Hiroto Yoshida

Last Updated :2024/07/05

Affiliations, Positions
Graduate School of Advanced Science and Engineering, Professor
E-mail
yhirotohiroshima-u.ac.jp

Basic Information

Major Professional Backgrounds

  • 2001/04/01, 2006/11/30, Hiroshima University, Graduate School of Engineering, Research Assistant
  • 2006/09/01, 2006/11/10, Iowa State University, Researcher
  • 2006/12/01, 2007/03/31, Hiroshima University, Graduate School of Engineering, Assistant Professor
  • 2007/04/01, 2020/03/31, Hiroshima University, Graduate School of Engineering, Associate Professor
  • 2012/10, JST ACT-C, Principal Investigator
  • 2016/02, 2016/02, Graduate School of Natural Science and Technology, Okayama University, Lecturer (part-time)
  • 2020/04/01, Hiroshima University, Graduate School of Advanced Science and Engineering, Professor

Educational Backgrounds

  • Kyoto University, Graduate School, Division of Engineering, Department of Material Chemistry, Japan, 1998/04, 2001/03
  • Kyoto University, 1996/04, 1998/03
  • Kyoto University, Faculty of Engineering, Japan, 1992/04, 1996/03

Academic Degrees

  • Doctor of Engineering, Kyoto University
  • Master of Engineering, Kyoto University

Educational Activity

  • [Bachelor Degree Program] School of Science : Chemistry : Chemistry
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program
  • [Master's Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Applied Chemistry Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Chemistry Program
  • [Doctoral Program] Graduate School of Advanced Science and Engineering : Division of Advanced Science and Engineering : Applied Chemistry Program

In Charge of Primary Major Programs

  • Chemistry

Research Fields

  • Chemistry;Basic chemistry;Organic chemistry
  • Chemistry;Applied chemistry;Synthetic chemistry

Research Keywords

  • transition metal catalyst
  • Main Group Organometallics
  • reactive intermediate

Affiliated Academic Societies

  • Catalysis Society of Japan
  • The Society of Physical Organic Chemistry, Japan

Educational Activity

Course in Charge

  1. 2024, Liberal Arts Education Program1, 2Term, Modern Chemistry
  2. 2024, Liberal Arts Education Program1, 1Term, Introductory Seminar for First-Year Students
  3. 2024, Undergraduate Education, 4Term, Advanced Chemistry
  4. 2024, Undergraduate Education, Year, Chemistry Internship
  5. 2024, Undergraduate Education, First Semester, Special Study for Graduation
  6. 2024, Undergraduate Education, Second Semester, Special Study for Graduation
  7. 2024, Undergraduate Education, 3Term, Organic Main Group Chemistry
  8. 2024, Undergraduate Education, 1Term, Organic Chemistry I
  9. 2024, Graduate Education (Master's Program) , 2Term, Synthetic Organic Chemistry
  10. 2024, Graduate Education (Master's Program) , 2Term, Special Lectures in Chemistry C
  11. 2024, Graduate Education (Master's Program) , First Semester, Exercises in Chemistry A
  12. 2024, Graduate Education (Master's Program) , Second Semester, Exercises in Chemistry B
  13. 2024, Graduate Education (Master's Program) , Academic Year, Master's Thesis in Chemistry
  14. 2024, Graduate Education (Doctoral Program) , Academic Year, Doctoral Thesis in Chemistry

Award of Education

  1. 2019/72
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  3. 2015
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  4. 2014
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  5. 2012
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  6. 2012/11
  7. 2010
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  8. 2008
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Research Activities

Academic Papers

  1. Direct Suzuki-Miyaura Coupling of Naphthalene-1,8-diaminato (dan)-Substituted Cyclopropylboron Compounds, ADVANCED SYNTHESIS & CATALYSIS, 365(5), 682-686, 20230307
    Link to Paper Search Results by DOI
  2. Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides, RSC ADVANCES, 13(4), 2451-2457, 20230111
    Link to Paper Search Results by DOI
  3. Main-Group Organometallics Containing Boron or Tin that Open New Frontiers in Organic Synthesis, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 80(5), 477-488, 2022
    Link to Paper Search Results by DOI
  4. A stable silylborane with diminished boron Lewis acidity, DALTON TRANSACTIONS, 51(17), 6543-6546, 20220503
    Link to Paper Search Results by DOI
  5. Preparation of (pin)B-B(dan), ORGANIC SYNTHESES, 95, 218-+, 2018
    Link to Paper Search Results by DOI
  6. Platinum-P(BFPy)(3)-catalyzed regioselective diboration of terminal alkynes with (pin)B-B(aam), ORGANIC CHEMISTRY FRONTIERS, 9(5), 1370-1374, 20220301
    Link to Paper Search Results by DOI
  7. Straightforward construction of diarylmethane skeletons via aryne insertion into carbon-carbon sigma-bonds, CHEMICAL COMMUNICATIONS, 1505-1507, 2007
    Link to Paper Search Results by DOI
  8. Insertion of arynes into carbon-halogen sigma-bonds: regioselective acylation of aromatic rings, CHEMICAL COMMUNICATIONS, 2405-2407, 2007
    Link to Paper Search Results by DOI
  9. Three-component coupling of arynes, aminosilanes, and aldehydes, ORGANIC LETTERS, 9(17), 3367-3370, 20070816
    Link to Paper Search Results by DOI
  10. Three-component coupling using arynes and aminosilanes for ortho-selective double functionalization of aromatic skeletons, JOURNAL OF ORGANIC CHEMISTRY, 73(14), 5452-5457, 20080718
    Link to Paper Search Results by DOI
  11. Direct access to anthranilic acid derivatives via CO(2) incorporation reaction using arynes, ORGANIC LETTERS, 10(17), 3845-3847, 20080904
    Link to Paper Search Results by DOI
  12. Palladium-catalyzed disilylation of o-quinodimethanes: Synthesis of 9-and 10-membered disilacarbocycles, ORGANIC LETTERS, 10(19), 4319-4322, 20081002
    Link to Paper Search Results by DOI
  13. Fluorenes as new molecular scaffolds for carbon-carbon sigma-bond cleavage reaction: acylfluorenylation of arynes, CHEMICAL COMMUNICATIONS, 5963-5965, 2008
    Link to Paper Search Results by DOI
  14. Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes, ORGANIC LETTERS, 11(2), 373-376, 20090115
    Link to Paper Search Results by DOI
  15. Copper-catalysed bromoalkynylation of arynes, CHEMICAL COMMUNICATIONS, 46(4), 640-642, 2010
    Link to Paper Search Results by DOI
  16. Insertion of Arynes into Carbon-Chlorine Bonds of Chlorotriazines, CHEMISTRY LETTERS, 38(12), 1132-1133, 20091205
    Link to Paper Search Results by DOI
  17. Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes, CHEMICAL COMMUNICATIONS, 46(10), 1763-1765, 2010
    Link to Paper Search Results by DOI
  18. Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 83(3), 199-219, 20100315
    Link to Paper Search Results by DOI
  19. An Aryne Route to Cytosporone B and Phomopsin C, CHEMISTRY LETTERS, 39(5), 508-509, 20101205
    Link to Paper Search Results by DOI
  20. Facile access to boryltetralins and borylnaphthalenes via a cycloaddition using o-quinodimethanes, CHEMICAL COMMUNICATIONS, 46(29), 5253-5255, 2010
    Link to Paper Search Results by DOI
  21. Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by (13C) CP-MAS NMR, CHEMISTRY LETTERS, 39(11), 1215-1217, 20101105
    Link to Paper Search Results by DOI
  22. Hybridization of Carbon Nanotubes with Si-pi Polymers and Attachment of Resulting Hybrids to TiO2 Surface, CHEMISTRY LETTERS, 40(1), 87-89, 20110105
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  23. Synthesis of Dithienogermole-Containing pi-Conjugated Polymers and Applications to Photovoltaic Cells, ORGANOMETALLICS, 30(12), 3233-3236, 20110627
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  24. Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides, CHEMICAL COMMUNICATIONS, 47(30), 8512-8514, 2011
    Link to Paper Search Results by DOI
  25. Aryne reaction with trifluoromethyl ketones in three modes: C-C bond cleavage, [2+2] cycloaddition and O-arylation, CHEMICAL COMMUNICATIONS, 47(30), 8664-8666, 2011
    Link to Paper Search Results by DOI
  26. Three-Component Coupling of Arynes and Organic Bromides, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 50(41), 9676-9679, 2011
    Link to Paper Search Results by DOI
  27. An ortho-Quinodimethane Route to Lasofoxifene and U23469, CHEMISTRY LETTERS, 40(11), 1272-1274, 20111105
    Link to Paper Search Results by DOI
  28. Synthesis and Optical Properties of Pyridino End-Capped Oligothiophenes, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 84(11), 1243-1247, 20111115
    Link to Paper Search Results by DOI
  29. Palladium-Iminophosphine-Catalysed Carbostannylation of Arynes: Synthesis of ortho-Substituted Arylstannanes, Chem. Commun., 1880-1881, 20010401
  30. Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism, Bull. Chem. Soc. Jpn, 637-647, 20010401
  31. Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes, Organometallics, 5671-5678, 20000401
  32. Mechanistic Aspects of Palladium-Catalyzed Allylstannylation of Alkynes, Org. Lett., 2209-2211, 20000401
  33. Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synethesis and Reaction of e-Oxoallylstannanes, J. Am. Chem. Soc., 9030-9031, 20000401
  34. Diphenylphosphinophenolate: a Ligand for the Palladium-Catalysed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon, Chem. Commun., 1895-1896, 20000401
  35. Palladium-Catalyzed Dimerization-Carbostannylation of Alkynes: Synthesis of Highly Conjugated Alkenylstannanes, J. Am. Chem. Soc., 4290-4291, 19990401
  36. Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes: Stereoselective Synthesis of Trisubstituted Vinylstannanes, J. Am. Chem. Soc., 10221-10222, 19990401
  37. Carbostannylation of Alkynes Catalyzed by an Iminophosphine-Palladium Complex, J. Am. Chem. Soc., 2975-2976, 19980401
  38. An Iminophosphine-Palladium Catalyst for Cross-Coupling of Aryl Halides with Organostannanes, Tetrahedron Lett., 3759-3762, 19970401
  39. On the Catalytic Cycle of the Palladium-Catalyzed Cross-Coupling Reaction of Alkynylstannane with Aryl Iodide, Tetrahedron Lett., 5177-5180, 19970401
  40. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives, Angew. Chem. Int. Ed., 3247-3249, 20020401
  41. Base-Free Oxidative Homocoupling of Arylboronic Esters, Tetrahedron Lett., 1541-1544, 20030401
  42. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes: Synthesis of Benzo-Annulated Disilacarbocycles, J. Am. Chem. Soc., 6638-6639, 20030401
  43. Activator-Free Oxidative Homocoupling of Organosilanes Catalysed by a Palladium-DPPP Complex, Chem. Commun., 1510-1511, 20030401
  44. Thiostannylation of Arynes with Stannyl Sulfides: Synthesis and Reaction of 2-(Arylthio)arylstannanes, Chem. Commun., 1980-1981, 20040401
  45. Arynes in Three-Component Coupling Reaction: Straightforward Synthesis of Benzo-Annulated Iminofurans, Angew. Chem. Int. Ed., 3935-3938, 20040401
  46. Distannylation of Strained Carbon-Carbon Triple Bonds Catalyzed by a Palladium Complex, Angew. Chem. Int. Ed., 5052-5055, 20040401
  47. Straightforward Access to 2-Iminoisoindolines via Three-Component Coupling of Arynes, Isocyanides and Imines, Tetrahedron Lett., 8659-8662, 20040401
  48. A 2 : 1 Coupling Reaction of Arynes with Aldehydes via o-Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes, Org. Lett., 4049-4051, 20040401
  49. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent, Chem. Lett., 56-57, 20050401
  50. Cyclic Voltammetry and Theoretical Calculations of Silyl-substituted 1,4-Benzoquinones, J. Organomet. Chem., 1324-1331, 20050401
  51. Aminosilylation of Arynes with Aminosilanes: Synthesis of 2-Silylaniline Derivatives, Chem. Commun., 3454－3456, 20050401
  52. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide, Chem. Lett., 1538-1539, 20050401
  53. Palladium-Catalyzed Distannylation of ortho-Quinodimethanes, Org. Lett., 4157-4159, 20060401
  54. CO2 Incorporation Reaction using Arynes: Straightforward Access to Benzoxazinone, J. Am. Chem. Soc., 11040-11041, 20060401
  55. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles, Tetrahedron, 4793-4805, 20070401
  56. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes, Org. Lett., 3367-3370, 20070701
  57. Aryne Insertion Reactions into sigma-Bonds, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 69(8), 877-888, 20110801
  58. Facile synthesis of N-alkyl-N '-arylimidazolium salts via addition of imidazoles to arynes, ORGANIC LETTERS, 4(16), 2767-2769, 20020808
    Link to Paper Search Results by DOI
  59. Base-free oxidative homocoupling of arylboronic esters, TETRAHEDRON LETTERS, 44(8), 1541-1544, 20030217
    Link to Paper Search Results by DOI
  60. Palladium-catalyzed bissilylation of arynes with cyclic disilanes: Synthesis of benzo-annulated disilacarbocycles, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(22), 6638-6639, 20030604
    Link to Paper Search Results by DOI
  61. Activator-free oxidative homocoupling of organosilanes catalysed by a palladium-DPPP complex, CHEMICAL COMMUNICATIONS, 1510-1511, 2003
    Link to Paper Search Results by DOI
  62. Synthesis of organosilanylene-thienylene alternating oligomers bearing ether side chains, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 682(1-2), 267-271, 20031001
    Link to Paper Search Results by DOI
  63. 2,3,5,6-tetrasilyl- and 2,3,5,6-tetragermyl-1,4-benzoquinones: X-ray crystallographic analysis, cyclic voltammetry, and DFT calculations, ORGANOMETALLICS, 23(7), 1554-1561, 20040329
    Link to Paper Search Results by DOI
  64. Arynes in a three-component coupling reaction: Straightforward synthesis of benzoannulated iminofurans, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(30), 3935-3938, 2004
    Link to Paper Search Results by DOI
  65. Thiostannylation of arynes with stannyl sulfides: synthesis and reaction of 2-(arylthio)arylstannanes, CHEMICAL COMMUNICATIONS, 1980-1981, 2004
    Link to Paper Search Results by DOI
  66. Distannylation of strained carbon-carbon triple bonds catalysed by a palladium complex, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(38), 5052-5055, 2004
    Link to Paper Search Results by DOI
  67. A 2 : 1 coupling reaction of arynes with aldehydes via o-quinone methides: Straightforward synthesis of 9-arylxanthenes, ORGANIC LETTERS, 6(22), 4049-4051, 20041028
    Link to Paper Search Results by DOI
  68. Straightforward access to 2-iminoisoindolines via three-component coupling of arynes, isocyanides and imines, TETRAHEDRON LETTERS, 45(47), 8659-8662, 20041115
    Link to Paper Search Results by DOI
  69. Cyclic voltammetry and theoretical calculations of silyl-substituted 1,4-benzoquinones, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690(5), 1324-1331, 20050301
    Link to Paper Search Results by DOI
  70. Addition of silicon-silicon or-bonds to arynes or bisarynes catalyzed by a palladium complex, ORGANOMETALLICS, 24(1), 156-162, 20050103
    Link to Paper Search Results by DOI
  71. Facile synthesis of polycyclic aromatic hydrocarbons via a trisaryne equivalent, CHEMISTRY LETTERS, 34(1), 56-57, 20050105
    Link to Paper Search Results by DOI
  72. Palladium-catalysed dimerisation-distannylation of arynes: synthesis and reaction of 2,2 '-distannylbiaryls, CHEMICAL COMMUNICATIONS, 5678-5680, 2005
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  73. Transition metal-catalyzed reactions or electrophilic coupling reactions using arynes, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 63(6), 627-639, 200506
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  74. Facile insertion reaction of arynes into carbon-carbon sigma-bonds, CHEMICAL COMMUNICATIONS, 3292-3294, 2005
    Link to Paper Search Results by DOI
  75. Aminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivatives, CHEMICAL COMMUNICATIONS, 3454-3456, 2005
    Link to Paper Search Results by DOI
  76. Aryne insertion into alpha-cyanocarbonyl compounds: direct introduction of carbonyl and cyanomethyl moieties into the aromatic skeletons, TETRAHEDRON LETTERS, 46(39), 6729-6731, 20050926
    Link to Paper Search Results by DOI
  77. Sonogashira coupling of diethynylsilane and dibromoarene in wet solvent for the formation of poly[(ethynylenearylene)-co-(diethynylenesilylenearylene)], JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690(17), 3951-3956, 20050901
    Link to Paper Search Results by DOI
  78. Carbophosphinylation of arynes with cyanomethyldiphenylphosphine oxide, CHEMISTRY LETTERS, 34(11), 1538-1539, 20051105
    Link to Paper Search Results by DOI
  79. CO2 incorporation reaction using arynes: Straightforward access to benzoxazinone, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(34), 11040-11041, 20060830
    Link to Paper Search Results by DOI
  80. Palladium-catalyzed distannylation of ortho-quinodimethanes, ORGANIC LETTERS, 8(18), 4157-4159, 20060831
    Link to Paper Search Results by DOI
  81. Synthesis of organosilicon polymers containing donor-acceptor type pi-conjugated units and their applications to dye-sensitized solar cells, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(4), 801-805, 20070115
    Link to Paper Search Results by DOI
  82. Synthesis of diarylenenaphthylene- and diaryleneanthrylene-containing organosilicon polymers and their applications to organic EL devices, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(5), 1020-1024, 20070201
    Link to Paper Search Results by DOI
  83. Three-component coupling using arynes and isocyanides: straightforward access to benzo-annulated nitrogen or oxygen heterocycles, TETRAHEDRON, 63(22), 4793-4805, 20071228
    Link to Paper Search Results by DOI
  84. Aryne Insertion Reactions into sigma-Bonds, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 69(8), 877-888, 201108
    Link to Paper Search Results by DOI
  85. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 51(1), 235-238, 2012
    Link to Paper Search Results by DOI
  86. MULTICOMPONENT COUPLING REACTION OF ARYNES FOR CONSTRUCTION OF HETEROCYCLIC SKELETONS, HETEROCYCLES, 85(6), 1333-1349, 20120601
    Link to Paper Search Results by DOI
  87. Aryne Insertion Reactions into Carbon-Carbon sigma-Bonds, SYNLETT, 1725-1732, 201207
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  88. Hetero-Diels-Alder reaction of photochemically generated alpha-hydroxy-o-quinodimethanes with trifluoromethyl ketones, TETRAHEDRON LETTERS, 53(31), 3974-3976, 20120801
    Link to Paper Search Results by DOI
  89. Copper-Catalyzed Three-Component Borylstannylation of Alkynes, CHEMISTRY-A EUROPEAN JOURNAL, 18(46), 14841-14844, 201211
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  90. SYNTHESIS AND REACTIONS OF SILICON-BRIDGED DITHIENYLBIPHENYLS. FINE TUNING OF ELECTRONIC STATES BY BRIDGING SILICON CHAIN LENGTHS, HETEROCYCLES, 86(2), 1167-1176, 20121231
    Link to Paper Search Results by DOI
  91. Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes, ORGANIC LETTERS, 15(4), 952-955, 20130215
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  92. Synchronous Ar-F and Ar-Sn Bond Formation through Fluorostannylation of Arynes, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 52(33), 8629-8632, 20130812
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  93. Copper-catalyzed distannylation of alkynes, CHEMICAL COMMUNICATIONS, 49(99), 11671-11673, 2013
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  94. A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons, CHEMICAL COMMUNICATIONS, 50(61), 8299-8302, 201408
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  95. Three-Component Carboboration of Alkenes under Copper Catalysis, SYNTHESIS-STUTTGART, 46(14), 1924-1932, 201407
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  96. Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes, ORGANIC LETTERS, 16(13), 3512-3515, 201407
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  97. N-Heterocyclic carbene-catalyzed double acylation of enones with benzils, CHEMICAL COMMUNICATIONS, 50(82), 12285-12288, 201410
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  98. Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes, SYNTHESIS-STUTTGART, 46(22), 3024-3032, 201411
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  99. Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes, ASIAN JOURNAL OF ORGANIC CHEMISTRY, 3(11), 1204-1209, 201411
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  100. Synchronous Ar?F and Ar?Sn Bond Formation through Fluorostannylation of Arynes, Synform, A147-A149, 20131201
  101. Convenient Synthesis of 2-Amino-4H-chromenes from Photochemically Generated o-Quinone Methides and Malononitrile, JOURNAL OF HETEROCYCLIC CHEMISTRY, 52(1), 59-66, 201501
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  102. Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron, CHEMICAL COMMUNICATIONS, 51(29), 6297-6300, 201502
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  103. Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide, CHEMICAL COMMUNICATIONS, 51(46), 9440-9442, 201504
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  104. Copper-catalyzed alpha-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes, CHEMICAL COMMUNICATIONS, 51(53), 10616-10619, 201505
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  105. Copper-Catalyzed Metallation Reactions of Unsaturated Carbon-Carbon Bonds, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 73(6), 632-648, 201506
  106. Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si, CHEMICAL RECORD, 16(1), 419-434, 201602
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  107. Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments, ACS CATALYSIS, 6(3), 1799-1811, 201603
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  108. Stannylation Reactions under Base Metal Catalysis: Some Recent Advances, SYNTHESIS-STUTTGART, 48(16), 2540-2552, 201608
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  109. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes, ORGANIC LETTERS, 19(4), 830-833, 20170217
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  110. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes, CHEMISTRYSELECT, 2(11), 3212-3215, 20170413
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  111. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides, ORGANOMETALLICS, 36(7), 1345-1351, 20170410
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  112. Naphthobispyrazine as an Electron-deficient Building Unit for pi-Conjugated Polymers: Efficient Synthesis and Polymer Properties, CHEMISTRY LETTERS, 46(8), 1193-1196, 201708
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  113. Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan), ORGANIC CHEMISTRY FRONTIERS, 4(7), 1215-1219, 201707
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  114. Aryne-Imine-Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o-Quinone Methides and Arynes, ASIAN JOURNAL OF ORGANIC CHEMISTRY, 6(8), 973-976, 201708
    Link to Paper Search Results by DOI
  115. NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 13, 1816-1822, 20170830
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  116. B(MIDA)-Containing Diborons, ACS OMEGA, 2(9), 5911-5916, 201709
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  117. &ITmeso&IT-Tetraaryl(porphyrinato)cobalt(III)-catalyzed Oxygenation of Disilanes under Aerobic Conditions, CHEMISTRY LETTERS, 46(12), 1807-1809, 201712
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  118. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes, Org. Lett., 19(4), 830-833, 20170401
  119. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes, ChemistrySelect, 2(11), 3212-3215, 20170401
  120. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides, Organometallics, 36(7), 1345-1351, 20170401
  121. Naphthobispyrazine as an Electron-deficient Building Unit for -Conjugated Polymers: Efficient Synthesis and Polymer Properties, Chem. Lett., 46(8), 1193-1196, 20170601
  122. Copper-Catalyzed Direct Borylation of Alkyl, Alkenyl and Aryl Halides with B(dan), Org. Chem. Front., 4(7), 1215-1219, 20170701
  123. Aryne–Imine–Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o-Quinone Methides and Arynes, Asian J. Org. Chem., 6(8), 973-976, 20170801
  124. NHC-Catalyzed Cleavage of Vicinal Diketones and Triketones Followed by Insertion of Enones and Ynones, Beilstein J. Org. Chem., 13, 1816-1822, 20170801
  125. B(MIDA)-Containing Diborons, ACS Omega, 2(9), 5911-5916, 20170901
  126. Copper-catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar-Br Bond, CHEMISTRY LETTERS, 47(8), 957-959, 201808
    Link to Paper Search Results by DOI
  127. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer, CHEMICAL COMMUNICATIONS, 54(67), 9290-9293, 20180828
    Link to Paper Search Results by DOI
  128. Anthranilamide (aam)-substituted arylboranes in direct carbon-carbon bond-forming reactions, CHEMICAL COMMUNICATIONS, 55(18), 2624-2627, 20190304
    Link to Paper Search Results by DOI
  129. Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates, MOLECULES, 24(8), 20190402
    Link to Paper Search Results by DOI
  130. An anthranilamide-substituted borane [H-B(aam)]: its stability and application to iridium-catalyzed stereoselective hydroboration of alkynes, CHEMICAL COMMUNICATIONS, 55(38), 5420-5422, 20190511
    Link to Paper Search Results by DOI
  131. Copper-catalyzed arylstannylation of arynes in a sequence, CHEMICAL COMMUNICATIONS, 55(46), 6503-6506, 20190611
    Link to Paper Search Results by DOI
  132. Copper-Catalyzed B(dan)-Installing Allylic Borylation of Allylic Phosphates, ADVANCED SYNTHESIS & CATALYSIS, 361(10), 2286-2290, 20190514
    Link to Paper Search Results by DOI
  133. Preparation of (pin)B–B(dan), Organic Syntheses, 95, 218-230, 201807
  134. Dithiazolylthienothiophene Bisimide: A Novel Electron-Deficient Building Unit for N-Type Semiconducting Polymers, ACS APPLIED MATERIALS & INTERFACES, 11(26), 23410-23416, 20190703
    Link to Paper Search Results by DOI
  135. One-pot Sequential Fluorostannylation-Arylstannylation of Arynes, CHEMISTRY LETTERS, 48(9), 1032-1034, 201909
    Link to Paper Search Results by DOI
  136. Direct Suzuki-Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons, ACS CATALYSIS, 10(1), 346-351, 20200103
    Link to Paper Search Results by DOI
  137. Dithiazolylthienothiophene Bisimide-Based pi-Conjugated Polymers: Improved Synthesis and Application to Organic Photovoltaics as P-Type Semiconductor, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 93(4), 561-567, 202004
    Link to Paper Search Results by DOI
  138. Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H-B(dan) as a B(dan) electrophile, CHEMICAL COMMUNICATIONS, 56(47), 6388-6391, 20200614
    Link to Paper Search Results by DOI
  139. A leap forward in sulfonium salt and sulfur ylide chemistry, CHINESE CHEMICAL LETTERS, 32(1), 299-312, 202101
    Link to Paper Search Results by DOI
  140. Synthetic Chemistry with Lewis Acidity-Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross-Couplings, ADVANCED SYNTHESIS & CATALYSIS, 363(9), 2310-2324, 20210427
    Link to Paper Search Results by DOI
  141. Transition Metal-Free B(dan)-Installing Reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) Electrophile, Chemical Communications, 56(47), 6388-6391, 20200430
    Link to Paper Search Results by DOI
  142. RECENT ADVANCES IN SYNTHETIC TRANSFORMATIONS WITH ROBUST YET REACTIVE B(DAN) MOIETY, HETEROCYCLES, 102(8), 1478-1516, 2021
    Link to Paper Search Results by DOI
  143. MPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters, SYNTHESIS-STUTTGART, 53(24), 4678-4681, 20211217
    Link to Paper Search Results by DOI
  144. Borylation and Stannylation Reactions with Tuning of Lewis Acidity, CHEMICAL RECORD, 21(12), 3483-3497, 202112
    Link to Paper Search Results by DOI
  145. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes, ACS CATALYSIS, 11(23), 14381-14387, 20211203
    Link to Paper Search Results by DOI

Publications such as books

  1. 2022, Science of Synthesis Knowledge Updates 2022/3, 4.4.6 Product Subclass 6, Thieme, 2022, Scholarly Book, Contributor, 英語, O. Jackowski, C. Marschner, H. Ohmiya, A. Perez-Luna, D. C. G. A. Pinto, D. H. A. Rocha, C. M. M. dos Santos, V. L. M. Silva, Y. Sumida, N. Takeda, X. Tang, H. Yoshida, 9783132452862, 536, 1-21
  2. 2022, Comprehensive Aryne Synthetic Chemistry, Elsevier, 2022, Scholarly Book, Supervisor, 英語, A. T. Biju, J. Chen, S. Deswal, A. Guin, T. Hamura, T. Ikawa, X. Jiang, J. Tan, H. Tanaka, G. Zhu, H. Yoshida, 978-0-323-85153-4, 381, 1-381
    Amazon URLAmazon Image Link (Small)
  3. 2022, Comprehensive Aryne Synthetic Chemistry, General introduction to Comprehensive Aryne Synthetic Chemistry, Elsevier, 2022, Scholarly Book, Contributor, 英語, A. T. Biju, J. Chen, S. Deswal, A. Guin, T. Hamura, T. Ikawa, X. Jiang, J. Tan, H. Tanaka, G. Zhu, H. Yoshida, 978-0-323-85153-4, 381, 1-11
    Amazon URLAmazon Image Link (Small)
  4. 2022, Comprehensive Aryne Synthetic Chemistry, Insertion into sigma-Bonds, Elsevier, 2022, Scholarly Book, Contributor, 英語, A. T. Biju, J. Chen, S. Deswal, A. Guin, T. Hamura, T. Ikawa, X. Jiang, J. Tan, H. Tanaka, G. Zhu, H. Yoshida, 978-0-323-85153-4, 381, 57-123
    Amazon URLAmazon Image Link (Small)
  5. 2021, Modern Aryne Chemistry, Multicomponent Reactions Involving Arynes and Related Chemistry, Wiley-VCH, 2021, Scholarly Book, Contributor, 英語, Hiroto Yoshida, 505
  6. 2021, e-EROS Encyclopedia of Reagents for Organic Synthesis, N-(Carboxymethyl)-N-methyl-glycine, Wiley, 2021, Dictionary/Encyclopedia, Single work, 英語, Hiroto Yoshida
  7. 2020/05/04, e-EROS, Encyclopedia of Reagents for Organic Synthesis, 1H-Naphtho[1,8-de]-1,3,2-diazaborine, 2,3-Dihydro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-, Wiley, 2020, 2020, Dictionary/Encyclopedia, Single work, 英語, Hiroto Yoshida

Invited Lecture, Oral Presentation, Poster Presentation

  1. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes, Takumi Tsushima, Masaaki Nakamoto, Hiroto Yoshida, 21st International symposium on organometallic chemistry directed toward organic synthesis, 2023/07/27, Without Invitation, English, OMCOS XXI, Vancouver, Canada
  2. Palladium/Copper Co-Catalyzed Direct Suzuki–Miyaura Cross-Coupling of dan-Substituted Organoboron Reagents, Kazuki Tomota, Masaaki Nakamoto, Hiroto Yoshida, 21st International symposium on organometallic chemistry directed toward organic synthesis, 2023/07/25, Without Invitation, English, OMCOS XXI, Vancouver, Canada
  3. A stable silapyramidane, T. Imagawa, D. M. Andrada, H. Yoshida, M. Nakamoto, D. Scheschkewitz, The 8th Asian Silicon Symposium (ASiS8), 2022/10/28, Without Invitation, English, Taipei, Taiwan
  4. Synthesis and Reaction of H–B(mdan) with Diminished Lewis Acidity, K. Miyazaki, M. Nakamoto, H. Yoshida, 25th IUPAC Conference on Physical Organic Chemistry (ICPOC-25), 2022/07/14, Without Invitation, English, International Union of Pure and Applied Chemistry (IUPAC)
    Related URL
  5. Attempt to synthesize silyl-substituted diphophatetrahedrane: highly strained organophosphorus molecule, Y. Shimada, R. Shang, H. Yoshida, M. Nakamoto, NaBic2021, 2021/12/14, Without Invitation, English, The Chemical Society of Nano Bio Info, online
  6. Synthesis and Reactivity of the Anionic Iridium Complex bearing All-carbon Ligated Pincer Ligands with Dipyrido-annulated Carbene Framework, K. Nakanishi, R. Shang, Y. Yamamoto, J. Oscar C. Jimenez-Halla, S. Yamazoe, M. Nakamoto, H. Yoshida, E Quimica Inorganica (EQI, Mexican Meeting of Inorganic Chemistry, 2021/10/05, Without Invitation, English, EQI, online
  7. Synthetic Chemistry with Lewis Acidity-Diminished Organoboron Compounds, Hiroto Yoshida, Hiroshima University & National Taiwan University Joint Symposium on Chemistry, 2022/03/19, With Invitation, English, Hiroshima Univ. and National Taiwan Univ., online
  8. Internal Selective Borylations of Terminal Alkynes with Lewis Acidity-Decreased Boron Reagents, 2020/12/11, Without Invitation, English
  9. Anthranilamide (aam)-Substituted Diboron: Pd-Catalyzed Selective B(aam) Transfer and Direct Cross-Coupling of Ar–B(aam) Therefrom, Hiroto Yoshida, Shintaro Kamio, Itaru Osaka, The 14th International Kyoto Conference on New Aspects of Organic Chemistry, 2018/11/15, Without Invitation, English
  10. Anthranilamide (aam)-Substituted Diboron: Palladium-Catalyzed Selective B(aam) Transfer, Hiroto Yoshida, International Congress on Pure & Applied Chemistry Langkawi 2018, 2018/11/01, With Invitation, English, Institut Kimia Malaysia, Langkawi, Malaysia
  11. 有機典型金属化合物の高選択的合成に向けた銅触媒反応の開発, Hiroto Yoshida, 有機金属化学仙台ミニシンポジウム, 2016/09/20, With Invitation, Japanese, 有機金属化学仙台ミニシンポジウム, Sendai, Japan
  12. Borylation Reactions with a Masked Diboron under Copper Catalysis, Hiroto Yoshida, International Symposium on Pure & Applied Chemistry 2016, 2016/08/17, With Invitation, English, International Symposium on Pure & Applied Chemistry 2016, Kuching, Malaysia
  13. Copper-Catalyzed Stannylation Reactions of Alkynes", Poster Presentation, Hiroto Yoshida, 20th International Symposium on Homogeneous Catalysis, 2016/07/14, Without Invitation, English, 20th International Symposium on Homogeneous Catalysis, Kyoto, Japan
  14. A Masked Borylcopper Species for Catalytic Borylation Reactions, Hiroto Yoshida, 1st International Symposium on Precisely Designed Catalysts with Customized Scaffolding, 2016/07/09, With Invitation, English, 科研費新学術領域研究「精密制御反応場」, Osaka, Japan
  15. アラインおよび銅触媒を利用した反応開発, Hiroto Yoshida, 早稲田大学講演会, 2016/06/17, With Invitation, Japanese, Tokyo, Japan
  16. Copper-Catalyzed Borylation Reactions with a Masked Diboron, Hiroto Yoshida, Yuki Takemoto, Ken Takaki, The 13th International Kyoto Conference on New Aspect of Organic Chemistry (IKCOC-13), 2015/11/13, Without Invitation, English
  17. Copper-Catalyzed Borylation Reactions with a Masked Diboron, 2015/09/09, Without Invitation, Japanese
  18. Copper-Catalyzed Reaction of a Masked Diboron with Organic Halides, Hiroto Yoshida, Yuki Takemoto, Ken Takaki, 2016/03/25, Without Invitation, English

Awards

  1. 2006, Tetrahedron Letters Most Cited Paper 2003-2006 Award, Elsevier
  2. 2019/09/29, Asian Core Program (ACP) Lectureship Award, ICCEOCA-14 Coordinator of Korea, Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons

Patented

  1. Patent, JP4734571, 2011/05/13

External Funds

Acceptance Results of Competitive Funds

  1. 2022/04, 2023/03
  2. 2021/04/01, 2022/03/31
  3. KAKENHI, 2016, 2017
  4. Strategic Basic Research Programs（ACT-C), 2012/10/01, 2018/03/31
  5. Strategic Basic Research Programs(ACT-C), 2012/10/01, 2016/03/31
  6. KAKENHI, Development of atom-economical multicomponent coupling reactions via hypervalent ate complexes, 2011, 2012
    Permalink
  7. KAKENHI, Development of synthetic method for constructing benzo-annulated framework by utilizing arynes, 2010, 2012
    Permalink
  8. KAKENHI, Development of novel organic transistor materials based on new molecular design utilizing element character, 2008, 2010
    Permalink
  9. KAKENHI, ortho-Selective double functionalization of aromatic skeletons based on multicomponent coupling reactions using arynes, 2007, 2008
    Permalink
  10. KAKENHI, 2005, 2006
    Permalink
  11. Strategic Basic Research Programs（ACT-C), 2012/10/01, 2018/03/31
  12. KAKENHI(Grant-in-Aid for Scientific Research (C)), 2017, 2019
  13. Strategic Basic Research Programs（ACT-C), 2012/10/01, 2018/03/31

Social Activities

Organizing Academic Conferences, etc.

  1. 2023/10, 2023/10
  2. 第27回基礎有機化学討論会, 2016/04, 2016/09

History as Peer Reviews of Academic Papers

  1. 2023, Tetrahedron Lett., reviewer, 1
  2. 2023, Org. Chem. Front., reviewer, 2
  3. 2023, Polymer International, reviewer, 2
  4. 2023, Org. Lett., reviewer, 2
  5. 2023, Org. Biomol. Chem., reviewer, 10
  6. 2023, New. J. Chem., reviewer, 1
  7. 2023, Nature Synthesis, reviewer, 2
  8. 2023, J. Organomet. Chem., reviewer, 1
  9. 2023, J. Org. Chem., reviewer, 2
  10. 2023, J. Am. Chem.Soc., reviewer, 2
  11. 2023, Eur. J. Org. Chem., reviewer, 2
  12. 2023, Chem. Eur. J., reviewer, 2
  13. 2023, ACS Omega, reviewer, 1
  14. 2023, Angew. Chem. Int. Ed., reviewer, 3
  15. 2023, Asian J. Org. Chem., reviewer, 1
  16. 2023, Adv. Synth. Catal., reviewer, 1
  17. 2022, Tetrahedron Letters, Others, reviewer, 1
  18. 2022, Tetrahedron, Others, reviewer, 3
  19. 2022, Synlett, Others, reviewer, 1
  20. 2022, Synthesis, Others, reviewer, 1
  21. 2022, ChemistrySelect, Others, reviewer, 2
  22. 2022, Chemical Science, Others, reviewer, 1
  23. 2022, Polyhedron, Others, reviewer, 2
  24. 2022, Organic & Biomolecular Chemistry, Others, reviewer, 5
  25. 2022, Journal of Organic Chemistry, Others, reviewer, 4
  26. 2022, Journal of the American Chemical Society, Others, reviewer, 2
  27. 2022, European Journal of Organic Chemistry, Others, reviewer, 5
  28. 2022, European Journal of Inorganic Chemistry, Others, reviewer, 1
  29. 2022, ACS Catalysis, Others, reviewer, 3
  30. 2022, Heterocycles, Others, reviewer, 1
  31. 2022, Chemical Communications, Others, reviewer, 3
  32. 2022, Angewandte Chemie International Edition, Others, reviewer, 7
  33. 2022, Advanced Synthesis & Catalysis, Others, reviewer, 1
  34. 2021, Tetrahedron Letters, Others, reviewer, 1
  35. 2021, The Chemical Records, Others, reviewer, 1
  36. 2021, Synlett, reviewer, 2
  37. 2021, Synthesis, reviewer, 3
  38. 2021, ChemistrySelect, Others, reviewer, 2
  39. 2021, Organic Letters, Others, reviewer, 2
  40. 2021, Organic & Biomolecular Chemistry, reviewer, 3
  41. 2021, Journal of Organometallic Chemistry, Others, reviewer, 1
  42. 2021, European Journal of Inorganic Chemistry, Others, reviewer, 3
  43. 2021, Heterocycles, Others, reviewer, 1
  44. 2021, Chemistry Letters, Others, reviewer, 1
  45. 2021, Chemical Communications, Others, reviewer, 5
  46. 2021, Bulletin of Chemical Society of Japan, reviewer, 1
  47. 2021, Angewandte Chemie International Edition, Others, reviewer, 2
  48. 2021, Advanced Synthesis and Catalysis, Others, reviewer, 1
  49. 2021, Catalysts, Editor, Editorial Board Member