generation of stannylpotassium: highly reactive stannyl anions and applications, CHEMICAL SCIENCE, 15(37), 15152-15159, 20240925
  5. Modulation of Lewis Acidity and Steric Parameters in Cyclic Boronates: Copper-Catalyzed Internal-Selective Borylation of Challenging Terminal Alkynes, ACS CATALYSIS, 14(17), 12694-12703, 20240808
  6. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation, CHEMICAL COMMUNICATIONS, 60(50), 20240618
  7. Ethynyl-B(dan) in [3+2] Cycloaddition and Larock Indole Synthesis: Synthesis of Stable Boron-Containing Heteroaromatic Compounds, CHEMISTRY-A EUROPEAN JOURNAL, 30(8), 20240207
  8. Complexation-Triggered Fluctuation of π-Conjugation on an Antiaromatic Dicyanoanthracene Dianion, CHEMISTRY-A EUROPEAN JOURNAL, 29(70), 20231214
  9. Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines, ORGANIC LETTERS, 25(39), 7192-7197, 20230921
  10. Efficient one-pot synthesis of dan-substituted organo- and silyl-boron compounds, ORGANIC & BIOMOLECULAR CHEMISTRY, 21(26), 20230705
  11. Direct Suzuki-Miyaura Coupling of Naphthalene-1,8-diaminato (dan)-Substituted Cyclopropylboron Compounds, ADVANCED SYNTHESIS & CATALYSIS, 365(5), 682-686, 20230307
  12. Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides, RSC ADVANCES, 13(4), 2451-2457, 20230111
  13. Main-Group Organometallics Containing Boron or Tin that Open New Frontiers in Organic Synthesis, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 80(5), 477-488, 2022
  14. A stable silylborane with diminished boron Lewis acidity, DALTON TRANSACTIONS, 51(17), 6543-6546, 20220503
  15. Preparation of (pin)B-B(dan), ORGANIC SYNTHESES, 95, 218-+, 2018
  16. Platinum-P(BFPy)(3)-catalyzed regioselective diboration of terminal alkynes with (pin)B-B(aam), ORGANIC CHEMISTRY FRONTIERS, 9(5), 1370-1374, 20220301
  17. Straightforward construction of diarylmethane skeletons via aryne insertion into carbon-carbon sigma-bonds, CHEMICAL COMMUNICATIONS, 1505-1507, 2007
  18. Insertion of arynes into carbon-halogen sigma-bonds: regioselective acylation of aromatic rings, CHEMICAL COMMUNICATIONS, 2405-2407, 2007
  19. Three-component coupling of arynes, aminosilanes, and aldehydes, ORGANIC LETTERS, 9(17), 3367-3370, 20070816
  20. Three-component coupling using arynes and aminosilanes for ortho-selective double functionalization of aromatic skeletons, JOURNAL OF ORGANIC CHEMISTRY, 73(14), 5452-5457, 20080718
  21. Direct access to anthranilic acid derivatives via CO(2) incorporation reaction using arynes, ORGANIC LETTERS, 10(17), 3845-3847, 20080904
  22. Palladium-catalyzed disilylation of o-quinodimethanes: Synthesis of 9-and 10-membered disilacarbocycles, ORGANIC LETTERS, 10(19), 4319-4322, 20081002
  23. Fluorenes as new molecular scaffolds for carbon-carbon sigma-bond cleavage reaction: acylfluorenylation of arynes, CHEMICAL COMMUNICATIONS, 5963-5965, 2008
  24. Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes, ORGANIC LETTERS, 11(2), 373-376, 20090115
  25. Copper-catalysed bromoalkynylation of arynes, CHEMICAL COMMUNICATIONS, 46(4), 640-642, 2010
  26. Insertion of Arynes into Carbon-Chlorine Bonds of Chlorotriazines, CHEMISTRY LETTERS, 38(12), 1132-1133, 20091205
  27. Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes, CHEMICAL COMMUNICATIONS, 46(10), 1763-1765, 2010
  28. Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 83(3), 199-219, 20100315
  29. An Aryne Route to Cytosporone B and Phomopsin C, CHEMISTRY LETTERS, 39(5), 508-509, 20101205
  30. Facile access to boryltetralins and borylnaphthalenes via a cycloaddition using o-quinodimethanes, CHEMICAL COMMUNICATIONS, 46(29), 5253-5255, 2010
  31. Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by (13C) CP-MAS NMR, CHEMISTRY LETTERS, 39(11), 1215-1217, 20101105
  32. Hybridization of Carbon Nanotubes with Si-pi Polymers and Attachment of Resulting Hybrids to TiO2 Surface, CHEMISTRY LETTERS, 40(1), 87-89, 20110105
  33. Synthesis of Dithienogermole-Containing pi-Conjugated Polymers and Applications to Photovoltaic Cells, ORGANOMETALLICS, 30(12), 3233-3236, 20110627
  34. Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides, CHEMICAL COMMUNICATIONS, 47(30), 8512-8514, 2011
  35. Aryne reaction with trifluoromethyl ketones in three modes: C-C bond cleavage, [2+2] cycloaddition and O-arylation, CHEMICAL COMMUNICATIONS, 47(30), 8664-8666, 2011
  36. Three-Component Coupling of Arynes and Organic Bromides, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 50(41), 9676-9679, 2011
  37. An ortho-Quinodimethane Route to Lasofoxifene and U23469, CHEMISTRY LETTERS, 40(11), 1272-1274, 20111105
  38. Synthesis and Optical Properties of Pyridino End-Capped Oligothiophenes, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 84(11), 1243-1247, 20111115
  39. Palladium-Iminophosphine-Catalysed Carbostannylation of Arynes: Synthesis of ortho-Substituted Arylstannanes, Chem. Commun., 1880-1881, 20010401
  40. Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism, Bull. Chem. Soc. Jpn, 637-647, 20010401
  41. Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes, Organometallics, 5671-5678, 20000401
  42. Mechanistic Aspects of Palladium-Catalyzed Allylstannylation of Alkynes, Org. Lett., 2209-2211, 20000401
  43. Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synethesis and Reaction of e-Oxoallylstannanes, J. Am. Chem. Soc., 9030-9031, 20000401
  44. Diphenylphosphinophenolate: a Ligand for the Palladium-Catalysed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon, Chem. Commun., 1895-1896, 20000401
  45. Palladium-Catalyzed Dimerization-Carbostannylation of Alkynes: Synthesis of Highly Conjugated Alkenylstannanes, J. Am. Chem. Soc., 4290-4291, 19990401
  46. Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes: Stereoselective Synthesis of Trisubstituted Vinylstannanes, J. Am. Chem. Soc., 10221-10222, 19990401
  47. Carbostannylation of Alkynes Catalyzed by an Iminophosphine-Palladium Complex, J. Am. Chem. Soc., 2975-2976, 19980401
  48. An Iminophosphine-Palladium Catalyst for Cross-Coupling of Aryl Halides with Organostannanes, Tetrahedron Lett., 3759-3762, 19970401
  49. On the Catalytic Cycle of the Palladium-Catalyzed Cross-Coupling Reaction of Alkynylstannane with Aryl Iodide, Tetrahedron Lett., 5177-5180, 19970401
  50. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives, Angew. Chem. Int. Ed., 3247-3249, 20020401
  51. Base-Free Oxidative Homocoupling of Arylboronic Esters, Tetrahedron Lett., 1541-1544, 20030401
  52. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes: Synthesis of Benzo-Annulated Disilacarbocycles, J. Am. Chem. Soc., 6638-6639, 20030401
  53. Activator-Free Oxidative Homocoupling of Organosilanes Catalysed by a Palladium-DPPP Complex, Chem. Commun., 1510-1511, 20030401
  54. Thiostannylation of Arynes with Stannyl Sulfides: Synthesis and Reaction of 2-(Arylthio)arylstannanes, Chem. Commun., 1980-1981, 20040401
  55. Arynes in Three-Component Coupling Reaction: Straightforward Synthesis of Benzo-Annulated Iminofurans, Angew. Chem. Int. Ed., 3935-3938, 20040401
  56. Distannylation of Strained Carbon-Carbon Triple Bonds Catalyzed by a Palladium Complex, Angew. Chem. Int. Ed., 5052-5055, 20040401
  57. Straightforward Access to 2-Iminoisoindolines via Three-Component Coupling of Arynes, Isocyanides and Imines, Tetrahedron Lett., 8659-8662, 20040401
  58. A 2 : 1 Coupling Reaction of Arynes with Aldehydes via o-Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes, Org. Lett., 4049-4051, 20040401
  59. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent, Chem. Lett., 56-57, 20050401
  60. Cyclic Voltammetry and Theoretical Calculations of Silyl-substituted 1,4-Benzoquinones, J. Organomet. Chem., 1324-1331, 20050401
  61. Aminosilylation of Arynes with Aminosilanes: Synthesis of 2-Silylaniline Derivatives, Chem. Commun., 3454-3456, 20050401
  62. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide, Chem. Lett., 1538-1539, 20050401
  63. Palladium-Catalyzed Distannylation of ortho-Quinodimethanes, Org. Lett., 4157-4159, 20060401
  64. CO2 Incorporation Reaction using Arynes: Straightforward Access to Benzoxazinone, J. Am. Chem. Soc., 11040-11041, 20060401
  65. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles, Tetrahedron, 4793-4805, 20070401
  66. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes, Org. Lett., 3367-3370, 20070701
  67. Aryne Insertion Reactions into sigma-Bonds, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 69(8), 877-888, 20110801
  68. Facile synthesis of N-alkyl-N '-arylimidazolium salts via addition of imidazoles to arynes, ORGANIC LETTERS, 4(16), 2767-2769, 20020808
  69. Base-free oxidative homocoupling of arylboronic esters, TETRAHEDRON LETTERS, 44(8), 1541-1544, 20030217
  70. Palladium-catalyzed bissilylation of arynes with cyclic disilanes: Synthesis of benzo-annulated disilacarbocycles, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(22), 6638-6639, 20030604
  71. Activator-free oxidative homocoupling of organosilanes catalysed by a palladium-DPPP complex, CHEMICAL COMMUNICATIONS, 1510-1511, 2003
  72. Synthesis of organosilanylene-thienylene alternating oligomers bearing ether side chains, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 682(1-2), 267-271, 20031001
  73. 2,3,5,6-tetrasilyl- and 2,3,5,6-tetragermyl-1,4-benzoquinones: X-ray crystallographic analysis, cyclic voltammetry, and DFT calculations, ORGANOMETALLICS, 23(7), 1554-1561, 20040329
  74. Arynes in a three-component coupling reaction: Straightforward synthesis of benzoannulated iminofurans, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(30), 3935-3938, 2004
  75. Thiostannylation of arynes with stannyl sulfides: synthesis and reaction of 2-(arylthio)arylstannanes, CHEMICAL COMMUNICATIONS, 1980-1981, 2004
  76. Distannylation of strained carbon-carbon triple bonds catalysed by a palladium complex, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(38), 5052-5055, 2004
  77. A 2 : 1 coupling reaction of arynes with aldehydes via o-quinone methides: Straightforward synthesis of 9-arylxanthenes, ORGANIC LETTERS, 6(22), 4049-4051, 20041028
  78. Straightforward access to 2-iminoisoindolines via three-component coupling of arynes, isocyanides and imines, TETRAHEDRON LETTERS, 45(47), 8659-8662, 20041115
  79. Cyclic voltammetry and theoretical calculations of silyl-substituted 1,4-benzoquinones, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690(5), 1324-1331, 20050301
  80. Addition of silicon-silicon or-bonds to arynes or bisarynes catalyzed by a palladium complex, ORGANOMETALLICS, 24(1), 156-162, 20050103
  81. Facile synthesis of polycyclic aromatic hydrocarbons via a trisaryne equivalent, CHEMISTRY LETTERS, 34(1), 56-57, 20050105
  82. Palladium-catalysed dimerisation-distannylation of arynes: synthesis and reaction of 2,2 '-distannylbiaryls, CHEMICAL COMMUNICATIONS, 5678-5680, 2005
  83. Transition metal-catalyzed reactions or electrophilic coupling reactions using arynes, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 63(6), 627-639, 200506
  84. Facile insertion reaction of arynes into carbon-carbon sigma-bonds, CHEMICAL COMMUNICATIONS, 3292-3294, 2005
  85. Aminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivatives, CHEMICAL COMMUNICATIONS, 3454-3456, 2005
  86. Aryne insertion into alpha-cyanocarbonyl compounds: direct introduction of carbonyl and cyanomethyl moieties into the aromatic skeletons, TETRAHEDRON LETTERS, 46(39), 6729-6731, 20050926
  87. Sonogashira coupling of diethynylsilane and dibromoarene in wet solvent for the formation of poly[(ethynylenearylene)-co-(diethynylenesilylenearylene)], JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690(17), 3951-3956, 20050901
  88. Carbophosphinylation of arynes with cyanomethyldiphenylphosphine oxide, CHEMISTRY LETTERS, 34(11), 1538-1539, 20051105
  89. CO2 incorporation reaction using arynes: Straightforward access to benzoxazinone, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(34), 11040-11041, 20060830
  90. Palladium-catalyzed distannylation of ortho-quinodimethanes, ORGANIC LETTERS, 8(18), 4157-4159, 20060831
  91. Synthesis of organosilicon polymers containing donor-acceptor type pi-conjugated units and their applications to dye-sensitized solar cells, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(4), 801-805, 20070115
  92. Synthesis of diarylenenaphthylene- and diaryleneanthrylene-containing organosilicon polymers and their applications to organic EL devices, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(5), 1020-1024, 20070201
  93. Three-component coupling using arynes and isocyanides: straightforward access to benzo-annulated nitrogen or oxygen heterocycles, TETRAHEDRON, 63(22), 4793-4805, 20071228
  94. Aryne Insertion Reactions into sigma-Bonds, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 69(8), 877-888, 201108
  95. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 51(1), 235-238, 2012
  96. MULTICOMPONENT COUPLING REACTION OF ARYNES FOR CONSTRUCTION OF HETEROCYCLIC SKELETONS, HETEROCYCLES, 85(6), 1333-1349, 20120601
  97. Aryne Insertion Reactions into Carbon-Carbon sigma-Bonds, SYNLETT, 1725-1732, 201207
  98. Hetero-Diels-Alder reaction of photochemically generated alpha-hydroxy-o-quinodimethanes with trifluoromethyl ketones, TETRAHEDRON LETTERS, 53(31), 3974-3976, 20120801
  99. Copper-Catalyzed Three-Component Borylstannylation of Alkynes, CHEMISTRY-A EUROPEAN JOURNAL, 18(46), 14841-14844, 201211
  100. SYNTHESIS AND REACTIONS OF SILICON-BRIDGED DITHIENYLBIPHENYLS. FINE TUNING OF ELECTRONIC STATES BY BRIDGING SILICON CHAIN LENGTHS, HETEROCYCLES, 86(2), 1167-1176, 20121231
  101. Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes, ORGANIC LETTERS, 15(4), 952-955, 20130215
  102. Synchronous Ar-F and Ar-Sn Bond Formation through Fluorostannylation of Arynes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 52(33), 8629-8632, 20130812
  103. Copper-catalyzed distannylation of alkynes, CHEMICAL COMMUNICATIONS, 49(99), 11671-11673, 2013
  104. A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons, CHEMICAL COMMUNICATIONS, 50(61), 8299-8302, 201408
  105. Three-Component Carboboration of Alkenes under Copper Catalysis, SYNTHESIS-STUTTGART, 46(14), 1924-1932, 201407
  106. Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes, ORGANIC LETTERS, 16(13), 3512-3515, 201407
  107. N-Heterocyclic carbene-catalyzed double acylation of enones with benzils, CHEMICAL COMMUNICATIONS, 50(82), 12285-12288, 201410
  108. Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes, SYNTHESIS-STUTTGART, 46(22), 3024-3032, 201411
  109. Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes, ASIAN JOURNAL OF ORGANIC CHEMISTRY, 3(11), 1204-1209, 201411
  110. Synchronous Ar?F and Ar?Sn Bond Formation through Fluorostannylation of Arynes, Synform, A147-A149, 20131201
  111. Convenient Synthesis of 2-Amino-4H-chromenes from Photochemically Generated o-Quinone Methides and Malononitrile, JOURNAL OF HETEROCYCLIC CHEMISTRY, 52(1), 59-66, 201501
  112. Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron, CHEMICAL COMMUNICATIONS, 51(29), 6297-6300, 201502
  113. Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide, CHEMICAL COMMUNICATIONS, 51(46), 9440-9442, 201504
  114. Copper-catalyzed alpha-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes, CHEMICAL COMMUNICATIONS, 51(53), 10616-10619, 201505
  115. Copper-Catalyzed Metallation Reactions of Unsaturated Carbon-Carbon Bonds, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 73(6), 632-648, 201506
  116. Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si, CHEMICAL RECORD, 16(1), 419-434, 201602
  117. Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments, ACS CATALYSIS, 6(3), 1799-1811, 201603
  118. Stannylation Reactions under Base Metal Catalysis: Some Recent Advances, SYNTHESIS-STUTTGART, 48(16), 2540-2552, 201608
  119. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes, ORGANIC LETTERS, 19(4), 830-833, 20170217
  120. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes, CHEMISTRYSELECT, 2(11), 3212-3215, 20170413
  121. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides, ORGANOMETALLICS, 36(7), 1345-1351, 20170410
  122. Naphthobispyrazine as an Electron-deficient Building Unit for pi-Conjugated Polymers: Efficient Synthesis and Polymer Properties, CHEMISTRY LETTERS, 46(8), 1193-1196, 201708
  123. Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan), ORGANIC CHEMISTRY FRONTIERS, 4(7), 1215-1219, 201707
  124. Aryne-Imine-Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o-Quinone Methides and Arynes, ASIAN JOURNAL OF ORGANIC CHEMISTRY, 6(8), 973-976, 201708
  125. NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 13, 1816-1822, 20170830
  126. B(MIDA)-Containing Diborons, ACS OMEGA, 2(9), 5911-5916, 201709
  127. &ITmeso&IT-Tetraaryl(porphyrinato)cobalt(III)-catalyzed Oxygenation of Disilanes under Aerobic Conditions, CHEMISTRY LETTERS, 46(12), 1807-1809, 201712
  128. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes, Org. Lett., 19(4), 830-833, 20170401
  129. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes, ChemistrySelect, 2(11), 3212-3215, 20170401
  130. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides, Organometallics, 36(7), 1345-1351, 20170401
  131. Naphthobispyrazine as an Electron-deficient Building Unit for -Conjugated Polymers: Efficient Synthesis and Polymer Properties, Chem. Lett., 46(8), 1193-1196, 20170601
  132. Copper-Catalyzed Direct Borylation of Alkyl, Alkenyl and Aryl Halides with B(dan), Org. Chem. Front., 4(7), 1215-1219, 20170701
  133. Aryne–Imine–Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o-Quinone Methides and Arynes, Asian J. Org. Chem., 6(8), 973-976, 20170801
  134. NHC-Catalyzed Cleavage of Vicinal Diketones and Triketones Followed by Insertion of Enones and Ynones, Beilstein J. Org. Chem., 13, 1816-1822, 20170801
  135. B(MIDA)-Containing Diborons, ACS Omega, 2(9), 5911-5916, 20170901
  136. Copper-catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar-Br Bond, CHEMISTRY LETTERS, 47(8), 957-959, 201808
  137. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer, CHEMICAL COMMUNICATIONS, 54(67), 9290-9293, 20180828
  138. Anthranilamide (aam)-substituted arylboranes in direct carbon-carbon bond-forming reactions, CHEMICAL COMMUNICATIONS, 55(18), 2624-2627, 20190304
  139. Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates, MOLECULES, 24(8), 20190402
  140. An anthranilamide-substituted borane [H-B(aam)]: its stability and application to iridium-catalyzed stereoselective hydroboration of alkynes, CHEMICAL COMMUNICATIONS, 55(38), 5420-5422, 20190511
  141. Copper-catalyzed arylstannylation of arynes in a sequence, CHEMICAL COMMUNICATIONS, 55(46), 6503-6506, 20190611
  142. Copper-Catalyzed B(dan)-Installing Allylic Borylation of Allylic Phosphates, ADVANCED SYNTHESIS & CATALYSIS, 361(10), 2286-2290, 20190514
  143. Preparation of (pin)B–B(dan), Organic Syntheses, 95, 218-230, 201807
  144. Dithiazolylthienothiophene Bisimide: A Novel Electron-Deficient Building Unit for N-Type Semiconducting Polymers, ACS APPLIED MATERIALS & INTERFACES, 11(26), 23410-23416, 20190703
  145. One-pot Sequential Fluorostannylation-Arylstannylation of Arynes, CHEMISTRY LETTERS, 48(9), 1032-1034, 201909
  146. Direct Suzuki-Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons, ACS CATALYSIS, 10(1), 346-351, 20200103
  147. Dithiazolylthienothiophene Bisimide-Based pi-Conjugated Polymers: Improved Synthesis and Application to Organic Photovoltaics as P-Type Semiconductor, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 93(4), 561-567, 202004
  148. Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H-B(dan) as a B(dan) electrophile, CHEMICAL COMMUNICATIONS, 56(47), 6388-6391, 20200614
  149. A leap forward in sulfonium salt and sulfur ylide chemistry, CHINESE CHEMICAL LETTERS, 32(1), 299-312, 202101
  150. Synthetic Chemistry with Lewis Acidity-Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross-Couplings, ADVANCED SYNTHESIS & CATALYSIS, 363(9), 2310-2324, 20210427
  151. Transition Metal-Free B(dan)-Installing Reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) Electrophile, Chemical Communications, 56(47), 6388-6391, 20200430
  152. RECENT ADVANCES IN SYNTHETIC TRANSFORMATIONS WITH ROBUST YET REACTIVE B(DAN) MOIETY, HETEROCYCLES, 102(8), 1478-1516, 2021
  153. MPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters, SYNTHESIS-STUTTGART, 53(24), 4678-4681, 20211217
  154. Borylation and Stannylation Reactions with Tuning of Lewis Acidity, CHEMICAL RECORD, 21(12), 3483-3497, 202112
  155. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes, ACS CATALYSIS, 11(23), 14381-14387, 20211203

Publications such as books

  1. 2022, Science of Synthesis Knowledge Updates 2022/3, 4.4.6 Product Subclass 6, Thieme, 2022, Scholarly Book, Contributor, 英語, O. Jackowski, C. Marschner, H. Ohmiya, A. Perez-Luna, D. C. G. A. Pinto, D. H. A. Rocha, C. M. M. dos Santos, V. L. M. Silva, Y. Sumida, N. Takeda, X. Tang, H. Yoshida, 9783132452862, 536, 1-21
  2. 2022, Comprehensive Aryne Synthetic Chemistry, Elsevier, 2022, Scholarly Book, Supervisor, 英語, A. T. Biju, J. Chen, S. Deswal, A. Guin, T. Hamura, T. Ikawa, X. Jiang, J. Tan, H. Tanaka, G. Zhu, H. Yoshida, 978-0-323-85153-4, 381, 1-381
  3. 2022, Comprehensive Aryne Synthetic Chemistry, General introduction to Comprehensive Aryne Synthetic Chemistry, Elsevier, 2022, Scholarly Book, Contributor, 英語, A. T. Biju, J. Chen, S. Deswal, A. Guin, T. Hamura, T. Ikawa, X. Jiang, J. Tan, H. Tanaka, G. Zhu, H. Yoshida, 978-0-323-85153-4, 381, 1-11
  4. 2022, Comprehensive Aryne Synthetic Chemistry, Insertion into sigma-Bonds, Elsevier, 2022, Scholarly Book, Contributor, 英語, A. T. Biju, J. Chen, S. Deswal, A. Guin, T. Hamura, T. Ikawa, X. Jiang, J. Tan, H. Tanaka, G. Zhu, H. Yoshida, 978-0-323-85153-4, 381, 57-123
  5. 2021, Modern Aryne Chemistry, Multicomponent Reactions Involving Arynes and Related Chemistry, Wiley-VCH, 2021, Scholarly Book, Contributor, 英語, Hiroto Yoshida, 505
  6. 2021, e-EROS Encyclopedia of Reagents for Organic Synthesis, N-(Carboxymethyl)-N-methyl-glycine, Wiley, 2021, Dictionary/Encyclopedia, Single work, 英語, Hiroto Yoshida
  7. 2020/05/04, e-EROS, Encyclopedia of Reagents for Organic Synthesis, 1H-Naphtho[1,8-de]-1,3,2-diazaborine, 2,3-Dihydro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-, Wiley, 2020, 2020, Dictionary/Encyclopedia, Single work, 英語, Hiroto Yoshida

Invited Lecture, Oral Presentation, Poster Presentation

  1. Palladium-Catalyzed Direct Suzuki–Miyaura Cross-Coupling of dan-Substituted Organoboron Reagents under Weak Base Conditions, Kazuki Tomota, Masaaki Nakamoto, Takumi Tsushima, and Hiroto Yoshida, 2024/09/09, Without Invitation, Japanese
  2. Stannylation of Aryl Chlorides with Stannylpotassium Reagents, Ryoka Hirata, Yuta Hiraoka, Masaaki Nakamoto, Takumi Tsushima, and Hiroto Yoshida, 2024/09/09, Without Invitation, Japanese
  3. Synthesis of 2-Iodoarylstannanes by Iodostannylation of Arynes, Taiga Obayashi, Masaaki Nakamoto, Takumi Tsushima, and Hiroto Yoshida, 2024/09/09, Without Invitation, Japanese
  4. Synthetic study of cyclobutadiene dimer via chemical transformation of silyl substituents, Hinata Kawabe, Taiki Imagawa, Airi Oguri, Hiroto Yoshida, Masaaki Nakamoto, The 20th International Symposium on Silicon Chemistry, 2024/05/13, Without Invitation, English, Organizing Committee of ISOS-20 Hiroshima, Hiroshima, Japan
  5. Modulation of Lewis Acidity and Steric Parameters in Cyclic Boronates: Copper-Catalyzed Internal-Selective Borylation of Challenging Terminal Alkynes, Takumi Tsushima, Masaaki Nakamoto, and Hiroto Yoshida, 1st Hiroshima–Yonsei Joint Symposium, 2024/09/20, Without Invitation, English, Department of chemistry, Hiroshima University, Hiroshima University
  6. Direct Suzuki–Miyaura Cross-Coupling of dan-Substituted Organoboron Reagents under Weak Base Conditions, Kazuki Tomota, Masaaki Nakamoto, Takumi Tsushima, and Hiroto Yoshida, 1st Hiroshima–Yonsei Joint Symposium, 2024/09/20, Without Invitation, English, Department of chemistry, Hiroshima University, Hiroshima University
  7. Synthesis of 2-Iodoarylstannanes by Iodostannylation of Arynes, Taiga Obayashi, Masaaki Nakamoto, Takumi Tsushima, and Hiroto Yoshida, 1st Hiroshima–Yonsei Joint Symposium, 2024/09/20, Without Invitation, English, Department of chemistry, Hiroshima University, Hiroshima University
  8. Stannylation of Aryl Chlorides with Stannylpotassium Reagents, Ryoka Hirata, Yuta Hiraoka, Masaaki Nakamoto, Takumi Tsushima, and Hiroto Yoshida, 1st Hiroshima–Yonsei Joint Symposium, 2024/09/20, Without Invitation, English, Department of chemistry, Hiroshima University, Hiroshima University
  9. Synthetic Study toward Cyclobutadiene Dimer: Development of Functionalization on Cyclobutadiene Complexes, Hinata Kawabe, Taiki Imagawa, Airi Oguri, Hiroto Yoshida, Masaaki Nakamoto, 1st Hiroshima–Yonsei Joint Symposium, 2024/09/20, Without Invitation, English, Department of chemistry, Hiroshima University, Hiroshima University
  10. Synthesis of Carbon Pyramidane: The Reaction of Stable Cyclobutadiene and "C1" Sources, Rento Ota, Taiki Imagawa, Hiroto Yoshida, Masaaki Nakamoto, 1st Hiroshima–Yonsei Joint Symposium, 2024/09/20, Without Invitation, English, Department of chemistry, Hiroshima University, Hiroshima University
  11. Synthetic chemistry with Lewis acidity-diminished organoboron compounds: a case of direct Suzuki–Miyaura coupling, Hiroto Yoshida, 5th International symposium of chemistry education center for sustainability, 2024/11/21, With Invitation, Japanese, BK21 FOUR chemistry education center for sustainabliry, Department of chemistry in Yonsei University, Seoul, Korea
  12. Direct Suzuki–Miyaura Coupling Reaction of R–B(dan), Hiroto Yoshida, 1st Hiroshima–Yonsei Joint Symposium, 2024/09/20, With Invitation, Japanese, Department of Chemistry, Hiroshima University, Hiroshima University
  13. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes, Takumi Tsushima, Masaaki Nakamoto, Hiroto Yoshida, 21st International symposium on organometallic chemistry directed toward organic synthesis, 2023/07/27, Without Invitation, English, OMCOS XXI, Vancouver, Canada
  14. Palladium/Copper Co-Catalyzed Direct Suzuki–Miyaura Cross-Coupling of dan-Substituted Organoboron Reagents, Kazuki Tomota, Masaaki Nakamoto, Hiroto Yoshida, 21st International symposium on organometallic chemistry directed toward organic synthesis, 2023/07/25, Without Invitation, English, OMCOS XXI, Vancouver, Canada
  15. A stable silapyramidane, T. Imagawa, D. M. Andrada, H. Yoshida, M. Nakamoto, D. Scheschkewitz, The 8th Asian Silicon Symposium (ASiS8), 2022/10/28, Without Invitation, English, Taipei, Taiwan
  16. Synthesis and Reaction of H–B(mdan) with Diminished Lewis Acidity, K. Miyazaki, M. Nakamoto, H. Yoshida, 25th IUPAC Conference on Physical Organic Chemistry (ICPOC-25), 2022/07/14, Without Invitation, English, International Union of Pure and Applied Chemistry (IUPAC)
  17. Attempt to synthesize silyl-substituted diphophatetrahedrane: highly strained organophosphorus molecule, Y. Shimada, R. Shang, H. Yoshida, M. Nakamoto, NaBic2021, 2021/12/14, Without Invitation, English, The Chemical Society of Nano Bio Info, online
  18. Synthesis and Reactivity of the Anionic Iridium Complex bearing All-carbon Ligated Pincer Ligands with Dipyrido-annulated Carbene Framework, K. Nakanishi, R. Shang, Y. Yamamoto, J. Oscar C. Jimenez-Halla, S. Yamazoe, M. Nakamoto, H. Yoshida, E Quimica Inorganica (EQI, Mexican Meeting of Inorganic Chemistry, 2021/10/05, Without Invitation, English, EQI, online
  19. Synthetic Chemistry with Lewis Acidity-Diminished Organoboron Compounds, Hiroto Yoshida, Hiroshima University & National Taiwan University Joint Symposium on Chemistry, 2022/03/19, With Invitation, English, Hiroshima Univ. and National Taiwan Univ., online
  20. Internal Selective Borylations of Terminal Alkynes with Lewis Acidity-Decreased Boron Reagents, 2020/12/11, Without Invitation, English
  21. Anthranilamide (aam)-Substituted Diboron: Pd-Catalyzed Selective B(aam) Transfer and Direct Cross-Coupling of Ar–B(aam) Therefrom, Hiroto Yoshida, Shintaro Kamio, Itaru Osaka, The 14th International Kyoto Conference on New Aspects of Organic Chemistry, 2018/11/15, Without Invitation, English
  22. Anthranilamide (aam)-Substituted Diboron: Palladium-Catalyzed Selective B(aam) Transfer, Hiroto Yoshida, International Congress on Pure & Applied Chemistry Langkawi 2018, 2018/11/01, With Invitation, English, Institut Kimia Malaysia, Langkawi, Malaysia
  23. 有機典型金属化合物の高選択的合成に向けた銅触媒反応の開発, Hiroto Yoshida, 有機金属化学仙台ミニシンポジウム, 2016/09/20, With Invitation, Japanese, 有機金属化学仙台ミニシンポジウム, Sendai, Japan
  24. Borylation Reactions with a Masked Diboron under Copper Catalysis, Hiroto Yoshida, International Symposium on Pure & Applied Chemistry 2016, 2016/08/17, With Invitation, English, International Symposium on Pure & Applied Chemistry 2016, Kuching, Malaysia
  25. Copper-Catalyzed Stannylation Reactions of Alkynes", Poster Presentation, Hiroto Yoshida, 20th International Symposium on Homogeneous Catalysis, 2016/07/14, Without Invitation, English, 20th International Symposium on Homogeneous Catalysis, Kyoto, Japan
  26. A Masked Borylcopper Species for Catalytic Borylation Reactions, Hiroto Yoshida, 1st International Symposium on Precisely Designed Catalysts with Customized Scaffolding, 2016/07/09, With Invitation, English, 科研費新学術領域研究「精密制御反応場」, Osaka, Japan
  27. アラインおよび銅触媒を利用した反応開発, Hiroto Yoshida, 早稲田大学講演会, 2016/06/17, With Invitation, Japanese, Tokyo, Japan
  28. Copper-Catalyzed Borylation Reactions with a Masked Diboron, Hiroto Yoshida, Yuki Takemoto, Ken Takaki, The 13th International Kyoto Conference on New Aspect of Organic Chemistry (IKCOC-13), 2015/11/13, Without Invitation, English
  29. Copper-Catalyzed Borylation Reactions with a Masked Diboron, 2015/09/09, Without Invitation, Japanese
  30. Copper-Catalyzed Reaction of a Masked Diboron with Organic Halides, Hiroto Yoshida, Yuki Takemoto, Ken Takaki, 2016/03/25, Without Invitation, English

Awards

  1. 2006, Tetrahedron Letters Most Cited Paper 2003-2006 Award, Elsevier
  2. 2019/09/29, Asian Core Program (ACP) Lectureship Award, ICCEOCA-14 Coordinator of Korea, Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons

Patented

  1. Patent, JP4734571, 2011/05/13

External Funds

Acceptance Results of Competitive Funds

  1. KAKENHI(Grant-in-Aid for Challenging Research (Exploratory)), 2023, 2025
  2. KAKENHI(Grant-in-Aid for Scientific Research (B)), 2022, 2025
  3. 2022/04, 2023/03
  4. 2021/04/01, 2022/03/31
  5. KAKENHI, 2016, 2017
  6. Strategic Basic Research Programs(ACT-C), 2012/10/01, 2018/03/31
  7. Strategic Basic Research Programs(ACT-C), 2012/10/01, 2016/03/31
  8. KAKENHI, Development of atom-economical multicomponent coupling reactions via hypervalent ate complexes, 2011, 2012
  9. KAKENHI, Development of synthetic method for constructing benzo-annulated framework by utilizing arynes, 2010, 2012
  10. KAKENHI, Development of novel organic transistor materials based on new molecular design utilizing element character, 2008, 2010
  11. KAKENHI, ortho-Selective double functionalization of aromatic skeletons based on multicomponent coupling reactions using arynes, 2007, 2008
  12. KAKENHI, 2005, 2006
  13. Strategic Basic Research Programs(ACT-C), 2012/10/01, 2018/03/31
  14. KAKENHI(Grant-in-Aid for Scientific Research (C)), 2017, 2019
  15. Strategic Basic Research Programs(ACT-C), 2012/10/01, 2018/03/31

Social Activities

Organizing Academic Conferences, etc.

  1. 2024/10, 2024/10
  2. 2023/10, 2023/10
  3. 第27回基礎有機化学討論会, 2016/04, 2016/09

History as Peer Reviews of Academic Papers

  1. 2023, Tetrahedron Lett., reviewer, 1
  2. 2023, Org. Chem. Front., reviewer, 2
  3. 2023, Polymer International, reviewer, 2
  4. 2023, Org. Lett., reviewer, 2
  5. 2023, Org. Biomol. Chem., reviewer, 10
  6. 2023, New. J. Chem., reviewer, 1
  7. 2023, Nature Synthesis, reviewer, 2
  8. 2023, J. Organomet. Chem., reviewer, 1
  9. 2023, J. Org. Chem., reviewer, 2
  10. 2023, J. Am. Chem.Soc., reviewer, 2
  11. 2023, Eur. J. Org. Chem., reviewer, 2
  12. 2023, Chem. Eur. J., reviewer, 2
  13. 2023, ACS Omega, reviewer, 1
  14. 2023, Angew. Chem. Int. Ed., reviewer, 3
  15. 2023, Asian J. Org. Chem., reviewer, 1
  16. 2023, Adv. Synth. Catal., reviewer, 1
  17. 2022, Tetrahedron Letters, Others, reviewer, 1
  18. 2022, Tetrahedron, Others, reviewer, 3
  19. 2022, Synlett, Others, reviewer, 1
  20. 2022, Synthesis, Others, reviewer, 1
  21. 2022, ChemistrySelect, Others, reviewer, 2
  22. 2022, Chemical Science, Others, reviewer, 1
  23. 2022, Polyhedron, Others, reviewer, 2
  24. 2022, Organic & Biomolecular Chemistry, Others, reviewer, 5
  25. 2022, Journal of Organic Chemistry, Others, reviewer, 4
  26. 2022, Journal of the American Chemical Society, Others, reviewer, 2
  27. 2022, European Journal of Organic Chemistry, Others, reviewer, 5
  28. 2022, European Journal of Inorganic Chemistry, Others, reviewer, 1
  29. 2022, ACS Catalysis, Others, reviewer, 3
  30. 2022, Heterocycles, Others, reviewer, 1
  31. 2022, Chemical Communications, Others, reviewer, 3
  32. 2022, Angewandte Chemie International Edition, Others, reviewer, 7
  33. 2022, Advanced Synthesis & Catalysis, Others, reviewer, 1
  34. 2021, Tetrahedron Letters, Others, reviewer, 1
  35. 2021, The Chemical Records, Others, reviewer, 1
  36. 2021, Synlett, reviewer, 2
  37. 2021, Synthesis, reviewer, 3
  38. 2021, ChemistrySelect, Others, reviewer, 2
  39. 2021, Organic Letters, Others, reviewer, 2
  40. 2021, Organic & Biomolecular Chemistry, reviewer, 3
  41. 2021, Journal of Organometallic Chemistry, Others, reviewer, 1
  42. 2021, European Journal of Inorganic Chemistry, Others, reviewer, 3
  43. 2021, Heterocycles, Others, reviewer, 1
  44. 2021, Chemistry Letters, Others, reviewer, 1
  45. 2021, Chemical Communications, Others, reviewer, 5
  46. 2021, Bulletin of Chemical Society of Japan, reviewer, 1
  47. 2021, Angewandte Chemie International Edition, Others, reviewer, 2
  48. 2021, Advanced Synthesis and Catalysis, Others, reviewer, 1
  49. 2021, Catalysts, Editor, Editorial Board Member